The influence of molecular weight on the large deformation behavior of SBS triblock copolymer elastomers

1977 ◽  
Vol 21 (3) ◽  
pp. 629-643 ◽  
Author(s):  
Y.-D. M. Chen ◽  
R. E. Cohen
Keyword(s):  
Molecular Weight ◽  
Large Deformation ◽  
Deformation Behavior ◽  
Triblock Copolymer

Study on Constitutive Modeling for Large Deformation Behavior of Polyethylene Considering Strain Rate Effect

2013 ◽  
Author(s):  
Sijia Zhong ◽  
Jianfeng Shi ◽  
Jinyang Zheng
Keyword(s):  
Strain Rate ◽  
Large Deformation ◽  
Constitutive Modeling ◽  
Deformation Behavior ◽  
True Strain ◽  
True Stress ◽  
Uniaxial Tensile ◽  
Pipeline System ◽  
Composite Effect ◽  
Time Deformation

Polyethylene (PE) pipes have been applied in transportation of key energy medium such as natural gas in the past decades. The mechanical property of PE is of great importance for better design and safer application of PE pipeline system. The large deformation behavior is a key character of PE, not only for its significant strain rate sensitivity, but also for localized necking process after yielding. In this paper, a new constitutive modeling method was proposed to charaterize the rate-denpendent large deformation behavior of PE, in which the true stress is regarded as a function of true stain and true strain rate alone. Uniaxial tensile tests of PE were conducted under various cross-head speeds, and a digital camera was used to record the real-time deformation of specimens. By separating the composite effect into respective effect of local true strain and strain rate on the local true stress in the necking region, a phenomenological model for describing the rate-dependent deformation behavior under uniaxial tension was ealstablished. Model results were validated and found in good agreement with experimental data.

scholarly journals Hydrophilic Dual Layer Hollow Fiber Membranes for Ultrafiltration

Membranes ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 143
Author(s):  
Lara Grünig ◽  
Ulrich A. Handge ◽  
Joachim Koll ◽  
Oliver Gronwald ◽  
Martin Weber ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Hollow Fiber ◽  
Triblock Copolymer ◽  
Pure Water ◽  
Vinyl Pyrrolidone ◽  
Scattering Data ◽  
Coupling Mechanism ◽  
Additive Concentration ◽  
Hollow Fiber Membranes ◽  
Fiber Membranes

In this study, a triblock copolymer was used as additive to fabricate new dual layer hollow fiber membranes with a hydrophilic active inner surface in order to improve their fouling resistance. The polymeric components of the solutions for membrane fabrication were poly(ether sulfone), poly(N-vinyl pyrrolidone), and the triblock copolymer. The additive consists of three blocks: a middle hydrophobic poly(ether sulfone) block and two outer hydrophilic alkyl poly(ethylene glycol) blocks. By varying the additive concentration in the solutions, it was possible to fabricate dual layer hollow fiber membranes that are characterized by a hydrophilic inner layer, a pure water permeance of over 1800 L/(m2 bar h) and a molecular weight cut-off of 100 kDa similar to commercial membranes. Contact angle and composition determination by XPS measurements revealed the hydrophilic character of the membranes, which improved with increasing additive concentration. Rheological, dynamic light scattering, transmission, and cloud point experiments elucidated the molecular interaction, precipitation, and spinning behavior of the solutions. The low-molecular weight additive reduces the solution viscosity and thus the average relaxation time. On the contrary, slow processes appear with increasing additive concentration in the scattering data. Furthermore, phase separation occurred at a lower non-solvent concentration and the precipitation time increased with increasing additive content. These effects revealed a coupling mechanism of the triblock copolymer with poly(N-vinyl pyrrolidone) in solution. The chosen process parameters as well as the additive solutions provide an easy and inexpensive way to create an antifouling protection layer in situ with established recipes of poly(ether sulfone) hollow fiber membranes. Therefore, the membranes are promising candidates for fast integration in the membrane industry.

Steel Sheet Shear Walls with Burring Holes for Low- to Mid-Rise Housings

2019 ◽  
Author(s):  
Yoshimichi Kawai ◽  
Shigeaki Tohnai ◽  
Shinichiro Hashimoto ◽  
Atsushi Sato ◽  
Tetsuro Ono
Keyword(s):  
Finite Element ◽  
Shear Stress ◽  
Large Deformation ◽  
Deformation Behavior ◽  
Steel Sheet ◽  
Shear Walls ◽  
Shear Load ◽  
Finite Element Analyses ◽  
Plane Shear ◽  
Out Of Plane

<p>Steel sheet shear walls with cold formed edge stiffened burring holes are applied to low- to mid-rise housings in seismically active and typhoon- or hurricane-prone regions. A configuration with burrs on the inside and smooth on the outside enables the construction of omitting the machining of holes for equipments and thinner walls with simplified attachments of finishings. In-plane shear experiments and finite element analyses revealed that the walls allowed shear stress to concentrate in intervals between the burring holes. The walls maintained stable shear load and large deformation behavior, and the deformation areas were limited in the intervals and a large out-of-plane waveform in a sheet was effectively prevented owing to edge stiffened burring ribs. The design methods are developed for evaluating the shear load of the walls at story angle from zero to 1/100, using the idea of decreasing the band width of the inclined tension fields on the intervals with the effects of the thickness.</p>

Large Deformation Behavior of Compliant Mechanisms

2001 ◽  
Author(s):  
Jinyong Joo ◽  
Sridhar Kota ◽  
Noboru Kikuchi
Keyword(s):  
Shape Optimization ◽  
Large Deformation ◽  
Deformation Behavior ◽  
Compliant Mechanisms ◽  
Compliant Mechanism ◽  
Linear Formulation ◽  
Scaling Effect ◽  
Beam Elements ◽  
Linear And Nonlinear ◽  
Amplification Mechanism

Abstract This paper presents a non-linear formulation for size and shape optimization of compliant mechanisms using tapered beam elements. Designs based on linear and nonlinear formulations are compared using a stroke amplification mechanism example. Also, the scaling effect of the compliant mechanism is investigated.

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