Kinetics of sulfur vulcanization of 1,4-cis-polyisoprene by differential scanning calorimetry

2007 ◽  
Vol 104 (2) ◽  
pp. 754-757 ◽  
Author(s):  
N. N. Kolesnikova ◽  
O. A. Ostroukhova ◽  
A. A. Popov
Keyword(s):  
Differential Scanning Calorimetry ◽  
Scanning Calorimetry ◽  
Sulfur Vulcanization ◽  
Kinetics Of

Molecular Dynamics and Kinetics of Isothermal Cold Crystallization in the Chiral Smectogenic 3F7HPhH6 Glassformer

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1487
Author(s):  
Aleksandra Deptuch ◽  
Małgorzata Jasiurkowska-Delaporte ◽  
Ewa Juszyńska-Gałązka ◽  
Anna Drzewicz ◽  
Wojciech Zając ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Optical Microscopy ◽  
Dielectric Spectroscopy ◽  
Cold Crystallization ◽  
Scanning Calorimetry ◽  
Broadband Dielectric Spectroscopy ◽  
Smectic C ◽  
Dimension Analysis ◽  
Fractal Dimension Analysis ◽  
Kinetics Of

An investigation of the glass transition of the antiferroelectric smectic C*A phase and cold crystallization of (S)-4’-(1-methylheptylcarbonyl)biphenyl-4-yl 4-[7-(2,2,3,3,4,4,4-heptafluoro- butoxy)heptyl-1-oxy]benzoate (denoted as 3F7HPhH6) by differential scanning calorimetry, polarizing optical microscopy and broadband dielectric spectroscopy is presented. The fragility index mf = 72, classifying 3F7HPhH6 as a glassformer with intermediate fragility, was obtained from the temperature dependence of the α-process relaxation time, measured upon cooling. Duplication of the α-process was observed exclusively upon heating, before the onset of cold crystallization, and is connected with the pre-transitional effect. The presence of two crystal phases likely influences the kinetics of cold crystallization; the idea stems from a comparison with previous results for the 3F7HPhF6 and 3F7HPhH7 compounds. Additionally, the presence of the smectic C*α; sub-phase in a narrow temperature range was proved based on the differential scanning calorimetry and broadband dielectric spectroscopy results, as well as the fractal dimension analysis of the textures obtained by polarizing optical microscopy.

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