The influence of solvent type and polymer concentration on the physical properties of solid state polymerized PA66 nanofiber yarn

2012 ◽  
Vol 126 (3) ◽  
pp. 1112-1120 ◽  
Author(s):  
Razieh Hashemi Sanatgar ◽  
Sedigheh Borhani ◽  
Seyed Abdolkarim Hosseini Ravandi ◽  
Ali Akbar Gharehaghaji
Keyword(s):  
Solid State ◽  
Physical Properties ◽  
Polymer Concentration ◽  
Nanofiber Yarn ◽  
Solvent Type ◽  
Influence Of Solvent

Mechanical and Biological Characteristics of Electrospun PCL Meshes – the Influence of Solvent Type and Concentration

2013 ◽  
Vol 683 ◽  
pp. 137-140 ◽  
Author(s):  
Juliana Dias ◽  
Antonio Gloria ◽  
Paulo J. Bártolo
Keyword(s):  
Polymer Concentration ◽  
Research Work ◽  
Biological Properties ◽  
Physical Structure ◽  
Nanometer Scale ◽  
Solvent Type ◽  
Fiber Dimensions ◽  
Good Cell ◽  
Solution Electrospinning ◽  
Influence Of Solvent

Non-woven scaffolds, with fiber dimensions at a nanometer scale, can mimic the physical structure of natural extracellular matrices, being ideal construts for Tissue Engineering applications. This research work explores solution electrospinning to produce nanoscale meshes. Different Poly (ε-caprolactone) (PCL) solutions were considered and the influence of both polymer concentration and type of solvent studied regarding the fabrication of polymeric meshes and their mechanical and biological properties. PCL solutions were prepared using two different solvents: glacial acetic acid with triethylamine (AA/TEA)) and Acetone (DMK) at different concentrations. PCL/AA/TEA meshes present better mechanical properties and good cell viability and proliferation.

Improved Sol-Gel Materials for Efficient Solid State Dye Lasers

1993 ◽  
Vol 329 ◽  
Author(s):  
Michael Canva ◽  
Patrick Georges ◽  
Jean-Fran^ois Perelgritz ◽  
Alain Brun ◽  
Fréddric Chaput ◽  
...  
Keyword(s):  
Solid State ◽  
Physical Properties ◽  
Room Temperature ◽  
Sol Gel ◽  
Tunable Lasers ◽  
Optical Quality ◽  
Dye Lasers ◽  
Laser Dyes ◽  
Host Matrix ◽  
Host Matrices

AbstractPhotoresistant laser dyes were trapped in silica based xerogel host matrices to obtain solid state tunable lasers. For this purpose very dense xerogel samples with improved chemical and physical properties were prepared at room temperature by the sol-gel technology. The as-prepared materials were polished to obtain optical quality surfaces and were used as new lasing media.Lasing action of such different dyes as rhodamine, perylene and pyrromethene doping dense sol-gel matrices was demonstrated. Efficiencies of 30 % or lifetimes of more than 100,000 shots were achieved with different new ≤dye dopant/host matrix≥ couples. Their different performances are reviewed and discussed.

Crosslinking Reaction of Rubber with Aldehydes

1970 ◽  
Vol 43 (2) ◽  
pp. 188-209
Author(s):  
Y. Minoura ◽  
M. Tsukasa
Keyword(s):  
Solid State ◽  
Organic Acids ◽  
Physical Properties ◽  
Lewis Acids ◽  
Solid State Reactions ◽  
Crosslinking Reaction ◽  
Reaction Products ◽  
Toluenesulfonic Acid ◽  
Ionic Reaction ◽  
Acidic Catalysts

Abstract The reactions of rubber with aldehydes have previously been studied in latex or in solutions and the reaction products formed by cyclization, condensation, or addition, have been reported. In the present study, solid-state reactions of rubber with aldehydes were carried out. It was found that crosslinked rubbers may be obtained by press curing in the presence of aldehydes with acidic catalysts. Poly-chloroprene and Hypalon especially undergo these reactions without a catalyst or with a small amount of catalyst. In the experiments using various aldehydes, some improvements in the properties of the crosslinked rubber were observed when aldehydes such as paraformaldehyde or α-polyoxymethylene were used. Some Lewis acids such as SnCl2·2H2O were found to be more effective catalysts than the above, and it was found that organic acids such as p-toluenesulfonic acid could also be used. The curing seemed to be an ionic reaction. The physical properties of the crosslinked rubber are similar to those of sulfur-cured rubbers.

