Natural hydroxyapatite-supported MnO2: a green heterogeneous catalyst for selective aerobic oxidation of alkylarenes and alcohols

2016 ◽  
Vol 30 (9) ◽  
pp. 772-776 ◽  
Author(s):  
Ahmad Shaabani ◽  
Hadi Afaridoun ◽  
Shabnam Shaabani
RSC Advances ◽  
2016 ◽  
Vol 6 (99) ◽  
pp. 97367-97375 ◽  
Author(s):  
Ahmad Shaabani ◽  
Hadi Afaridoun ◽  
Shabnam Shaabani ◽  
Mina Keramati Nejad

Natural hydroxyapatite supported cobalt tetrasulfophthalocyanine (CoTSPc-NHAp) as a green, renewable and biomaterial-based heterogeneous catalyst promotes aerobic oxidation of alkyl arenes and alcohols.


2017 ◽  
Vol 29 (6) ◽  
pp. 646-650 ◽  
Author(s):  
Yuta Nabae ◽  
Masatomo Mikuni ◽  
Nobuhiro Takusari ◽  
Teruaki Hayakawa ◽  
Masa-aki Kakimoto

Hyperbranched polyimide functionalized with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was studied as a heterogeneous catalyst for the aerobic oxidation of benzyl alcohol. The catalyst material was synthesized by an A2 + B3 polymerization of pyromellitic dianhydride and 1,3,5-tris(4-aminophenyl)benzene followed by an end-capping reaction with 4-amino-TEMPO. Selective aerobic oxidation of benzyl alcohol to benzaldehyde has been demonstrated using the prepared materials as a catalyst. The recyclability of these materials has been confirmed by recycling tests using the catalyst collected by filtration.


RSC Advances ◽  
2016 ◽  
Vol 6 (54) ◽  
pp. 48396-48404 ◽  
Author(s):  
Ahmad Shaabani ◽  
Shabnam Shaabani ◽  
Hadi Afaridoun

Cobalt was successfully immobilized on natural hydroxyapatite nanocrystals which was obtained from cow bones (Co–NHAp). NHAp as the support enhanced both catalytic activity and selectivity in aerobic oxidation of alkyl arenes and alcohols.


RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37517-37520 ◽  
Author(s):  
Prashant Chauhan ◽  
Ning Yan

A Cu-tetrasulfonate-phthalocyanine was conjugated to cationic cellulose nanocrystals which serve as a heterogeneous based catalyst for aerobic oxidation of alcohols and alkyl arenes at room temperature in aqueous medium.


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