Preparation and characterization of flame-retardant melamine cyanurate/polyamide 6 nanocomposites byin situpolymerization

2009 ◽  
Vol 113 (4) ◽  
pp. 2109-2116 ◽  
Author(s):  
Zhi-Yong Wu ◽  
Wei Xu ◽  
Yao-Chi Liu ◽  
Jin-Kui Xia ◽  
Qian-Xin Wu ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyamide 6 ◽  
Melamine Cyanurate

Preparation of Polyamide 6/Silica Modified Melamine Cyanurate Non-Halogen Flame Retardant Nanocomposites by In Situ Polymerization

2016 ◽  
Vol 16 (9) ◽  
pp. 9919-9924 ◽  
Author(s):  
Shanshan Wei ◽  
Leyu Wang ◽  
Ce Liu ◽  
Mulin Yu ◽  
Xianhong Chen ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyamide 6 ◽  
Melamine Cyanurate

Effect of halloysite nanotubes on thermal and flame retardant properties of polyamide 6/melamine cyanurate composites

2014 ◽  
Vol 36 (5) ◽  
pp. 892-896 ◽  
Author(s):  
Lili Li ◽  
Zhihao Wu ◽  
Shuaishuai Jiang ◽  
Sideng Zhang ◽  
Shouyang Lu ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyamide 6 ◽  
Halloysite Nanotubes ◽  
Melamine Cyanurate ◽  
Flame Retardant Properties

scholarly journals Preparation and characterization of polyamide 6 fibre based on a phosphorus-containing flame retardant

RSC Advances ◽  
2018 ◽  
Vol 8 (17) ◽  
pp. 9261-9271 ◽  
Author(s):  
Ke Liu ◽  
Yuanyuan Li ◽  
Lei Tao ◽  
Ru Xiao
Keyword(s):  
Flame Retardant ◽  
Melt Spinning ◽  
Polyamide 6 ◽  
Melt Polycondensation ◽  
Phosphorus Containing

Intrinsically flame retardant polyamide 6 (FRPA6) was synthesized by melt polycondensation of caprolactam and 9,10-dihydro-10-[2,3-di(hydroxycarbonyl)propyl]-10-phosphaphenanthrene-10-oxide (DDP). And the FRPA6 fibres were prepared by melt spinning.

Effect of Modified-Silicon Rubber on Thermal Degradation and Anti-Droplet Properties of Polyamide 6/Melamine Cyanurate Flame Retardant Composites

2011 ◽  
Vol 130-134 ◽  
pp. 1511-1515
Author(s):  
Na Feng ◽  
Jian Hui Liu ◽  
Hiroshi Uyama ◽  
Wei Liu
Keyword(s):  
Thermal Stability ◽  
Thermogravimetric Analysis ◽  
Thermal Degradation ◽  
Flame Retardant ◽  
Polyamide 6 ◽  
Condensation Process ◽  
Char Residue ◽  
Silicon Rubber ◽  
Melamine Cyanurate ◽  
Thermal Stability Of

In this paper, the effect of modified-silicon rubber (MSR) on thermal degradation and anti-droplet properties of melamine cyanurate (MCA) flame retardant polyamide 6 (PA6) composites was studied by using thermogravimetric analysis (TG) and vertical burning test. TG analyses indicated that modified-silicon rubber could markedly promote the condensation process of PA6/MCA/MSR composites compared with PA6/MCA composites, and the char residue of PA6/MCA/MSR composites at 600¡æwas much higher than that of PA6/MCA composites. DTGcurves showed that MSR could slow down the rate of degradation of PA6/MCA composites. More importantly, there was no melt-drip produced when PA6/MCA/MSR composites was burning. It was concluded that MSR increase the thermal stability of composites and could effectively prevent the formation of melt drip.

Preparation of Flame Retardant Polyamide 6 Fibers with Melamine Cyanurate and Bicyclic Phosphates via Melt Spinning

2012 ◽  
Vol 621 ◽  
pp. 44-47 ◽  
Author(s):  
Yun Zhi Lin ◽  
Kai Sha ◽  
Hai Yan Xu ◽  
Yin Tang ◽  
Ru Xiao
Keyword(s):  
Flame Retardant ◽  
Polyethylene Oxide ◽  
Melt Spinning ◽  
Oxygen Index ◽  
Polyamide 6 ◽  
Solid Residue ◽  
Melamine Cyanurate ◽  
Dispersing Agent ◽  
Ft Ir ◽  
Co Addition

Melamine cyanurate (MCA) and bicyclic phosphates (BP) were combined and added into polyamide6 (PA6) with the polyethylene oxide (PEO) as dispersing agent by melt blend, then the flame retardant PA6 fibers were prepared by melt spinning. Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM) were utilized to characterize the morphology and properties of the blends. The results indicated that the MCA particles with diametric size about 400nm are highly uniformly in the PA6 matrix, the spinnability and tensile strength of flame retardant PA6 fibers declined due to co-addition of MCA and M102B, TGA showed the flame retardant PA6 fibers decomposed early and retained high solid residue. From Flammability testing, an increase of oxygen index to 33.2% and an improvement of the UL-94 classification to V-0 were observed.

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