Durability of wood flour-plastic composites exposed to accelerated freeze–thaw cycling. II. High density polyethylene matrix

2006 ◽  
Vol 100 (1) ◽  
pp. 35-39 ◽  
Author(s):  
Jeanette M. Pilarski ◽  
Laurent M. Matuana
Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 236
Author(s):  
Wanyu Liu ◽  
Yue Li ◽  
Shunmin Yi ◽  
Limin Wang ◽  
Haigang Wang ◽  
...  

To expand the use of wood plastic composites in the structural and engineering constructions applications, continuous aramid fiber (CAF) with nondestructive modification was incorporated as reinforcement material into wood-flour and high-density-polyethylene composites (WPC) by extrusion method with a special die. CAF was treated with dopamine (DPA), vinyl triethoxysilane (VTES), and DPA/VTES, respectively. The effects of these modifications on compatibility between CAF and WPCs and the properties of the resulting composites were explored. The results showed that compared with the original CAF, the adhesion strength of DPA and VTES combined modified CAF and WPCs increased by 143%. Meanwhile, compared with pure WPCs, CAF after modification increased the tensile strength, tensile modulus, and impact strength of the resulting composites by 198, 92, and 283%, respectively.


BioResources ◽  
2020 ◽  
Vol 15 (1) ◽  
pp. 1233-1251
Author(s):  
Jafar Ghaje Beigloo ◽  
Habibollah Khademi Eslam ◽  
Amir Hooman Hemmasi ◽  
Behzad Bazyar ◽  
Ismaeil Ghasemi

The effect of nanographene amount was evaluated relative to the physical, mechanical, thermal, and morphological features of wood-plastic composites. Composites were prepared using recycled polyethylene (high-density polyethylene), nanographene, and wood-flour. The amount of 80% of polymer matrix and 20% of wood flour, and nanographene at four weight levels of 0.5%, 1.5%, and 2.5%, were used. An internal mixture was utilized for making the samples. The results showed that with the 0.5 wt% increase of the amount of nanographene, the tensile and flexural strengths, the flexural and tensile modulus and the notched impact strength composite increased. With the addition of 2.5 wt% nanographene, these properties decreased. With the increase of the level of nanographene by 2.5 wt%, water absorption and the thickness swelling of the composite decreased. With the increase of the level of nanographene, the level of residue ash and thermal stability also increased. Scanning electron microscope images showed that the samples with 0.5 wt% nanographene had less holes and a smoother surface compared to the other samples.


Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4462
Author(s):  
Maria del Carmen Morcillo ◽  
Ramón Tejada ◽  
Diego Lascano ◽  
Daniel Garcia-Garcia ◽  
David Garcia-Sanoguera

The use of wood plastic composites (WPC) is growing very rapidly in recent years, in addition, the use of plastics of renewable origin is increasingly implemented because it allows to reduce the carbon footprint. In this context, this work reports on the development of composites of bio-based high density polyethylene (BioHDPE) with different contents of pinecone (5, 10, and 30 wt.%). The blends were produced by extrusion and injection-molded processes. With the objective of improving the properties of the materials, a compatibilizer has been used, namely polyethylene grafted with maleic anhydride (PE-g-MA 2 phr). The effect of the compatibilizer in the blend with 5 wt.% has been compared with the same blend without compatibilization. Mechanical, thermal, morphological, colorimetric, and wettability properties have been analyzed for each blend. The results showed that the compatibilizer improved the filler–matrix interaction, increasing the ductile mechanical properties in terms of elongation and tensile strength. Regarding thermal properties, the compatibilizer increased thermal stability and improved the behavior of the materials against moisture. In general, the pinecone materials obtained exhibited reddish-brown colors, allowing their use as wood plastic composites with a wide range of properties depending on the filler content in the blend.


2017 ◽  
Vol 267 ◽  
pp. 76-81 ◽  
Author(s):  
Janis Kajaks ◽  
Karlis Kalnins ◽  
Anita Zagorska ◽  
Juris Matvejs

One type of birch wood plywood by-product: plywood sanding dust (PSD) and recycled high density polyethylene (rHDPE) composites physical mechanical properties (tensile, flexural strength and modulus, impact strength and microhardness), water resistance and fluidity of the composite melts, were evaluated. These studies showed the possibility of the usage of presented by-product as an excellent reinforcement for recycled high density polyethylene matrix. It was observed that the modulus of the tensile for unmodified rHDPE+PSD composites increased up to 2.3 times, the modulus of flexural till 4 times, but the microhardness only 1.4 times. Optimal content of the PSD in recycled high density polyethylene composites could be 50 wt. %. As a coupling agent, the maleated polyethylene (MAPE) for modifying of the rHDPE+50 wt. % PSD composite was used. Due to the MAPE additives, the improvement (30-50 %) of the investigated exploitation properties was observed, but in comparison with unmodified composites the resistance of water increased up to 3.0 times. Optimal content of MAPE in rHDPE+50 wt. % PSD composition could be 3 wt.%.


