Production of Structured Triacylglycerol via Enzymatic Interesterification of Medium‐Chain Triacylglycerol and Soybean Oil Using a Pilot‐Scale Solvent‐Free Packed Bed Reactor

2020 ◽  
Vol 97 (3) ◽  
pp. 271-280 ◽  
Author(s):  
Zhen Zhang ◽  
Siwen Zhang ◽  
Wan Jun Lee ◽  
Oi Ming Lai ◽  
Chin Ping Tan ◽  
...  
2011 ◽  
Vol 109 (3) ◽  
pp. 637-646 ◽  
Author(s):  
Amber R. Boles ◽  
Teresa Conneely ◽  
Robert McKeever ◽  
Paul Nixon ◽  
Klaus R. Nüsslein ◽  
...  

2021 ◽  
Author(s):  
Eric Skrotzki ◽  
Jaya Kishore Vandavasi ◽  
Stephen Newman

Ozone is a powerful oxidant, most commonly used for oxidation of alkenes to carbonyls. The synthetic utility of other ozone-mediated reactions is hindered by its high reactivity and propensity to over-oxidize organic molecules, including most solvents. This challenge can largely be mitigated by adsorbing both substrate and ozone onto silica gel, providing a solvent-free oxidation method. In this manuscript, a flow-based packed bed reactor approach is described that provides exceptional control of reaction temperature and time of this reaction to achieve improved control and chemoselectivity over this challenging reaction. A powerful method to oxidize primary amines into nitroalkanes is achieved. Examples of pyridine, C–H bond, and arene oxidations are also demonstrated, confirming the system is generalizable to diverse ozone-mediated processes.<br>


2009 ◽  
Vol 45 (3) ◽  
pp. 188-194 ◽  
Author(s):  
M. Hajar ◽  
S. Shokrollahzadeh ◽  
F. Vahabzadeh ◽  
A. Monazzami

2011 ◽  
Vol 88 (12) ◽  
pp. 1925-1933 ◽  
Author(s):  
Roberta Claro da Silva ◽  
Fabiana Andreia Schaffer De Martini Soares ◽  
Thaís Gonzaga Fernandes ◽  
Anna Laura Donadi Castells ◽  
Kelly Caroline Guimarães da Silva ◽  
...  

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