Facile functionalization of isotactic polypropylene by azide and alkyne groups for click chemistry application

Chuanhui Zhang; Hui Niu; Jin-Yong Dong

doi:10.1002/aoc.1819

Facile functionalization of isotactic polypropylene by azide and alkyne groups for click chemistry application

Applied Organometallic Chemistry ◽

10.1002/aoc.1819 ◽

2011 ◽

Vol 25 (8) ◽

pp. 632-637 ◽

Cited By ~ 23

Author(s):

Chuanhui Zhang ◽

Hui Niu ◽

Jin-Yong Dong

Keyword(s):

Click Chemistry ◽

Isotactic Polypropylene

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Synthesis of Star Isotactic Polypropylene Using Click Chemistry

Macromolecules ◽

10.1021/ma1019335 ◽

2010 ◽

Vol 43 (20) ◽

pp. 8331-8335 ◽

Cited By ~ 27

Author(s):

Huahua Huang ◽

Hui Niu ◽

Jin-Yong Dong

Keyword(s):

Click Chemistry ◽

Isotactic Polypropylene

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Facile functionalization of isotactic polypropylene via click chemistry

Polymer Chemistry ◽

10.1039/c9py01225g ◽

2019 ◽

Vol 10 (46) ◽

pp. 6368-6378 ◽

Cited By ~ 4

Author(s):

Yu-Lian Li ◽

Dong-Po Song ◽

Li Pan ◽

Zhe Ma ◽

Yue-Sheng Li

Keyword(s):

Click Chemistry ◽

Isotactic Polypropylene ◽

Graft Copolymers

Alkynyl functionalized iPP, with 1–4 mol% comonomer incorporation, can be efficiently synthesized and conveniently converted into various functional iPPs and graft copolymers via alkynyl/N3 reaction.

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New click chemistry reaction: sulfur fluoride exchange

AccessScience ◽

10.1036/1097-8542.br0902141 ◽

2015 ◽

Keyword(s):

Click Chemistry ◽

Sulfur Fluoride

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Click Chemistry Expedited Radiosynthesis: Sulfur [18F]fluoride Exchange of Aryl Fluorosulfates

10.26434/chemrxiv.10314647.v1 ◽

2019 ◽

Cited By ~ 1

Author(s):

Qinheng Zheng ◽

Hongtao Xu ◽

Hua Wang ◽

Wen-Ge Han Du ◽

Nan Wang ◽

...

Keyword(s):

Click Chemistry ◽

High Performance ◽

Isotopic Exchange ◽

Tumor Imaging ◽

Radiochemical Yield ◽

Exchange Method ◽

Molar Activity ◽

Positron Emission ◽

Sulfur Fluoride

The lack of simple, efficient [18F]fluorination processes and new target-specific organofluorine probes remains the major challenge of fluorine-18-based positron emission tomography (PET). We report here a fast isotopic exchange method for the radiosynthesis of aryl [18F]fluorosulfate based PET agents enabled by the emerging sulfur fluoride exchange (SuFEx) click chemistry. The method has been applied to the fully-automated 18F-radiolabeling of twenty-five structurally diverse aryl fluorosulfates with excellent radiochemical yield (83–100%) and high molar activity (up to 281 GBq µmol–1) at room temperature in 30 seconds. The purification of radiotracers requires no time-consuming high-performance liquid chromatography (HPLC), but rather a simple cartridge filtration. The utility of aryl [18F]fluorosulfate is demonstrated by the in vivo tumor imaging by targeting poly(ADP-ribose) polymerase 1 (PARP1).

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Properties of nanocomposites based on isotactic polypropylene and high-pressure polyethylene with metal-containing nanofillers

Perspektivnye Materialy ◽

10.30791/1028-978x-2020-9-59-64 ◽

2020 ◽

pp. 59-64

Author(s):

N. I. Kurbanova ◽

◽

T. M. Gulieva ◽

N. Ya. Ischenko ◽

◽

...

Keyword(s):

High Pressure ◽

Synergistic Effect ◽

Polymer Matrix ◽

Isotactic Polypropylene ◽

Rheological Parameters ◽

Mechanochemical Method ◽

X Ray ◽

Effect Of Additives ◽

High Pressure Polyethylene ◽

Properties Of Composites

The effect of additives of nanofillers (NF) containing nanoparticles (NP) of copper oxide, stabilized by a polymer matrix of maleized polyethylene (MPE), obtained by the mechanochemical method, on the properties of composites based on isotactic polypropylene (PP) and high-pressure polyethylene (PE) was studied by X-ray phase (XRD) and thermogravimetric (TGA) analyzes. The enhancement of strength, deformation, and rheological parameters, as well as the thermo-oxidative stability of the obtained nanocomposites was revealed, which, apparently, is due to the synergistic effect of the interaction of copper-containing nanoparticles with anhydride groups of MPE. It is shown that nanocomposites based on PP/PE/NF can be processed both by pressing and injection molding and extrusion, which expands the scope of its application.

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