Interactions of a smart cationic polyelectrolyte based on hydroxypropylcellulose with an anionic surfactant

2007 ◽  
Vol 107 (5) ◽  
pp. 3184-3189 ◽  
Author(s):  
Kamila Rosół ◽  
Krzysztof Szczubiałka ◽  
Barbara Jachimska ◽  
Szczepan Zapotoczny ◽  
Maria Nowakowska
Keyword(s):  
Anionic Surfactant ◽  
Cationic Polyelectrolyte

Regularities of the Two-Layer Adsorption of Anionic Surfactant and Cationic Polyelectrolyte on the Fused Quartz Surface

2005 ◽  
Vol 67 (4) ◽  
pp. 520-521 ◽  
Author(s):  
I. P. Sergeeva ◽  
T. B. Ermakova ◽  
A. D. Anuchkina ◽  
V. D. Sobolev ◽  
N. V. Churaev
Keyword(s):  
Anionic Surfactant ◽  
Cationic Polyelectrolyte ◽  
Quartz Surface ◽  
Layer Adsorption ◽  
Fused Quartz

Mixtures of Cationic Polyelectrolyte and Anionic Surfactant Studied with Small-Angle Neutron Scattering

2000 ◽  
Vol 104 (49) ◽  
pp. 11689-11694 ◽  
Author(s):  
Per M. Claesson ◽  
Magnus Bergström ◽  
Andra Dedinaite ◽  
Mikael Kjellin ◽  
Jean-Francois Legrand ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Anionic Surfactant ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Cationic Polyelectrolyte

A Small-Angle X-ray Scattering Study of Complexes Formed in Mixtures of a Cationic Polyelectrolyte and an Anionic Surfactant

2002 ◽  
Vol 106 (44) ◽  
pp. 11412-11419 ◽  
Author(s):  
Magnus Bergström ◽  
U. R. Mikael Kjellin ◽  
Per M. Claesson ◽  
Jan Skov Pedersen ◽  
Martin M. Nielsen
Keyword(s):  
Anionic Surfactant ◽  
Small Angle ◽  
Cationic Polyelectrolyte ◽  
X Ray ◽  
X Ray Scattering ◽  
Scattering Study ◽  
Ray Scattering

Direct Measurement of Charge Reversal on Lipid Bilayers using Heterodyne-Detected Second Harmonic Generation Spectroscopy

2019 ◽  
Author(s):  
HanByul Chang ◽  
Paul Ohno ◽  
Yangdongling Liu ◽  
Franz Geiger
Keyword(s):  
Lipid Bilayers ◽  
Surface Potential ◽  
Second Harmonic ◽  
Fluid Phase ◽  
Cationic Polyelectrolyte ◽  
Charge Reversal ◽  
Buried Interfaces ◽  
Phase Transition Temperatures ◽  
Complementary Techniques ◽  
Order Susceptibility

We report the detection of charge reversal induced by the adsorption of a cationic polyelectrolyte, poly(allylamine) hydrochloride (PAH), to buried supported lipid bilayers (SLBs), used as idealized model biological membranes. We observe changes in the surface potential in isolation from other contributors to the total SHG response by extracting the phase-shifted potential-dependent third-order susceptibility from the overall SHG signal. We demonstrate the utility of this technique in detecting both the sign of the surface potential and the point of charge reversal at buried interfaces without any prior information or complementary techniques<i>.</i>Furthermore, isolation of the second-order susceptibility contribution from the overall SHG response allows us to directly monitor changes in the Stern Layer. Finally, we characterize the Stern and Diffuse Layers over single-component SLBs formed from three different zwitterionic lipids of different gel-to-fluid phase transition temperatures (T<sub>m</sub>s). We determine whether the surface potential changes with the physical phase state (gel, transitioning, or fluid) of the SLB and incorporate 20 percent of negatively charged lipids to the zwitterionic SLB to investigate how the surface potential changes with surface charge.

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