Tricomponent Supramolecular Multiblock Copolymers withTunable Composition via Sequential Seeded Growth

2021 ◽  
Author(s):  
Aritra Sarkar ◽  
Ranjan Sasmal ◽  
Angshuman Das ◽  
Akhil Venugopal ◽  
Sarit Agasti ◽  
...  
Keyword(s):  
Multiblock Copolymers ◽  
Seeded Growth

Tricomponent Supramolecular Multiblock Copolymers withTunable Composition via Sequential Seeded Growth

2021 ◽  
Author(s):  
Aritra Sarkar ◽  
Ranjan Sasmal ◽  
Angshuman Das ◽  
Akhil Venugopal ◽  
Sarit Agasti ◽  
...  
Keyword(s):  
Multiblock Copolymers ◽  
Seeded Growth

Morphological studies of linear (AB)n multiblock copolymers and their blends

1992 ◽  
Vol 50 (1) ◽  
pp. 384-385
Author(s):  
Richard J. Spontak ◽  
Steven D. Smith ◽  
Arman Ashraf
Keyword(s):  
Electron Microscopy ◽  
Microphase Separation ◽  
Multiblock Copolymers ◽  
First Order ◽  
Morphological Studies ◽  
Transmission Electron ◽  
First Order Phase Transition ◽  
Covalently Bonded ◽  
Total Molecular Weight ◽  
First Order Phase

Block copolymers are composed of sequences of dissimilar chemical moieties covalently bonded together. If the block lengths of each component are sufficiently long and the blocks are thermodynamically incompatible, these materials are capable of undergoing microphase separation, a weak first-order phase transition which results in the formation of an ordered microstructural network. Most efforts designed to elucidate the phase and configurational behavior in these copolymers have focused on the simple AB and ABA designs. Few studies have thus far targeted the perfectly-alternating multiblock (AB)n architecture. In this work, two series of neat (AB)n copolymers have been synthesized from styrene and isoprene monomers at a composition of 50 wt% polystyrene (PS). In Set I, the total molecular weight is held constant while the number of AB block pairs (n) is increased from one to four (which results in shorter blocks). Set II consists of materials in which the block lengths are held constant and n is varied again from one to four (which results in longer chains). Transmission electron microscopy (TEM) has been employed here to investigate the morphologies and phase behavior of these materials and their blends.

Crystal structure-size relationship in ultrafine metallic particles

1989 ◽  
Vol 47 ◽  
pp. 266-267
Author(s):  
Jun Liu ◽  
Mehmet Sarikaya ◽  
Ilhan A. Aksay
Keyword(s):  
Ultrafine Particles ◽  
Carbon Film ◽  
Lattice Defects ◽  
Careful Examination ◽  
Seeded Growth ◽  
Gold Particles ◽  
Metallic Particles ◽  
Interfacial Structures ◽  
Typical Particle ◽  
Many Particles

Ultrafine particles usually have unique physical properties. This study illustrates how the lattice defects and interfacial structures between particles are related to the size of ultrafine crystalline gold particles.Colloidal gold particles were produced by reducing gold chloride with sodium citrate at 100°C. In this process, particle size can be controlled by changing the concentration of the reactant. TEM samples are prepared by transferring a small amount of solution onto a thin (5 nm) carbon film which is suspended on a copper grid. In this work, all experiments were performed with Philips 430T at 300 kV.With controlled seeded growth, particles of different sizes are produced, as shown in Figure 1. By a careful examination, it can be resolved that very small particles have lattice defects with complex interfaces. Some typical particle structures include multiple twins, resulting in a five-fold symmetry bicrystals, and highly disordered regions. Many particles are too complex to be described by simple models.

Super2- Structures in Polydisperse Multiblock-Copolymers

1997 ◽  
Vol 7 (10) ◽  
pp. 1489-1497 ◽  
Author(s):  
A. N. Semenov
Keyword(s):  
Multiblock Copolymers

Rapid, Non-Toxic Synthesis of Beta Zeolites

2018 ◽  
Author(s):  
Felix Hemmann ◽  
Jonathan Hackebeil ◽  
Andreas Lißner ◽  
Florian Mertens
Keyword(s):  
Hydrofluoric Acid ◽  
Molecular Sieves ◽  
Toxic Chemicals ◽  
Lewis Acidity ◽  
Beta Zeolite ◽  
Seeded Growth ◽  
Related Research ◽  
Beta Zeolites ◽  
Growth Method ◽  
Fast Synthesis

Molecular sieves with beta zeolite topology are promising catalysts for various reactions as they exhibits extraordinary Lewis acidity. However, their industrial application and related research in academica is hindered because their synthesis is time consuming and typically involves toxic chemicals as hydrofluoric acid. Therefore, tetraethylammonium fluorid was tested as a non-toxic fluotide source for the synthesis of beta zeolites. In combination with the previously reported nano-seeded growth method, a fast synthesis of beta zeolites only involving non-toxic chemicals was possible. Synthesized zeolites show comparable selectivity in the Bayer-Villinger oxidation as conventional zeolites synthesized with hydrofluoric acid.<br>

