Effect of morphology of polyaniline nanomaterials on cure kinetics and properties of liquid crystalline epoxy nanocomposite

2011 ◽  
Vol 125 (1) ◽  
pp. 562-570 ◽  
Author(s):  
Joonwon Bae
2010 ◽  
Vol 428-429 ◽  
pp. 71-74 ◽  
Author(s):  
Jun Gang Gao ◽  
Cai Yun Zhang ◽  
Li Huo ◽  
Yuan Yuan Zhang

A liquid crystalline epoxy resin of p-biphenylene di-4-(2,3-epoxypropyloxy)benzoate (p-BDEPB) was synthesized from allyl bromide, 4-hydroxy ethyl benzoate and 4,4-dihydroxybiphenyl. Its structure and liquid crystalline behavior were characterized by DSC, 1H-NMR, FTIR, POM and XRD. The results are shown that this compound is smectic liquid crystalline.The melting point of p-BDEPB is 210 oC and clearing point is over 300 oC, the epoxy value is 0.312 mol/100g. The average curing Ea of p-BDEPB/3-methyl-tetrahydrophthalic anhydride (MeTHPA) system is 97.2kJ/mol. The gel point of cured-system Tgel is 89.0 oC, curing temperature Tcu is 132.5 oC and finishing temperature Tf is 146.5 oC. The curing reaction can be described by the autocatalytic Šesták-Berggren (S-B) equation, the two reaction orders m and n is 0.23 and 0.74, respectively.


2018 ◽  
Vol 663 ◽  
pp. 1-8 ◽  
Author(s):  
Xin Luo ◽  
Xiaoyan Yu ◽  
Yuanhui Ma ◽  
Kimiyoshi Naito ◽  
Qingxin Zhang

2011 ◽  
Vol 513 (1-2) ◽  
pp. 88-93 ◽  
Author(s):  
Yin-Ling Liu ◽  
Zhi-Qi Cai ◽  
Xiufang Wen ◽  
Pihui Pi ◽  
Dafeng Zheng ◽  
...  

2015 ◽  
Vol 114 (1) ◽  
pp. 46-51 ◽  
Author(s):  
Yun-Yuan Tai ◽  
Sheng-Hao Hsu ◽  
Rung-Shu Chen ◽  
Wei-Fang Su ◽  
Min-Huey Chen

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