Thin, highly crosslinked polymer layer synthesized via photoinitiated graft copolymerization on a self-assembled-monolayer-coated gold surface

2005 ◽  
Vol 97 (1) ◽  
pp. 158-164 ◽  
Author(s):  
Hu Yang ◽  
Dimitrios Lazos ◽  
Mathias Ulbricht
Keyword(s):  
Graft Copolymerization ◽  
Gold Surface ◽  
Polymer Layer ◽  
Self Assembled Monolayer ◽  
Crosslinked Polymer ◽  
Self Assembled

scholarly journals Formation of HCN+ in collisions of N+ and N2+ with a self-assembled propanethiol surface on gold

2021 ◽  
Author(s):  
Faro Hechenberger ◽  
Siegfried Kollotzek ◽  
Lorenz Ballauf ◽  
Felix Duensing ◽  
Milan Ončák ◽  
...  
Keyword(s):  
Energy Range ◽  
Incident Energy ◽  
Gold Surface ◽  
Self Assembled Monolayer ◽  
Polycrystalline Gold ◽  
Self Assembled

Collisions of N+ and N2+ with C3 hydrocarbons, represented by a self assembled monolayer of propanethiol on a polycrystalline gold surface, were investigated by experiments over the incident energy range between 5 eV and 100 eV.

Spectral and cyclic voltammetric characterization of self-assembled monolayers on gold of pyrene end-labeled oligonucleotide duplexes

1999 ◽  
Vol 77 (5-6) ◽  
pp. 1077-1084 ◽  
Author(s):  
R Scott Reese ◽  
Marye Anne Fox
Keyword(s):  
Gold Surface ◽  
Self Assembled Monolayers ◽  
Self Assembled Monolayer ◽  
Surface Emission ◽  
Assembled Monolayers ◽  
Oligonucleotide Duplex ◽  
Self Assembled ◽  
Duplex Formation

Self-assembled monolayers of sulfur-terminated oligonucleotide duplexes were formed on flat gold surfaces, either by exposure of a self-assembled monolayer bearing one oligonucleotide strand to the complementary strand or by preformation of a oligonucleotide duplex that was then deposited on a fresh gold surface. Virtually identical spectral behavior was observed whether the duplex was produced before deposition or by in situ complementary association. With a duplex bearing an appropriate pyrene end-label, the resulting thin film was photoresponsive. Surface emission measurements show no evidence for pyrene aggregation on the modified surfaces. The polarity of the photocurrent, reflecting photoinduced electron transfer initiated by photoexcitation of pyrene, is opposite that expected from the oligonucleotide-mediated reduction of the appended pyrene excited state.Key words: oligonucleotide, self-assembled monolayer, duplex formation, photoelectrochemistry, surface emission.

Specific Immobilization of Streptavidin on Mixed Self-Assembled Monolayers as Mixing Ratio

2007 ◽  
Vol 121-123 ◽  
pp. 495-498 ◽  
Author(s):  
Jun Hyung Park ◽  
Buyng Su Park ◽  
Gu Huh ◽  
Seung Hyun Lee ◽  
Hyun Sook Lee ◽  
...  
Keyword(s):  
Colorimetric Detection ◽  
Gold Surface ◽  
Self Assembled Monolayers ◽  
Scanning Tunneling ◽  
Local Domain ◽  
Mixing Ratio ◽  
Tunneling Microscopy ◽  
Self Assembled Monolayer ◽  
Assembled Monolayers ◽  
Self Assembled

We report on the distribution of mixed self-assembled monolayers (SAMs) composed of biotinylated and diluent alkylthiolates for streptavidin immobilization. Two thiol derivatives, 11-mercapto-1-undecanol (MUOH) and 11-mercaptoundecanoic-(8-biotinylamido-3,6-dioxaoctyl) amide (MBDA), were employed for mixed SAM. These thiols formed self-assembled monolayer without local domain, and streptavidins were immobilized onto biotinylated gold surface without nonspecific binding. In order to find the optimized condition of immobilization of streptavidin, we controlled the mixing ratio of two kind thiols by colorimetric detection assay, and the immobilization was characterized by atomic force microscopy (AFM), scanning tunneling microscopy (STM), and ellipsometer.

Selective detection of estradiol using a molecularly imprinted self-assembled monolayer on gold surface

2009 ◽  
Vol 1 (2) ◽  
pp. 117-121 ◽  
Author(s):  
Eunjoo Kim ◽  
Sung Jun Lee ◽  
Hyun-Chul Kim ◽  
Se Geun Lee ◽  
Tae-Jung Go ◽  
...  
Keyword(s):  
Gold Surface ◽  
Selective Detection ◽  
Self Assembled Monolayer ◽  
Molecularly Imprinted ◽  
Self Assembled

THE ELECTROCHEMICAL STUDIES ON A SELF-ASSEMBLED VIOLOGEN MONOLAYER USING QUARTZ CRYSTAL MICROBALANCE

2002 ◽  
Vol 01 (05n06) ◽  
pp. 593-596 ◽  
Author(s):  
J. Y. OCK ◽  
H. K. SHIN ◽  
Y. S. KWON ◽  
S. H. SONG ◽  
S. M. CHANG ◽  
...  
Keyword(s):  
Self Assembly ◽  
Quartz Crystal ◽  
Surface Coverage ◽  
Gold Surface ◽  
Frequency Change ◽  
Self Assembled Monolayer ◽  
Solution Interface ◽  
Reversible Redox ◽  
Mass Detector ◽  
Self Assembled

The electrochemical behavior of viologen self-assembled monolayer has been investigated with QCM, which has been known as ng order mass detector. The self-assembly process of viologen was monitored using resonant frequency (ΔF) and resonant resistance (R). The QCM measurements indicated a mass adsorption for viologen assembling on the gold surface with a frequency change of about 300, 135 Hz and its surface coverage (Γ) was calculated to be 5.02 × 10-9 and 1.64 × 10-9 mol/cm2. A reversible redox process was also observed and analyzed with an ionic interaction at the viologen/solution interface using ΔF.

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