The synthesis of metal-organic framework Al-MIL-53-derived Brønsted acid catalyst and its application in the Mannich reaction

2016 ◽  
Vol 31 (2) ◽  
pp. e3569 ◽  
Author(s):  
Zongcheng Miao ◽  
Chao Qi ◽  
Liangshi Wang ◽  
Allison M. Wensley ◽  
Yi Luan
Keyword(s):  
Mannich Reaction ◽  
Metal Organic Framework ◽  
Acid Catalyst ◽  
Bronsted Acid ◽  
Brönsted Acid ◽  
Brønsted Acid Catalyst ◽  
Metal Organic ◽  
The Mannich Reaction ◽  
Brönsted Acid Catalyst ◽  
Organic Framework

MIL-101-SO3H metal–organic framework as a Brønsted acid catalyst in Hantzsch reaction: an efficient and sustainable methodology for one-pot synthesis of 1,4-dihydropyridine

2019 ◽  
Vol 43 (17) ◽  
pp. 6806-6814 ◽  
Author(s):  
Nainamalai Devarajan ◽  
Palaniswamy Suresh
Keyword(s):  
Metal Organic Framework ◽  
Acid Catalyst ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
One Pot ◽  
Brönsted Acid ◽  
Brønsted Acid Catalyst ◽  
Metal Organic ◽  
Brönsted Acid Catalyst ◽  
Organic Framework

A straightforward and efficient methodology for the synthesis of the medicinally important 1,4-dihydropyridines has been demonstrated using MIL-101-SO3H metal–organic framework as a sustainable Brønsted acid catalyst.

scholarly journals Evolution of a Metal‐Organic Framework into a Brønsted Acid Catalyst for Glycerol Dehydration to Acrolein

ChemSusChem ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 5073-5079
Author(s):  
Xiaomin Li ◽  
Liang Huang ◽  
Alena Kochubei ◽  
Jun Huang ◽  
Wei Shen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Acid Catalyst ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
Brønsted Acid Catalyst ◽  
Glycerol Dehydration ◽  
Metal Organic ◽  
Brönsted Acid Catalyst ◽  
Organic Framework

Brønsted acid-catalyzed Mannich reaction through dual activation of aldehydes and N-Boc-imines

2015 ◽  
Vol 51 (92) ◽  
pp. 16472-16474 ◽  
Author(s):  
Taichi Kano ◽  
Yusuke Aota ◽  
Daisuke Asakawa ◽  
Keiji Maruoka
Keyword(s):  
Mannich Reaction ◽  
Acid Catalyst ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Iminium Salts ◽  
Brönsted Acid ◽  
Brønsted Acid Catalyst ◽  
Acid Catalyzed ◽  
Dual Activation ◽  
Brönsted Acid Catalyst

In the presence of a Brønsted acid catalyst, both aldehydes and N-Boc-aminals were converted to enecarbamates and N-Boc-iminium salts as activated nucleophiles and electrophiles, respectively, giving unprecedented Mannich adducts.

scholarly journals Identification of the strong Brønsted acid site in a metal–organic framework solid acid catalyst

2018 ◽  
Vol 11 (2) ◽  
pp. 170-176 ◽  
Author(s):  
Christopher A. Trickett ◽  
Thomas M. Osborn Popp ◽  
Ji Su ◽  
Chang Yan ◽  
Jonathan Weisberg ◽  
...  
Keyword(s):  
Acid Site ◽  
Solid Acid ◽  
Metal Organic Framework ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Bronsted Acid ◽  
Brønsted Acid Site ◽  
Brönsted Acid ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A hydrothermally stable ytterbium metal–organic framework as a bifunctional solid-acid catalyst for glucose conversion

2019 ◽  
Vol 55 (76) ◽  
pp. 11446-11449 ◽  
Author(s):  
David L. Burnett ◽  
Ryan Oozeerally ◽  
Ralentri Pertiwi ◽  
Thomas W. Chamberlain ◽  
Nikolay Cherkasov ◽  
...  
Keyword(s):  
Solid Acid ◽  
Metal Organic Framework ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Acid Sites ◽  
Bronsted Acid ◽  
Brønsted Acid Sites ◽  
Brönsted Acid ◽  
Metal Organic ◽  
Organic Framework

A ytterbium–organic framework containing Lewis and Brønsted acid sites that effects transformation of glucose to 5-HMF in water at 140 °C.

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