Effect of a coupling agent on the properties of hemp-hurd-powder-filled styrene-butadiene rubber

2011 ◽  
Vol 121 (2) ◽  
pp. 681-689 ◽  
Author(s):  
Jie Wang ◽  
Weidong Wu ◽  
Wencai Wang ◽  
Jianchun Zhang
Keyword(s):  
Coupling Agent ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Styrene Butadiene ◽  
Hemp Hurd

Starch/SBR Biocomposites Prepared by Solid Blend Method: Effect of Surface Modification and Coupling Agent

2012 ◽  
Vol 430-432 ◽  
pp. 1076-1080
Author(s):  
Mei Chun Li ◽  
Xin Ge ◽  
Jong Hyuk Lim ◽  
Min Su Kim ◽  
Ur Ryong Cho
Keyword(s):  
Mechanical Properties ◽  
Coupling Agent ◽  
Interfacial Interaction ◽  
Ceric Ammonium Nitrate ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Method Effect ◽  
Styrene Butadiene ◽  
Effect Of Surface

Starch/Styrene Butadiene Rubber (SBR) biocomposites were prepared by directly blending of starch and SBR on a two-roll miller. Two types of starch: pure starch and modified starch (M-starch) were used as rubber fillers. M-starch were synthesized by grafting of methyl methacrylate (MMA) monomer onto starch backbone using ceric ammonium nitrate-initiated radical polymerization. Coupling agent styrene-g-(maleic anhydride) (SMA) was used to further improve the interfacial interaction between the filler and rubber matrix. The morphology and mechanical properties of unmodified starch/SBR and M-starch/SBR biocomposites with SMA content of 0, 1, 3, and 5 phr were investigated. SEM observations showed the particle size of M-starch decreased and their dispersion in the SBR matrix significantly improved than unmodified starch. Mechanical properties of M-starch/SBR biocomposites were superior than those of unmodified starch/SBR biocomposites.

The Mechanical Properties of Modified Attapulgite Reinforced Nature Rubber and Styrene-Butadiene Rubber Nanocomposites

2010 ◽  
Vol 150-151 ◽  
pp. 762-765
Author(s):  
Ji Hu Wang ◽  
Hong Bo Liu ◽  
Shao Guo Wen ◽  
Yan Shen
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Coupling Agent ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
The Matrix ◽  
Modified Attapulgite ◽  
Rubber Nanocomposites ◽  
Styrene Butadiene

Attapulgite (AT)/natural rubber (NR)/ styrene-butadiene rubber (SBR) nanocomposites have been prepared after attapulgite was modified by different coupling agent. The treatment of AT caused the adhesion between AT nanorods and the nature rubber/styrene-butadiene rubber was improved, which enhanced the tensile properties of the matrix. The tensile strength of composites attained 15.6 MPa after AT was modified by 3%wt Si-69 coupling with addition of 20 phr.

Effect of silane coupling agent on filler and rubber interaction of silica reinforced solution styrene butadiene rubber

2013 ◽  
Vol 34 (10) ◽  
pp. 1575-1582 ◽  
Author(s):  
Liangliang Qu ◽  
Guozhu Yu ◽  
Ximing Xie ◽  
Lili Wang ◽  
Jing Li ◽  
...  
Keyword(s):  
Coupling Agent ◽  
Silane Coupling Agent ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Silane Coupling ◽  
Styrene Butadiene

scholarly journals Effect of Sulfur Variation on the Vulcanizate Structure of Silica-Filled Styrene-Butadiene Rubber Compounds with a Sulfide–Silane Coupling Agent

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2815
Author(s):  
Sangwook Han ◽  
Bonyoung Gu ◽  
Sungwoo Kim ◽  
Seongrae Kim ◽  
Dalyong Mun ◽  
...  
Keyword(s):  
Coupling Agent ◽  
Silane Coupling Agent ◽  
Influencing Factor ◽  
Coupling Efficiency ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Compounds ◽  
Silane Coupling ◽  
Silica Dispersion ◽  
Styrene Butadiene

The vulcanizate structure of filled compounds is affected by filler–rubber interactions (FRI) and the chemical crosslink density (CCD) of the matrix rubber. In particular, in filled compounds using a silica–silane system, FRIs due to silica–rubber coupling are a major influencing factor for the vulcanizate structure and physical properties. In this study, the effect of sulfur variation on the vulcanizate structure of silica-filled solution styrene–butadiene rubber compounds using a sulfide–silane coupling agent was studied. The vulcanizate structure according to sulfur variation was quantitatively analyzed using the swelling test and Flory–Rehner and Kraus equations. As the sulfur content increased, both FRI and the CCD increased, and it was confirmed that sulfur variation influenced the silica–rubber coupling efficiency through increased FRI. In addition, field emission scanning electron microscope images showed that increased FRI contributed to improvements in silica dispersion, abrasion resistance, and energy loss characteristics.

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