Nonisothermal crystallization kinetics of poly(vinylidene fluoride) in a poly(vinylidene fluoride)/dibutyl phthalate/di(2-ethylhexyl)phthalate system via thermally induced phase separation

2007 ◽  
Vol 107 (4) ◽  
pp. 2109-2117 ◽  
Author(s):  
Gen-Liang Ji ◽  
Bao-Ku Zhu ◽  
Chun-Fang Zhang ◽  
You-Yi Xu
Keyword(s):  
Phase Separation ◽  
Dibutyl Phthalate ◽  
Vinylidene Fluoride ◽  
Thermally Induced Phase Separation ◽  
Nonisothermal Crystallization ◽  
Thermally Induced ◽  
Poly Vinylidene Fluoride ◽  
Nonisothermal Crystallization Kinetics ◽  
Ethylhexyl Phthalate ◽  
Kinetics Of

Nonisothermal Crystallization Behavior of Poly(vinylidenefluoride)/Polysulfone/Diethylene Glycol Dibenzoate/Dibutyl Phthalate System via Thermally Induced Phase Separation

2015 ◽  
Vol 1120-1121 ◽  
pp. 581-585
Author(s):  
Jing Zhang ◽  
Lu Qi ◽  
Zhen Yu Cui
Keyword(s):  
Phase Separation ◽  
Diethylene Glycol ◽  
Crystallization Behavior ◽  
Dibutyl Phthalate ◽  
Vinylidene Fluoride ◽  
Thermally Induced Phase Separation ◽  
Scanning Calorimetry ◽  
Nonisothermal Crystallization ◽  
Thermally Induced ◽  
Poly Vinylidene Fluoride

Differential scanning calorimetry (DSC) measurement is used to investigate the nonisothermal crystallization behavior of poly (vinylidene fluoride) (PVDF)/polysulfone (PSF)/diethylene glycol dibenzoate (DEDB)/dibutyl phthalate (DBP) system via solid-liquid (S-L) phase separation during a thermally induced phase separation process. The effect of benzene ring in PSF on PVDF crystallization for PVDF/PSF/DEDB/DBP system is investigated. It is found that the Ozawa model can describe nonisothermal crystallization behavior of PVDF/PSF/DEDB/DBP system in a certain crystallization temperature range. Jeziorny method indicates that the secondary crystallization of PVDF exists in the process of nonisothermal crystallization and is enhanced by the increase of cooling rate.

Investigation of Formation for Poly(vinylidene fluoride) Membrane Using Thermally Induced Phase Separation

2020 ◽  
Vol 20 (11) ◽  
pp. 7140-7144
Author(s):  
Jeong Woo Lee ◽  
Kwang Seop Im ◽  
Sang Yong Nam
Keyword(s):  
Phase Separation ◽  
Dibutyl Phthalate ◽  
Vinylidene Fluoride ◽  
Weight Ratio ◽  
Porous Membrane ◽  
Silica Content ◽  
Dioctyl Phthalate ◽  
Thermally Induced Phase Separation ◽  
Thermally Induced ◽  
Poly Vinylidene Fluoride

In this study, thermally induced phase separation (TIPS) was used to fabricate a water treatment membrane composed of poly(vinylidene fluoride) (PVDF) and silica. Dioctyl phthalate (DOP) and dibutyl phthalate (DBP) were used as diluents. Crystallization temperature, cloud point, and morphology were observed to investigate the conditions of PVDF/silica/diluent membrane preparation. SEM revealed that the porosity of the membranes was increased with an increase in silica content. Phase diagram and morphology results revealed that 50 wt% PVDF+silica with a PVDF:silica weight ratio of 4.5:1 is the best composition for manufacturing a porous membrane.

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