Synthesis and rheological behavior of hydrophobically modified block copolymers

2010 ◽  
Vol 116 (5) ◽  
pp. 3047-3055 ◽  
Author(s):  
Jorge de A. Rodrigues ◽  
Regina Sandra V. Nascimento
1993 ◽  
Vol 26 (18) ◽  
pp. 4928-4934 ◽  
Author(s):  
Takao Ohta ◽  
Yoshihisa Enomoto ◽  
James L. Harden ◽  
Masao Doi

2005 ◽  
Vol 38 (7) ◽  
pp. 2981-2989 ◽  
Author(s):  
Sandra L. Cram ◽  
Hugh R. Brown ◽  
Geoffrey M. Spinks ◽  
Dominique Hourdet ◽  
Costantino Creton

RSC Advances ◽  
2015 ◽  
Vol 5 (43) ◽  
pp. 33905-33913 ◽  
Author(s):  
Miao Du ◽  
Yanjie Ma ◽  
Heng Su ◽  
Xiang Wang ◽  
Qiang Zheng

Polysulfobetaine methacrylate (PSBMA) that was hydrophobically modified with methacrylic acid 2,3-epoxypropyl ester (GMA) was synthesized via micellar copolymerization method. Viscosity of the hydrophobically modified PSBMA solution was sensitive to added salt concentration.


Polymers ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 3579
Author(s):  
Ilsia M. Davletbaeva ◽  
Alexander Yu. Alentiev ◽  
Zulfiya Z. Faizulina ◽  
Ilnaz I. Zaripov ◽  
Roman Yu. Nikiforov ◽  
...  

Organosubstituted silica derivatives were synthesized and investigated as modifiers of block copolymers based on macroinitiator and 2,4-toluene diisocyanate. A peculiarity of the modified block copolymers is the existence in their structure of coplanar rigid polyisocyanate blocks of acetal nature (O-polyisocyanates). Organosubstituted silica derivatives have a non-additive effect on high-temperature relaxation and α-transitions of modified polymers and exhibit the ability to influence the supramolecular structure of block copolymers. The use of the developed modifiers leads to a change in the gas transport properties of block copolymers. The increase of the permeability coefficients is due to the increase of the diffusion coefficients. At the same time, the gas solubility coefficients do not change. An increase in the ideal selectivity for a number of gas pairs is observed. An increase in the selectivity for the CO2/N2 gas pair (from 25 to 39) by 1.5 times demonstrates the promising use of this material for flue gases separation.


2018 ◽  
Vol 12 (1) ◽  
pp. 86-92 ◽  
Author(s):  
Fernanda Dias ◽  
◽  
Roberta Souza ◽  
Elizabete Lucas ◽  
◽  
...  

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