Tracking the fate of seed particles in dispersion polymerization: Preparation and application of fluorescent polymer particles

2012 ◽  
Vol 127 (4) ◽  
pp. 2635-2640 ◽  
Author(s):  
Zhipeng Song ◽  
Eric S. Daniels ◽  
E. David Sudol ◽  
James F. Gilchrist ◽  
Andrew Klein ◽  
...  
Keyword(s):  
Dispersion Polymerization ◽  
Polymer Particles ◽  
Seed Particles ◽  
Fluorescent Polymer

scholarly journals Effects of properties of the surface layer of seed particles on the formation of golf ball-like polymer particles by seeded dispersion polymerization

2010 ◽  
Vol 42 (1) ◽  
pp. 66-71 ◽  
Author(s):  
Natsumi Konishi ◽  
Teruhisa Fujibayashi ◽  
Takuya Tanaka ◽  
Hideto Minami ◽  
Masayoshi Okubo
Keyword(s):  
Surface Layer ◽  
Dispersion Polymerization ◽  
Golf Ball ◽  
Polymer Particles ◽  
Seed Particles ◽  
Seeded Dispersion Polymerization

scholarly journals RGD-decorated conjugated polymer particles as fluorescent biomedical probes prepared by Sonogashira dispersion polymerization

2015 ◽  
Vol 51 (45) ◽  
pp. 9358-9361 ◽  
Author(s):  
Naveed Anwar ◽  
Anne Rix ◽  
Wiltrud Lederle ◽  
Alexander J. C. Kuehne
Keyword(s):  
Click Chemistry ◽  
Fluorescent Probes ◽  
Conjugated Polymer ◽  
Dispersion Polymerization ◽  
Cell Labelling ◽  
Polymer Particles ◽  
Free Thiol ◽  
One Step

We present a one-step Sonogashira dispersion polymerization generating monodisperse conjugated polymer particles with acetylene units on their surface. These moieties can be bio-functionalized using copper-free thiol-yne click chemistry providing fluorescent probes for cell labelling and imaging.

Fluorescent polymer particles by emulsion and miniemulsion polymerization

2003 ◽  
Vol 41 (6) ◽  
pp. 766-778 ◽  
Author(s):  
Fr�d�ric Tronc ◽  
Mei Li ◽  
Jianping Lu ◽  
Mitchell A. Winnik ◽  
Bansi Lal Kaul ◽  
...  
Keyword(s):  
Miniemulsion Polymerization ◽  
Polymer Particles ◽  
Fluorescent Polymer

Synthesis of an Amphiphilic Macromonomer Bearing a Terminal Fluorene Moiety and Its Application to the Preparation of Fluorescent Polymer Particles

2012 ◽  
Vol 41 (11) ◽  
pp. 1487-1488 ◽  
Author(s):  
Jin Motoyanagi ◽  
Katsutoshi Nagura ◽  
Kohei Sawada ◽  
Sadao Miki ◽  
Masahiko Minoda
Keyword(s):  
Polymer Particles ◽  
Fluorescent Polymer

Preparation of fluorescent polymer particles by emulsion polymerization

e-Polymers ◽  
2005 ◽  
Vol 5 (1) ◽  
Author(s):  
Shunchao Gu ◽  
Naoto Anzai ◽  
Daisuke Nagao ◽  
Yoshio Kobayashi ◽  
Mikio Konno
Keyword(s):  
Emulsion Polymerization ◽  
Fluorescent Dyes ◽  
Reaction System ◽  
Ammonium Persulfate ◽  
Polymer Particles ◽  
Emulsion Copolymerization ◽  
Fluorescent Polymer ◽  
Fluorescent Particles ◽  
Average Size ◽  
Pyrene Concentration

AbstractCore-shell type fluorescent polymer particles were produced in multi-step emulsion polymerization. Cross-linking was introduced to the shell to suppress leakage of fluorescent dyes contained in the core particles. First, fluorescent polymer particles were synthesized by emulsion copolymerization of styrene (St) and butyl acrylate (BA) with an anionic surfactant (SE1025A) initiated by ammonium persulfate (APS) in the presence of pyrene. The concentrations of St, BA, SE1025A and APS were 550, 89, 8.2 and 5 mol/m3 water, respectively. Then the fluorescent particles were covered with cross-linked polymer by emulsion copolymerization of St, BA and divinylbenzene (DVB) with SE1025A emulsifier. In the polymerization, a mixture of St, BA, SE1025A and DVB was added dropwise to the reaction system. The average size of cross-linked fluorescent particles ranged from 50 to 70 nm. The fluorescence intensity of the particles prepared in a pyrene concentration range of 8 - 20 mol/m3 water increased linearly with pyrene concentration. Fluorescence intensities of the particles prepared with and without DVB were also measured. The cross-linked polymer formed by DVB addition drastically suppressed the intensity drop caused by dye leakage almost to one-third of the intensity drop measured for particles prepared without DVB addition.

Uncontrolled polymerization that occurred during photoinitiated RAFT dispersion polymerization of acrylic monomers promotes the formation of uniform raspberry-like polymer particles

2020 ◽  
Vol 11 (28) ◽  
pp. 4591-4603 ◽  
Author(s):  
Ruiming Zeng ◽  
Ying Chen ◽  
Li Zhang ◽  
Jianbo Tan
Keyword(s):  
Dispersion Polymerization ◽  
Polymer Particles ◽  
Acrylic Monomers

Uniform raspberry-like polymer particles are prepared by a different type of photoinitiated RAFT dispersion polymerization.

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