Study of radiation-induced graft polymerization of vinyl monomers to cellulose by infrared spectroscopy. II. Cellulose–polystyrene copolymers

1968 ◽  
Vol 12 (9) ◽  
pp. 2007-2011 ◽  
Author(s):  
D. Imrišováa ◽  
S. Maryška
2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Ji-Hye Park ◽  
Yun Ok Kang ◽  
Seong-Ho Choi

Vinyl polymer-grafted multiwalled carbon nanotube (MWNT) supports with anion groups were prepared for use as biosensor supports by radiation-induced graft polymerization (RIGP) of the vinyl monomers acryloyl diphosphoric acid (ADPA), acrylic acid (AA), sodium styrenesulfonate (NaSS), and methacrylic acid (MA) onto the surface of MWNTs. The electrogenerated chemiluminescence sensors based on a glass carbon electrode (ECL-GCE) and a screen printed electrode (ECL-SPE) were fabricated by immobilization of Ru(bpy)3 2+complex after coating of vinyl polymer-grafted MWNT inks on the surface of the GCE and SPE without any polymer binders in order to obtain high electrogenerated chemiluminescence intensity. For detection of alcohol concentration, alcohol dehydrogenase (ADH) was immobilized onto an ECL-GCE sensor prepared by poly(NaSS)-g-MWNT supports. The prepared biosensor based on ADH is suitable for the detection of ethanol concentration in commercial drinks.


1971 ◽  
Vol 28 (314) ◽  
pp. 524-530,552 ◽  
Author(s):  
Yoshiko Kanazawa ◽  
Fukuji Higashide

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2028
Author(s):  
Shin-ichi Sawada ◽  
Yasunari Maekawa

We prepared novel bipolar membranes (BPMs) consisting of cation and anion exchange layers (CEL and AEL) using radiation-induced asymmetric graft polymerization (RIAGP). In this technique, graft polymers containing cation and anion exchange groups were introduced into a base film from each side. To create a clear CEL/AEL boundary, grafting reactions were performed from each surface side using two graft monomer solutions, which are immiscible in each other. Sodium p-styrenesulfonate (SSS) and acrylic acid (AA) in water were co-grafted from one side of the base ethylene-co-tetrafluoroethylene film, and chloromethyl styrene (CMS) in xylene was simultaneously grafted from the other side, and then the CMS units were quaternized to afford a BPM. The distinct SSS + AA- and CMS-grafted layers were formed owing to the immiscibility of hydrophilic SSS + AA and hydrophobic CMS monomer solutions. This is the first BPM with a clear CEL/AEL boundary prepared by RIAGP. However, in this BPM, the CEL was considerably thinner than the AEL, which may be a problem in practical applications. Then, by using different starting times of the first SSS+AA and second CMS grafting reactions, the CEL and AEL thicknesses was found to be controlled in RIAGP.


1973 ◽  
pp. 1188-1194
Author(s):  
Shoji HASHIMOTO ◽  
Akira UDAGAWA ◽  
Eiichi KAGEYAMA

1993 ◽  
Vol 81 (3) ◽  
pp. 295-305 ◽  
Author(s):  
William Lee ◽  
Kyoichi Saito ◽  
Shintaro Furusaki ◽  
Takanobu Sugo ◽  
Keizo Makuuchi

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