2016 ◽  
Vol 51 (7) ◽  
pp. 955-964
Author(s):  
Yunsheng Ding ◽  
Guozhang Ni ◽  
Pei Xu ◽  
Bahader Ali ◽  
Shanzhong Yang

Wood–plastic composites were prepared from poplar wood flour and high-density polyethylene (HDPE) by melt blending and injection molding techniques, using polyethylene-grafted glycidylmethacrylate (HDPE- g-GMA) as compatibilizer and γ-aminopropyltriethoxysilane as coupling agent. The scanning electron microscopy results showed that a stronger interfacial adhesion was formed between the wood flour and HDPE matrices during the combined use of γ-aminopropyltriethoxysilane and HDPE- g-GMA, while the X-ray photoelectron spectroscopy results showed that more HDPE chains are linked to the surface of poplar wood flour through the formation of chemical bonding in the presence of γ-aminopropyltriethoxysilane and HDPE- g-GMA. So, HDPE- g-GMA and γ-aminopropyltriethoxysilane showed a synergistic effect on the improvement of compatibility between the poplar wood flour and HDPE matrices and better mechanical properties of wood–plastic composites could be obtained. Furthermore, the thermogravimetric analysis results also indicated the synergistic effects to some extent. The synergistic mechanism of γ-aminopropyltriethoxysilane and HDPE- g-GMA was proposed on the basis of investigation results.


2003 ◽  
Vol 774 ◽  
Author(s):  
Susan M. Rea ◽  
Serena M. Best ◽  
William Bonfield

AbstractHAPEXTM (40 vol% hydroxyapatite in a high-density polyethylene matrix) and AWPEX (40 vol% apatite-wollastonite glass ceramic in a high density polyethylene matrix) are composites designed to provide bioactivity and to match the mechanical properties of human cortical bone. HAPEXTM has had clinical success in middle ear and orbital implants, and there is great potential for further orthopaedic applications of these materials. However, more detailed in vitro investigations must be performed to better understand the biological interactions of the composites and so the bioactivity of each material was assessed in this study. Specifically, the effects of controlled surface topography and ceramic filler composition on apatite layer formation in acellular simulated body fluid (SBF) with ion concentration similar to those of human blood plasma were examined. Samples were prepared as 1 cm × 1 cm × 1 mm tiles with polished, roughened, or parallel-grooved surface finishes, and were incubated in 20 ml of SBF at 36.5 °C for 1, 3, 7, or 14 days. The formation of a biologically active apatite layer on the composite surface after immersion was demonstrated by thin-film x-ray diffraction (TF-XRD), environmental scanning electron microscopy (ESEM) imaging and energy dispersive x-ray (EDX) analysis. Variations in sample weight and solution pH over the period of incubation were also recorded. Significant differences were found between the two materials tested, with greater bioactivity in AWPEX than HAPEXTM overall. Results also indicate that within each material the surface topography is highly important, with rougher samples correlated to earlier apatite formation.


2013 ◽  
Vol 34 (1) ◽  
pp. 39-54 ◽  
Author(s):  
Ljerka Kratofil Krehula ◽  
Zvonimir Katančić ◽  
Anita Ptiček Siročić ◽  
Zlata Hrnjak-Murgić

2015 ◽  
Vol 16 (1) ◽  
pp. 129-137 ◽  
Author(s):  
M. E. Ali Mohsin ◽  
Agus Arsad ◽  
Syed K. H. Gulrez ◽  
Zurina Muhamad ◽  
H. Fouad ◽  
...  

2019 ◽  
Vol 69 (4) ◽  
pp. 313-321
Author(s):  
Xiaoxia Hu ◽  
Zhenghao Chen ◽  
Yang Cao ◽  
Zhangjing Chen ◽  
Shuangbao Zhang ◽  
...  

Abstract The focus of this study was to observe the properties of bamboo plastic composites modified with a self-made modifier, 18 acyl-dopamine (0, 0.25, 0.50, 0.75, 1.00, and 1.25 weight percent [wt%] based on the dry weight of bamboo powder). The effects of the modifier were demonstrated by measures of mechanical properties, water absorption, thermal stability, and scanning electron microscopy (SEM). The results revealed that 18 acyl-dopamine could be used as an effective modifier of bamboo powder/high-density polyethylene composites. When the modifier was increased, the toughness of the composite deteriorated, and the strength and rigidity improved. This indicated that when the dosage became higher, the compatibilization became stronger, and the toughening effect became worse. Based on the experimental data, a small dosage modifier acted as a toughening agent; as the dosage increased to 1.0 wt%, the compatibility began to appear. The modifier reacted with the hydroxyl groups on the surface of the bamboo powder, which caused the bamboo powder to absorb less water, so the thickness expansion rate was lowest at 1.25 wt%. The pyrolysis peak of bamboo powder and plastic showed a tendency to be close to each other, indicating that the interface was improving. Based on the equation of Flynn-Wall-Ozawa, as the dosage of the modifier increased from 0.50 to 1.25 wt%, the apparent activation energy also increased. The SEM analysis showed the binding between bamboo powder and the plastic matrix was strongest when the modifier dosage was 1.25 wt%.


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