Application of a constitutive equation to polymer melts

1981 ◽  
Vol 26 (6) ◽  
pp. 1847-1863 ◽  
Author(s):  
Ramesh N. Shroff ◽  
Mitsuzo Shida
Keyword(s):  
Constitutive Equation ◽  
Polymer Melts

Viscosity Models Based on Network Theory for Polymer Melts

2010 ◽  
Vol 129-131 ◽  
pp. 1244-1247
Author(s):  
Hai Hang Xu ◽  
Lei Zhong
Keyword(s):  
Experimental Data ◽  
Kinetic Equation ◽  
Constitutive Equation ◽  
Polymer Composites ◽  
Network Theory ◽  
Polymer Melts ◽  
Structure Parameter ◽  
Viscosity Models ◽  
Model Predictions ◽  
Good Agreement

New shear and extensional viscosity models based on Fredrickson kinetic equation coupled with Dewitt constitutive equation were established to predict viscosities of polymer melts. The experimental data of 125°C LDPE and LDPE filled with 35% glass beads reported from references were compared with the model predictions. The predictions showed good agreement with the measurements. The models are simple and easy to use. Because they contain no structure parameter, they are capable to describe the viscosities of pure polymer and polymer composites.

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