Preparation and characterization of polypropylene-montmorillonite nanocomposites generated byin situ metallocene catalyst polymerization

2005 ◽  
Vol 95 (5) ◽  
pp. 1228-1236 ◽  
Author(s):  
Jyh-Ming Hwu ◽  
George-J Jiang
Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2091
Author(s):  
Daniela Mileva ◽  
Jingbo Wang ◽  
René Androsch ◽  
Katalee Jariyavidyanont ◽  
Markus Gahleitner ◽  
...  

Propylene-based random copolymers with either ethylene or 1-hexene as comonomer, produced using a metallocene catalyst, were studied regarding their crystallization behaviors, with a focus on rapid cooling. To get an impression of processing effects, fast scanning chip calorimetry (FSC) was used in addition to the characterization of the mechanical performance. When comparing the comonomer type and the relation to commercial grades based on Ziegler–Natta-type catalysts, both an interaction with the catalyst-related regio-defects and a significant difference between ethylene and 1-hexene was observed. A soluble-type nucleating agent was found to modify the behavior, but to an increasingly lesser degree at high cooling rates.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Amal Amin ◽  
Moshera Samy

Different polyesteramides hyperbranched polymers (HPEA1-6)/montomorillonite clay (MMT) nanocomposites were prepared with three different loading contents of clay (4, 10, and 15 wt%). The obtained nanocomposites were characterized via XRD, thermal analyses, and TEM. Generally, intercalation behavior was observed. The hyperbranched polyesteramides (HPEA1-6) were originally prepared by the bulky reaction between maleic anhydride (MAn), succinic anhydride (ScAn), and phthalic anhydride (PhAn) with either diethanolamine (DEA) or diisopropanolamine (DiPA). The resulting hyperbranched polyesteramides (HPEA1-6) were characterized by GPC, IR,1H-NMR, TGA, and DSC.


2006 ◽  
Vol 55 (5) ◽  
pp. 500-504 ◽  
Author(s):  
Qingjun Ding ◽  
Baolei Liu ◽  
Qiang Zhang ◽  
Qihui He ◽  
Baixing Hu ◽  
...  

2003 ◽  
Vol 39 (8) ◽  
pp. 1641-1646 ◽  
Author(s):  
Bing Han ◽  
Gending Ji ◽  
Shishan Wu ◽  
Jian Shen

2015 ◽  
Vol 37 (8) ◽  
pp. 2396-2403 ◽  
Author(s):  
Shiwei Chen ◽  
Xuchen Lu ◽  
Zhimin Zhang ◽  
Tizhuang Wang ◽  
Feng Pan

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