Poly(vinyl pyrrolidone-co-vinyl acetate)-graft-poly(ε-caprolactone) as a compatibilizer for cellulose acetate/poly(ε-caprolactone) blends

2009 ◽  
Vol 113 (5) ◽  
pp. 2945-2954 ◽  
Author(s):  
Tomokazu Higeshiro ◽  
Yoshikuni Teramoto ◽  
Yoshiyuki Nishio
Keyword(s):  
Cellulose Acetate ◽  
Vinyl Acetate ◽  
Vinyl Pyrrolidone ◽  
Poly Vinyl Pyrrolidone

Ultrafine Cellulose Acetate Fibers with Nanoscale Structural Features

2008 ◽  
Vol 8 (9) ◽  
pp. 4461-4469 ◽  
Author(s):  
Lifeng Zhang ◽  
You-Lo Hsieh
Keyword(s):  
Hydrogen Bonding ◽  
Cellulose Acetate ◽  
Pore Volume ◽  
Structural Features ◽  
Fiber Formation ◽  
Vinyl Pyrrolidone ◽  
Chain Entanglement ◽  
Bicomponent Fibers ◽  
Micron Size ◽  
Poly Vinyl Pyrrolidone

Nano-structural features were introduced to ultrafine cellulose acetate (CA) fibers by electrospinning of its mixtures with either poly(vinyl pyrrolidone) PVP or β-cyclodextrin (β-CD) in DMF, followed by dissolution of the added PVP or β-CD. The presence of the charge-holding PVP enabled fiber formation from CA below its entanglement chain length and improved the electrospinning efficiency to produce bicomponent fibers with wide ranging diameters from 30 to 650 nm. At up to 50% contents, the PVP in the bicomponent fibers was phase-separated from CA and, upon removal, resulting in highly angulated fiber surfaces with nanometer-size spherulites and sub-micron size ridges and grooves. Adding β-CD to CA enabled fiber formation at concentrations below the chain entanglement concentration Ce (16.5%). Hydrogen bonding between β-CD and CA, as evident by FTIR, helped to distribute β-CD as individual molecules in the CA matrix and producing more uniform and finer (130–150 nm in diameters) fibers, irrespective of their β-CD contents. Removal of β-CD from the fibers originally containing 40% β-CD, generated nanoporous fibers with 2-nm nanopores and 70% increase in specific surface and doubled pore volume.

Variable morphologies of poly(vinyl acetate)–montmorillonite nanocomposites obtained by emulsion polymerization in the presence of poly(vinyl pyrrolidone)

e-Polymers ◽  
2006 ◽  
Vol 6 (1) ◽  
Author(s):  
Mihai-Cosmin Corobea ◽  
Violeta Uricanu ◽  
Dan Donescu ◽  
Szabolcs Deladi ◽  
Constantin Radovici ◽  
...  
Keyword(s):  
Emulsion Polymerization ◽  
Vinyl Acetate ◽  
Polymer Matrix ◽  
The Other ◽  
Vinyl Pyrrolidone ◽  
Clay Concentration ◽  
End Products ◽  
Poly Vinyl Pyrrolidone ◽  
Montmorillonite Nanocomposites

AbstractNanocomposites containing poly(vinyl acetate) and montmorillonite (MMT) were prepared using a one-batch emulsion polymerization recipe, assisted by poly (vinylpyrrolidone). The relative clay concentration with respect to the other reaction partners influences drastically the morphological units in the end-products. For low [MMT], well-defined, spherical PVAc particles are formed. At the other extreme, for high [MMT], production of polymeric, water-swollen aggregates is favored. Depending on the MMT/PVP ratio, the clay will be dispersed in the final polymer matrix in variable forms, from individual platelets to agglomerates of reformed tactoids.

Interaction and Scale of Mixing in Cellulose Acetate/Poly(N-vinyl Pyrrolidone-co-vinyl Acetate) Blends

Cellulose ◽  
2005 ◽  
Vol 12 (3) ◽  
pp. 281-291 ◽  
Author(s):  
Takahiro Ohno ◽  
Sachiko Yoshizawa ◽  
Yoshiharu Miyashita ◽  
Yoshiyuki Nishio
Keyword(s):  
Cellulose Acetate ◽  
Vinyl Acetate ◽  
Vinyl Pyrrolidone

Fibrous membranes of cellulose acetate and poly(vinyl pyrrolidone) by electrospinning method: Preparation and characterization

2010 ◽  
pp. NA-NA
Author(s):  
M. M. Castillo-Ortega ◽  
J. Romero-García ◽  
F. Rodríguez ◽  
A. Nájera-Luna ◽  
P. J. Herrera-Franco
Keyword(s):  
Cellulose Acetate ◽  
Vinyl Pyrrolidone ◽  
Electrospinning Method ◽  
Fibrous Membranes ◽  
Poly Vinyl Pyrrolidone
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