Ultrasonically irradiated emulsion polymerization of styrene in the presence of a polymeric surfactant

2004 ◽  
Vol 94 (2) ◽  
pp. 763-768 ◽  
Author(s):  
Jingzhi Zhang ◽  
Ya Cao ◽  
Yuhui He
Keyword(s):  
Emulsion Polymerization ◽  
Polymeric Surfactant

Emulsion polymerization of styrene using mixtures of hydrophobically modified inulin (polyfructose) polymeric surfactant and nonionic surfactants

2008 ◽  
Vol 108 (2) ◽  
pp. 811-815 ◽  
Author(s):  
Jérémie Nestor ◽  
Jordi Esquena ◽  
Conxita Solans ◽  
Bart Levecke ◽  
Karl Booten ◽  
...  
Keyword(s):  
Emulsion Polymerization ◽  
Nonionic Surfactants ◽  
Polymeric Surfactant ◽  
Hydrophobically Modified

Preparation of a New Polymeric Surfactant for Emulsion Polymerization

2006 ◽  
Vol 239 (1) ◽  
pp. 43-50 ◽  
Author(s):  
Ayfer Sarac ◽  
B. Filiz Senkal ◽  
Erdem Yavuz ◽  
Yesim Hepuzer Gürsel
Keyword(s):  
Emulsion Polymerization ◽  
Polymeric Surfactant

Random Copolymer as Polymeric Surfactant in Seed Emulsion Polymerization

2015 ◽  
Vol 52 (4) ◽  
pp. 323-328
Author(s):  
Xiuhua Yan ◽  
Wei Xu ◽  
Rong Shao ◽  
Lanqin Tang ◽  
Wenyan Shi
Keyword(s):  
Emulsion Polymerization ◽  
Random Copolymer ◽  
Polymeric Surfactant ◽  
Seed Emulsion Polymerization

scholarly journals Kinetic investigation of styrene emulsion polymerization with surface-active polyelectrolytes as emulsifier, 1 Kinetic study

e-Polymers ◽  
2005 ◽  
Vol 5 (1) ◽  
Author(s):  
Satoshi Kato ◽  
Kiyoshi Suzuki ◽  
Mamoru Nomura
Keyword(s):  
Emulsion Polymerization ◽  
Sodium Dodecyl ◽  
Monomer Concentration ◽  
Potassium Persulfate ◽  
Polymeric Surfactant ◽  
Emulsion Copolymerization ◽  
Rate Of Polymerization ◽  
Initial Monomer ◽  
Polymeric Emulsifier ◽  
Surface Active

AbstractA copolymer of methyl methacrylate and methacrylic acid to be used as a polymeric surfactant was synthesized by emulsifier-free semi-batch emulsion copolymerization. Emulsion polymerization of styrene was carried out at 50°C utilizing the ammonium salt of the copolymer as the polymeric emulsifier and potassium persulfate as the initiator, respectively. Both the number of polymer particles produced and the rate of polymerization were proportional to the 0.6 power of the initial emulsifier concentration, to the 0.4 power of the initial initiator concentration, and independent of the initial monomer concentration, respectively. These relationships are almost the same as those observed in the emulsion polymerization of styrene conducted using conventional surfactants like sodium dodecyl sulfate as the emulsifier and potassium persulfate as the initiator.

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