CuI heterogenized on thiosemicarbazide modified-multi walled carbon nanotubes (thiosemicarbazide-MWCNTs-CuI): Novel heterogeneous and reusable nanocatalyst in the C-N Ullmann coupling reactions

2016 ◽  
Vol 31 (8) ◽  
pp. e3676 ◽  
Author(s):  
Hojat Veisi ◽  
Yalda Metghalchi ◽  
Malak Hekmati ◽  
Shiva Samadzadeh
2018 ◽  
Vol 42 (4) ◽  
pp. 2782-2789 ◽  
Author(s):  
Elham Akhavan ◽  
Saba Hemmati ◽  
Malak Hekmati ◽  
Hojat Veisi

Herein, a novel MWCNTs-Met/CuCl nanocatalyst synthesis method by metformine covalent grafting on the surface of carbon nanotubes and subsequent coordination with a CuCl catalyst is described.


2016 ◽  
Vol 40 (6) ◽  
pp. 4945-4951 ◽  
Author(s):  
Mehdi Adib ◽  
Rahman Karimi-Nami ◽  
Hojat Veisi

In this article a new heterogeneous nanocatalyst based on palladium supported on functionalized multi-walled carbon nanotubes (MWCNTs) has been introduced.


Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 495
Author(s):  
Sojeong K. Folsom ◽  
Destiny J. Ivey ◽  
Frank S. McNair ◽  
Ali R. Siamaki

Nickel-Fe3O4 nanoparticles supported on multi-walled carbon nanotubes (Ni-Fe3O4/MWCNTs) were synthesized by mechanical grinding of a sample of nickel salt, Fe3O4 and MWCNTs using a ball-mill mixer. The preparation method allows for bulk production of Ni-Fe3O4 nanoparticles at room temperature without the necessity of any solvent or chemical reagent. The nanoparticles prepared by this method exhibit small particles size of 5–8 nm with uniform dispersion of nickel nanoparticles on the surface of multi-walled carbon nanotubes. The Ni-Fe3O4/MWCNTs demonstrated remarkable catalytic activity for Suzuki cross coupling reactions of functionalized aryl halides and phenylboronic acids with excellent turnover number and turnover frequency (e.g., 76,000 h−1) using Monowave 50 conventional heating reactor at 120 °C within a very short reaction time of 15 min. The catalyst is air-stable and exhibits easy removal from the reaction mixture due to its magnetic properties, recyclability with no loss of activity, and significantly better performance than the other well-known commercial nickel catalyst. The Ni-Fe3O4/MWCNTs nanoparticles were fully characterized by a variety of spectroscopic techniques including X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). Since nickel offers similar properties to other more expensive transition metals including the most widely used palladium counterpart in cross coupling catalysis, this work demonstrates a promising lower-cost, air-moisture stable and efficient alternative catalyst based on nickel nanoparticles for cross coupling reactions.


2018 ◽  
Vol 42 (16) ◽  
pp. 14009-14009 ◽  
Author(s):  
Elham Akhavan Taheri ◽  
Saba Hemmati ◽  
Malak Hekmati ◽  
Hojat Veisi

Correction for ‘CuCl heterogenized on metformine-modified multi walled carbon nanotubes as a recyclable nanocatalyst for Ullmann-type C–O and C–N coupling reactions’ by Elham Akhavan Taheri et al., New J. Chem., 2018, 42, 2782–2789.


Acta Naturae ◽  
2011 ◽  
Vol 3 (1) ◽  
pp. 99-106 ◽  
Author(s):  
E A Smirnova ◽  
A A Gusev ◽  
O N Zaitseva ◽  
E M Lazareva ◽  
G E Onishchenko ◽  
...  

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