Mechanical and dynamic mechanical properties of rice husk ash-filled natural rubber compounds

2002 ◽  
Vol 83 (11) ◽  
pp. 2331-2346 ◽  
Author(s):  
H. M. Da Costa ◽  
L. L. Y. Visconte ◽  
R. C. R. Nunes ◽  
C. R. G. Furtado
2011 ◽  
Vol 393-395 ◽  
pp. 92-96 ◽  
Author(s):  
Zong Qiang Zeng ◽  
He Ping Yu ◽  
Hong Chao Liu ◽  
Shuang Quan Liao ◽  
Zheng Peng

The preparation of rubber-based composite from agricultural by-product is the main trend to upgrade the performance of rubber and reduce the cost. In this work, the rice husk ash/natural rubber (RHA/NR) composites were prepared by latex mixing process using the RHA modified with rare earth coupling agent. The mechanical properties, dynamic mechanical properties, thermal stability and morphology of RHA/NR composites were analyzed by universal testing machine, dynamic mechanical analyzer, thermo gravimetric analyzer and scanning electron microscope. The results indicate that previous modification of RHA with rare earth coupling agent can improve the dispersion of RHA in NR matrix significantly and increase the interaction between RHA particles and NR matrix and thus upgrade the mechanical properties and anti-oxidative behaviors of RHA/NR composite. The RHA/NR composite of highest mechanical properties and anti-oxidative behaviors can be obtained with a RHA loading of 4 per hundred rubber.


2018 ◽  
Vol 2018 ◽  
pp. 1-14 ◽  
Author(s):  
Ladawan Srisuwan ◽  
Kasama Jarukumjorn ◽  
Nitinat Suppakarn

In this study, the effect of silane treatment methods on cure characteristics and mechanical, dynamic mechanical, and morphological properties of rice husk flour (RHF)/natural rubber (NR) composites was investigated. The RHF surface was pretreated with alkali solution and then treated with bis(triethoxysilylpropyl) tetrasulfide (TESPT) solution using the unwashing silane treatment method and washing silane treatment method. The expected difference between these two methods was the silane layers presented on the RHF surface. Unwashed TESPT-treated RHF (UW-ST) and washed TESPT-treated RHF (W-ST) were incorporated into NR to prepare RHF/NR composites. The TESPT molecules deposited on UW-ST and W-ST surfaces were confirmed by the additional peaks appeared in the FTIR spectra of UW-ST and W-ST. In addition, the decrement of decomposition temperatures and the changes in the residue amounts of UW-ST and W-ST proved the removal of the physisorbed silane layers after washing. The presence of TESPT molecules on the RHF surface enhanced compatibility and adhesion between RHF and NR matrix. This was confirmed by SEM micrographs of both UW-ST/NR and W-ST/NR composites. This result was also supported by the improvement of the mechanical and the dynamic mechanical properties of these two composites. According to mechanical properties of the NR composites, the washing silane treatment method was more effective than the unwashing silane treatment method for compatibility improvement between RHF and NR. The modulus, tensile strength, and tear strength of W-ST/NR composites can be enhanced without deterioration of their elongation at break.


1997 ◽  
Vol 36 (1-2) ◽  
pp. 39-51 ◽  
Author(s):  
Hanafi Ismail ◽  
U. S. Ishiaku ◽  
A. R. Arinab ◽  
Z. A. Mohd Ishak

2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
T. A. Dung ◽  
N. T. Nhan ◽  
N. T. Thuong ◽  
D. Q. Viet ◽  
N. H. Tung ◽  
...  

The dynamic mechanical behavior of modified deproteinized natural rubber (DPNR) prepared by graft copolymerization with various styrene contents was investigated at a wide range of temperatures. Graft copolymerization of styrene onto DPNR was performed in latex stage using tert-butyl hydroperoxide (TBHPO) and tetraethylene pentamine (TEPA) as redox initiator. The mechanical properties were measured by tensile test and the viscoelastic properties of the resulting graft copolymers at wide range of temperature and frequency were investigated. It was found that the tensile strength depends on the grafted polystyrene; meanwhile the dynamic mechanical properties of the modification of DPNR meaningfully improved with the increasing of both homopolystyrene and grafted polystyrene compared to DPNR. The dynamic mechanical properties of graft copolymer over a large time scale were studied by constructing the master curves. The value of bT has been used to prove the energetic and entropic elasticity of the graft copolymer.


2014 ◽  
Vol 925 ◽  
pp. 308-312 ◽  
Author(s):  
Mou'ad A. Tarawneh ◽  
Sahrim Haji Ahmad ◽  
Yu Li Jiun ◽  
Radwan Dweiri ◽  
Ibrahim N. Hassan

In this paper the polymer nanocomposite of nickel zinc (NiZn) ferrite nanoparticles incorporated into the thermoplastic natural rubber nanocomposite (TPNR) were prepared via melt blending method. The effect of different NiZn loading (2-10 wt%) on morphology, tensile and dynamic mechanical properties of the obtained composites was investigated. It was found that NiZn ferrite is well dispersed in the thermoplastic natural rubber matrix. The tensile results indicated that filler loading has improved the tensile strength and Youngs modulus of the nanocomposite. However, the elongation at break decreased with increasing the percentage of NiZn. Dynamic mechanical test showed that the highest storage modulus is at 8 wt% filler. Any further increment of the filler content leads to the formation of agglomerate hence affecting the properties. The Scanning electron micrograph (SEM) micrographs reveal aspect ratio and filler orientation in the TPNR matrix also strongly promoted interfacial adhesion between the filler and the matrix to control its properties.


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