Synthesis and properties of novel amphiphilic sulfated ionomers by the ring-opening reaction of an epoxidized styrene–butadiene–styrene triblock copolymer

2007 ◽  
Vol 107 (4) ◽  
pp. 2681-2688 ◽  
Author(s):  
Hong-Quan Xie ◽  
Wei Zhao ◽  
Wei Yang ◽  
Dong Xie
Keyword(s):  
Ring Opening ◽  
Triblock Copolymer ◽  
Ring Opening Reaction ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Compatibility and Storage Stability of Asphalt Binder Modified by Styrene-Butadiene-Styrene (SBS) Graft Copolymer

2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  
Keyword(s):  
Triblock Copolymer ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Solubility Parameters ◽  
Suitable Alternative ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.

Rheology of Styrene‐Butadiene‐Styrene Triblock Copolymer in n‐Tetradecane Systems

1984 ◽  
Vol 28 (4) ◽  
pp. 393-409 ◽  
Author(s):  
Hiroshi Watanabe ◽  
Souichiro Kuwahara ◽  
Tadao Kotaka
Keyword(s):  
Triblock Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Photoinitiator grafted styrene–butadiene–styrene triblock copolymer

2010 ◽  
Vol 30 (7) ◽  
pp. 1030-1037 ◽  
Author(s):  
Guoliang Wu ◽  
Songjun Zeng ◽  
Encai Ou ◽  
Puren Yu ◽  
Yanbing Lu ◽  
...  
Keyword(s):  
Triblock Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene
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