Seeded Growth of Single-Crystal Two-Dimensional Covalent Organic Frameworks

2017 ◽  
Author(s):  
Austin M. Evans ◽  
Lucas R. Parent ◽  
Nathan C. Flanders ◽  
Ryan P. Bisbey ◽  
Edon Vitaku ◽  
...  
Keyword(s):  
Molecular Transport ◽  
Controlled Synthesis ◽  
Two Dimensional ◽  
Covalent Organic Frameworks ◽  
Seeded Growth ◽  
Covalent Bonds ◽  
Crystalline Materials ◽  
Step Procedure ◽  
Structures And Properties ◽  
2D Polymer

<div> <div> <div> <p>Polymerizing monomers into periodic two-dimensional (2D) networks provides structurally precise, atomically thin macromolecular sheets linked by robust, covalent bonds. These materials exhibit desirable mechanical, optoelectrotronic, and molecular transport properties derived from their designed structure and permanent porosity. 2D covalent organic frameworks (COFs) offer broad monomer scope, but are generally isolated as polycrystalline, insoluble powders with limited processability. Here we overcome this limitation by controlling 2D COF formation using a two- step procedure. In the first step, 2D COF nanoparticle seeds are prepared with approximate diameters of 30 nm. Next, monomers are slowly added to suppress new nucleation while promoting epitaxial growth on the existing seeds to sizes of several microns. The resulting COF nanoparticles are of exceptional and unprecedented quality, isolated as single crystalline materials with micron-scale domain sizes. These findings advance the controlled synthesis of 2D layered COFs and will enable a broad exploration of synthetic 2D polymer structures and properties. </p> </div> </div> </div>

Seeded Growth of Single-Crystal Two-Dimensional Covalent Organic Frameworks

2017 ◽  
Author(s):  
Austin M. Evans ◽  
Lucas R. Parent ◽  
Nathan C. Flanders ◽  
Ryan P. Bisbey ◽  
Edon Vitaku ◽  
...  
Keyword(s):  
Molecular Transport ◽  
Controlled Synthesis ◽  
Two Dimensional ◽  
Covalent Organic Frameworks ◽  
Seeded Growth ◽  
Covalent Bonds ◽  
Crystalline Materials ◽  
Step Procedure ◽  
Structures And Properties ◽  
2D Polymer

<div> <div> <div> <p>Polymerizing monomers into periodic two-dimensional (2D) networks provides structurally precise, atomically thin macromolecular sheets linked by robust, covalent bonds. These materials exhibit desirable mechanical, optoelectrotronic, and molecular transport properties derived from their designed structure and permanent porosity. 2D covalent organic frameworks (COFs) offer broad monomer scope, but are generally isolated as polycrystalline, insoluble powders with limited processability. Here we overcome this limitation by controlling 2D COF formation using a two- step procedure. In the first step, 2D COF nanoparticle seeds are prepared with approximate diameters of 30 nm. Next, monomers are slowly added to suppress new nucleation while promoting epitaxial growth on the existing seeds to sizes of several microns. The resulting COF nanoparticles are of exceptional and unprecedented quality, isolated as single crystalline materials with micron-scale domain sizes. These findings advance the controlled synthesis of 2D layered COFs and will enable a broad exploration of synthetic 2D polymer structures and properties. </p> </div> </div> </div>

scholarly journals Seeded Growth of HgTe Nanocrystals for Shape Control and Their Use in Narrow Infrared Electroluminescence

2021 ◽  
Vol 33 (6) ◽  
pp. 2054-2061
Author(s):  
Yoann Prado ◽  
Junling Qu ◽  
Charlie Gréboval ◽  
Corentin Dabard ◽  
Prachi Rastogi ◽  
...  
Keyword(s):  
Shape Control ◽  
Seeded Growth

Enriching the branching of Au@PdAu core–shell nanocrystals using a syringe pump: kinetics control meets lattice mismatch

CrystEngComm ◽  
2021 ◽  
Vol 23 (13) ◽  
pp. 2582-2589
Author(s):  
Gongguo Zhang ◽  
Yanyun Ma ◽  
Xiaowei Fu ◽  
Wenjun Zhao ◽  
Feng Liu ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Surface Diffusion ◽  
Lattice Mismatch ◽  
Core Shell ◽  
Syringe Pump ◽  
Seeded Growth ◽  
Gold Nanocrystals

Gold@palladium–gold nanocrystals with a tunable branched shape are prepared via seeded growth, where the use of a syringe pump allows the manipulation over reaction kinetics as coupled by surface diffusion and strain caused by lattice mismatch.

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