Effect of the variation in the weight percentage of the loading and the reduction in the nanosizes of CaSO4 on the mechanical and thermal properties of styrene–butadiene rubber

2007 ◽  
Vol 104 (3) ◽  
pp. 2018-2026 ◽  
Author(s):  
S. Mishra ◽  
N. G. Shimpi
2015 ◽  
Vol 44 (2) ◽  
pp. 57-73 ◽  
Author(s):  
Salwa H El-Sabbagh ◽  
Nivin M. Ahmed

Purpose – This paper aims to express in detail the rheological, morphological and thermal properties of unpigmented and pigmented styrene-butadiene rubber composites with new prepared inorganic pigment based on kaolin covered with a thin layer of calcium and magnesium oxides or mixed oxide of both together. These new pigments combine the properties of both their constituents (kaolin and metal oxides), which are a new trend in inorganic pigments called core-shell pigments. The pigments used for comparison are kaolin (K), CaO/kaolin (CaO/K), MgO/kaolin (MgO/K) and CaO.MgO/kaolin (CaO.MgO/K). Design/methodology/approach – The different pigments were characterized using different analytical and spectrophotometric techniques, such as X-ray diffraction, scanning electron microscopy/energy dispersive X-ray and transmission electron microscopy, while rubber vulcanizates' rheological, morphological, swelling and thermal properties were examined using different standard and instrumental testing and methods. Findings – The study revealed that there is a significant effect of the new prepared pigments on SBR properties, where the optimum pigment loading was 40 phr for CaO/kaolin, while it was 2.5 phr for MgO/kaolin. Studying the effect of different ratios of oxides on kaolin (5, 10 and 20 per cent), different loadings of these pigments ranging between 2.5 and 40 phr were done for each pigment. These modified kaolin or core-shell metal oxide/kaolin pigments imparted new and improved reinforcing properties to SBR vulcanizates. Research limitations/implications – No research limitations were found. Practical implications – Core-shell MgO/kaolin pigments are eco-friendly and can replace other expensive pigments that are usually used as fillers in the rubber industry with less expenses and comparable efficiency. Originality/value – These new pigments are cheap and efficient and can be used in different fields other than rubber.


2016 ◽  
Vol 717 ◽  
pp. 57-61
Author(s):  
Wei Liu ◽  
Zhong Cun Bao ◽  
Cheng Zhong Zong

Flexible fatigue properties is an important property of rubber, it can reflect the service life of rubber products. Different types of SSBR were used in the vulcanized rubber with NR contributed different to the flexible fatigue properties. In this paper, 5 different types of SSBR with special structure were used to study the mechanical properties, thermal properties and the flexible fatigue properties. In a result, with different types SSBR, the vulcanized rubber show different basic mechanical properties and flexible fatigue properties, but little effect to the hardness and stretching stress. Above all these SSBR, RC2564S is the best which contribute to flexible fatigue properties.


Sign in / Sign up

Export Citation Format

Share Document