Soft segmental effect of methylene bis(p-cyclohexyl isocyanate) based thermoplastic polyurethane impregnated with lithium perchlorate/propylene carbonate on ionic conductivity

2001 ◽  
Vol 80 (7) ◽  
pp. 935-942 ◽  
Author(s):  
Ten-Chin Wen ◽  
Hsuan-Hsu Chen
2021 ◽  
Vol 12 (5) ◽  
pp. 6114-6123

Solid polymer electrolytes (SPEs) based carboxymethyl cellulose (CMC) with lithium perchlorate (LiClO4) were prepared via solution drop-cast technique. The CMC host is complexed by different concentrations of LiClO4 salt. SPEs were characterized by Electrochemical Impedance Spectroscopy (EIS) and Linear Sweep Voltammetry (LSV) in coin cells with lithium metal electrodes. EIS performed unique results based on various ionic conductivity values and dielectric properties. The higher ionic conductivity (1.32 × 10-5 S/cm) was obtained by SPEs 2 following by short-range ionic transport results based on dielectric properties depending on frequency. SPEs with LiClO4 addition are electrochemically stable over 2 V in lithium battery coin cells from LSV results.


2012 ◽  
Vol 66 ◽  
pp. 110-120 ◽  
Author(s):  
H. Nithya ◽  
S. Selvasekarapandian ◽  
P. Christopher Selvin ◽  
D. Arun Kumar ◽  
Junichi Kawamura

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