Structure−property relationships of halogen-free flame-retarded poly(butylene terephthalate) and glass fiber reinforced PBT

2011 ◽  
Vol 124 (1) ◽  
pp. 9-18 ◽  
Author(s):  
T. Köppl ◽  
S. Brehme ◽  
F. Wolff-Fabris ◽  
V. Altstädt ◽  
B. Schartel ◽  
...  
Keyword(s):  
Glass Fiber ◽  
Fiber Reinforced ◽  
Structure Property ◽  
Butylene Terephthalate ◽  
Structure Property Relationships ◽  
Glass Fiber Reinforced ◽  
Flame Retarded ◽  
Halogen Free

Fire performance of brominated and halogen-free flame retardants in glass-fiber reinforced poly(butylene terephthalate)

2017 ◽  
Vol 42 (1) ◽  
pp. 18-27 ◽  
Author(s):  
M. Suzanne ◽  
A. Ramani ◽  
S. Ukleja ◽  
M. McKee ◽  
J. Zhang ◽  
...  
Keyword(s):  
Glass Fiber ◽  
Flame Retardants ◽  
Fire Performance ◽  
Fiber Reinforced ◽  
Butylene Terephthalate ◽  
Glass Fiber Reinforced ◽  
Halogen Free

Novel synergists for flame retarded glass-fiber reinforced poly(1,4-butylene terephthalate)

Polimery ◽  
2013 ◽  
Vol 58 (5) ◽  
pp. 403-412 ◽  
Author(s):  
JEREMIE LOUISY ◽  
SERGE BOURBIGOT ◽  
SOPHIE DUQUESNE ◽  
PHILIPPE DESBOIS ◽  
ALEXANDER KOENIG ◽  
...  
Keyword(s):  
Glass Fiber ◽  
Fiber Reinforced ◽  
Butylene Terephthalate ◽  
Glass Fiber Reinforced ◽  
Flame Retarded

Aluminum hypophosphite and aluminum phenylphosphinate: A comprehensive comparison of chemical interaction during pyrolysis in flame-retarded glass-fiber-reinforced polyamide 6

2019 ◽  
Vol 37 (3) ◽  
pp. 193-212
Author(s):  
Xi Cheng ◽  
Jianming Wu ◽  
Chenguang Yao ◽  
Guisheng Yang
Keyword(s):  
Heat Release ◽  
Glass Fiber ◽  
Chemical Interaction ◽  
Fire Behavior ◽  
Polyamide 6 ◽  
Fiber Reinforced ◽  
Limiting Oxygen Index ◽  
Glass Fiber Reinforced ◽  
Flame Retarded ◽  
Aluminum Hypophosphite

This study compared thermal degradation, pyrolysis behavior, and the fire behavior of flame-retarded glass-fiber-reinforced polyamide 6 with aluminum hypophosphite and aluminum phenylphosphinate (BPA-Al), respectively. We sythesize aluminum phenylphosphinate by benzenephosphinic acid (BPA) and AlCl3.6H2O in water. so we call aluminum phenylphosphinate BPA-Al for short. The dependence of limiting oxygen index on phosphorus content was linear for aluminum hypophosphite and BPA-Al. Thermogravimetric analysis proved aluminum hypophosphite was less stable than BPA-Al. Thermogravimetric-Fourier transform infrared tests showed that aluminum hypophosphite system balanced the charring process and the gas releasing well, and that BPA-Al system enhanced the charring process and decreased the gas releasing. Peak heat release rate and total heat release data proved that aluminum hypophosphite system was superior to BPA-Al system in lowering the heat release. Their differences were caused by different P-H (aluminum hypophosphite) and P-phenyl (BPA-Al) structures. P-H structure did better than P-phenyl structure in balancing the condensed phase effect and the gaseous phase action. So P-H structure (aluminum hypophosphite) was more suitable than P-phenyl structure (BPA-Al) in the flame retardancy of glass-fiber-reinforced polyamide 6.

scholarly journals Halogen Free Flame-Retardant Glass Fiber Reinforced PA 66 / PPO Alloys

2021 ◽  
Author(s):  
Zhenya Zhang ◽  
Kunpeng Cai ◽  
Yaxin Guo ◽  
Xiaohua Liu ◽  
Suqin He ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Heat Resistance ◽  
Glass Fiber ◽  
Flame Retardant ◽  
Wear Volume ◽  
Fiber Reinforced ◽  
Wear Properties ◽  
Excellent Thermal Stability ◽  
Glass Fiber Reinforced ◽  
Halogen Free

Abstract Halogen-free flame retardants are ideal plastic additives that meet carbon neutral requirements. In this work, halogen free flame retardant with glass fiber reinforced PA66/PPO composites were prepared by using coated red phosphorus (FRM-150B) and phosphorus-silicon flame retardant (WR6002). The mechanical properties, heat resistance, friction and wear properties and flame retardancy were carried out to evaluate the performances of composites using as structural parts that require heat resistance, dimensional stability and accuracy. It was found that the friction coefficient and wear volume of the composites were improved with the contents of glass fiber increased, as a result, PA66/PPO composites was obtained with excellent comprehensive performance when the content of compatilizer is 7%, the glass fiber was 30%, the content of FRM is 8% and the phosphorous-silicon flame retardant is 16%. The flame retardant effect of FRM-150B and WR6002 in PA66/PPO was presented in the condensed phase, the results showed that the composite material with 16% WR6002 forms a carbon layer with excellent thermal stability. On the other hand, the mechanical properties of composites were hardly affected, has important prospects in automotive components and household appliances

Study on the Tensile Properties of Glass Fiber Reinforced Poly Cyclic Butylene Terephthalate Composites under and after High Temperature

2015 ◽  
Vol 727-728 ◽  
pp. 262-265
Author(s):  
Lu Zhang ◽  
Zhen Qing Wang ◽  
Ji Feng Zhang ◽  
Li Min Zhou
Keyword(s):  
High Temperature ◽  
Glass Fiber ◽  
Tensile Properties ◽  
Composite Laminates ◽  
Thermoplastic Composites ◽  
Fiber Reinforced ◽  
Melt Viscosity ◽  
Butylene Terephthalate ◽  
Glass Fiber Reinforced ◽  
Cyclic Butylene Terephthalate

A fatal disadvantage of continuously reinforced thermoplastic composites is the high melt viscosity of the matrix which hampers impregnation. However, the melt viscosity of low molecular weight cyclic butylene terephthalate resin can reach extremely low value, which simplifies impregnation and even allows for the use of thermoset production techniques resin transfer moulding. To solve the problem of the glass fiber reinforced poly cyclic butylene terephthalate composites applied in the environment of high temperature, the specimens of composite laminates were tested under and after different temperature. It has been observed that the tensile properties of GF/PCBT composites decrease with increasing temperature between room 25°C and 150°C and tend towards stability after the high temperature.

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