Evaluation of physical and dielectric properties of chloroprene and styrene butadiene rubber blends

2005 ◽  
Vol 96 (5) ◽  
pp. 1492-1504 ◽  
Author(s):  
Amit Das ◽  
Dipak Kumar Basu
Keyword(s):  
Dielectric Properties ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Blends ◽  
Styrene Butadiene

Characterization of Sulfur-Cured Styrene-Butadiene Copolymer Rubbers and Their Polybutadiene Blends

1970 ◽  
Vol 43 (6) ◽  
pp. 1332-1339 ◽  
Author(s):  
J. K. Clark ◽  
R. A. Scott
Keyword(s):  
Carbon Disulfide ◽  
High Speed ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Absorption Bands ◽  
Rubber Blends ◽  
Cast Films ◽  
Micro Structures ◽  
Styrene Butadiene

Abstract Dissolution of sulfur-cured, carbon black-loaded copolymers and their blends with cis-1,4-polybutadiene (PBD) are brought about by boiling with o-dichlorobenzene which contains a small amount of 2,2′-dibenzamidodiphenyl disulfide. The resulting slurries are subjected to a sequence of separations which include high-speed centrifugation to remove solids, and solvent precipitation followed by filtration to isolate the precipitates. The precipitates are washed with solvent to remove soluble organic materials followed by carbon disulfide washing to dissolve the polymers. Cast films of the polymers are obtained by evaporating the carbon disulfide washings onto sodium chloride discs. The infrared spectra of the cast films of these preparations are very similar to those of their respective polymers prior to loading and curing. Calculations for relative concentrations of bound styrene and PBD micro-structures permit nominal identification of the kinds of styrene-butadiene rubber and the amounts of cis-1,4-PBD used in a cured rubber formulation. Absorption bands used are near 3.35 μ for cis-1,4-PBD, 6.65 μ for bound styrene, 10.35 μ for trans-1,4-PBD; and 11.0 μ for vinyl-1,2-PBD. Efforts are being made to improve the data by using a grating infrared instrument and also to extend the calibrations to include other rubber blends.

Novel modification of styrene butadiene rubber/acrylic rubber blends to improve mechanical, dynamic mechanical, and swelling behavior for oil sealing applications

2021 ◽  
pp. 096739112110313
Author(s):  
Ahmed Abdel-Hakim ◽  
Soma A el-Mogy ◽  
Ahmed I Abou-Kandil
Keyword(s):  
Mechanical Properties ◽  
Crosslink Density ◽  
Physical And Mechanical Properties ◽  
Dynamic Mechanical Properties ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Blends ◽  
Dynamic Mechanical ◽  
Oil Resistance ◽  
Styrene Butadiene

Blending of rubber is an important route to modify properties of individual elastomeric components in order to obtain optimum chemical, physical, and mechanical properties. In this study, a novel modification of styrene butadiene rubber (SBR) is made by employing acrylic rubber (ACM) to obtain blends of outstanding mechanical, dynamic, and oil resistance properties. In order to achieve those properties, we used a unique vulcanizing system that improves the crosslink density between both polymers and enhances the dynamic mechanical properties as well as its resistance to both motor and break oils. Static mechanical measurements, tensile strength, elongation at break, and hardness are improved together with dynamic mechanical properties investigated using dynamic mechanical analyses. We also proposed a mechanism for the improvement of crosslink density and consequently oil resistance properties. This opens new opportunities for using SBR/ACM blends in oil sealing applications that requires rigorous mechanical and dynamic mechanical properties.

Dielectric Properties of Styrene—Butadiene Rubber/Silicon Dioxide Mixtures

1973 ◽  
Vol 5 (2) ◽  
pp. 83-90 ◽  
Author(s):  
Faika F. Hanna ◽  
Abbas A. Yehia ◽  
Abdel-Fattah Abou-Bakr
Keyword(s):  
Dielectric Properties ◽  
Silicon Dioxide ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Styrene Butadiene

Dynamic Mechanical and Dielectric Properties of Nanocomposites of Natural Rubber (NR), Carboxylated Styrene Butadiene Rubber (XSBR) Latices and their Blends

2007 ◽  
Vol 80 (4) ◽  
pp. 672-689 ◽  
Author(s):  
Ranimol Stephen ◽  
Sabu Thomas ◽  
K. V. S. N. Raju ◽  
Siby Varghese ◽  
Kuruvilla Joseph ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
Dielectric Permittivity ◽  
Natural Rubber ◽  
Storage Modulus ◽  
Viscoelastic Properties ◽  
Volume Resistivity ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Carboxylated Styrene Butadiene Rubber ◽  
Styrene Butadiene

Abstract The viscoelastic and dielectric properties of nano structured layered silicates reinforced natural rubber (NR), carboxylated styrene butadiene rubber (XSBR) and their blends have been analyzed. The viscoelastic properties such as storage modulus, loss modulus, damping behavior and glass transition temperature of nano filled latices have been investigated. Upon the addition of filler, the storage modulus of nanocomposites was found to increase due to the enhancement in stiffness of the material. Due to the restricted mobility of polymer chain segments, the damping values decreased as a function of filler loading. An investigation of the viscoelastic properties revealed that there was a strong interaction between the polymer and the filler. Latex nanocomposites was characterized by X-ray diffraction technique. The enhanced d values indicated the intercalation of polymer chain into the layers of silicates. The dielectric properties of nanocomposites have been investigated as a function of frequency in the range of 50Hz–100KHz. The effect of frequency on dielectric permittivity (Ε′), dielectric loss (Ε″), dissipation factor (tan δ) and volume resistivity (ρv) of latex nanocomposite have been measured under alternating current. The dielectric permittivity of the samples was found to be higher upon the incorporation of nano fillers. The volume resistivity decreased due to the enhanced conductivity of filled samples.

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