The efficacy of stone consolidants based on alkoxysilanes: Influence of solvent type

2018 ◽  
pp. 13-16
Author(s):  
B. Sena da Fonseca ◽  
A.P. Ferreira Pinto ◽  
S. Piçarra ◽  
M.F. Montemor
Keyword(s):  
Solvent Type ◽  
Stone Consolidants ◽  
Influence Of Solvent

scholarly journals Synergistic application of continuous granulation and selective laser sintering 3D printing for the development of pharmaceutical dosage forms with enhanced dissolution rates and physical properties

2021 ◽  
Author(s):  
Rishi Thakkar ◽  
Yu Zhang ◽  
Jiaxiang Zhang ◽  
Mohammed Maniruzzaman
Keyword(s):  
Solid State ◽  
3D Printing ◽  
Physical Properties ◽  
Dosage Forms ◽  
Flow Properties ◽  
Printing Process ◽  
Powder Bed ◽  
Printing Processes ◽  
Binder Jetting ◽  
Physical Mixtures

AbstractThis study demonstrated the first case of combining novel continuous granulation with powder-based pharmaceutical 3-dimensional (3D) printing processes to enhance the dissolution rate and physical properties of a poorly water-soluble drug. Powder bed fusion (PBF) and binder jetting 3D printing processes have gained much attention in pharmaceutical dosage form manufacturing in recent times. Although powder bed-based 3D printing platforms have been known to face printing and uniformity problems due to the inherent poor flow properties of the pharmaceutical physical mixtures (feedstock). Moreover, techniques such as binder jetting currently do not provide any solubility benefits to active pharmaceutical ingredients (APIs) with poor aqueous solubility (>40% of marketed drugs). For this study, a hot-melt extrusion-based versatile granulation process equipped with UV-Vis process analytical technology (PAT) tools for the in-line monitoring of critical quality attributes (i.e., solid-state) of indomethacin was developed. The collected granules with enhanced flow properties were mixed with vinylpyrrolidone-vinyl acetate copolymer and a conductive excipient for efficient sintering. These mixtures were further characterized for their bulk properties observing an excellent flow and later subjected to a PBF-3D printing process. The physical mixtures, processed granules, and printed tablets were characterized using conventional as well as advanced solid-state characterization. These characterizations revealed the amorphous nature of the drug in the processed granules and printed tablets. Further, the in vitro release testing of the tablets with produced granules as a reference standard depicted a notable solubility advantage (100% drug released in 5 minutes at >pH 6.8) over the pure drug and the physical mixture. Our developed system known as DosePlus combines innovative continuous granulation and PBF-3D printing process which can potentially improve the physical properties of the bulk drug and formulations in comparison to when used in isolation. This process can further find application in continuous manufacturing of granules and additive manufacturing of pharmaceuticals to produce dosage forms with excellent uniformity and solubility advantage.Abstract Figure

scholarly journals Amino Acid Composition and Physical Properties of Silk with Solid-State 13C NMR

2006 ◽  
Vol 62 (9) ◽  
pp. 191-198
Author(s):  
Masako Saito ◽  
Mizuho Ueda ◽  
Jun Yatabe ◽  
Riichiro Chujo
Keyword(s):  
Amino Acid ◽  
Solid State ◽  
Physical Properties ◽  
Amino Acid Composition ◽  
Acid Composition ◽  
13C Nmr ◽  
Solid State 13C Nmr
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