Kinetic study of the free-radical polymerization of vinyl acetate in the presence of deuterated chloroform by1H-NMR spectroscopy

2008 ◽  
Vol 110 (3) ◽  
pp. 1784-1796 ◽  
Author(s):  
Mohammad Ali Semsarzadeh ◽  
Mahdi Abdollahi
Keyword(s):  
Free Radical ◽  
Nmr Spectroscopy ◽  
Kinetic Study ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Free Radical Polymerization ◽  
Deuterated Chloroform

cis-Polychloroprene

1965 ◽  
Vol 38 (3) ◽  
pp. 526-531
Author(s):  
C. A. Aufdermarsh ◽  
R. Pariser
Keyword(s):  
Free Radical ◽  
Nmr Spectroscopy ◽  
Radical Polymerization ◽  
Free Radical Polymerization

Abstract cis-Polychloroprene was synthesized by chlorinolysis of 1,4-poly-2-(tri-n-butyltin)-l,3- butadiene. The latter was obtained by free radical polymerization of 2-(tri-n-butyltin)-l,3-butadiene. The structure of cis-polychloroprene was established by ozonolysis, and by infrared and NMR spectroscopy.

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