On‐Surface Hydrogen/Deuterium Isotope Exchange in Polycyclic Aromatic Hydrocarbons

2021 ◽  
Author(s):  
Christian Wäckerlin
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Isotope Exchange ◽  
Surface Hydrogen ◽  
Polycyclic Aromatic ◽  
Hydrogen Deuterium

Hydrogen–deuterium exchange and rearrangement of polycyclic aromatic hydrocarbons in dilute acid medium at elevated temperatures

1981 ◽  
Vol 59 (22) ◽  
pp. 3218-3219 ◽  
Author(s):  
Nick Henry Werstiuk ◽  
George Timmins
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
High Temperature ◽  
Acid Medium ◽  
Aromatic Hydrocarbons ◽  
Elevated Temperatures ◽  
High Yield ◽  
Hydrogen Deuterium Exchange ◽  
Dilute Acid ◽  
Polycyclic Aromatic ◽  
Hydrogen Deuterium

The high temperature – dilute acid (HTDA) method has been applied to the preparation of perdeuterated polycyclic aromatic hydrocarbons. Naphthalene (1), 1-methylnaphthalene (2), 2-methylnaphthalene (3), anthracene (4), phenanthrene (5), chrysene (6), pyrene (7), benz[a]anthracene (8), benzo[a]pyrene (9), 1,1′-binaphthyl (10), 1,2′-binaphthyl (11), and 2,2′-binaphthyl (12) have been perdeuterated in high yield in dilute DCl–D2O solutions at elevated temperatures (240–280 °C). 2, 3, 10, 11, and 12 also rearrange.

scholarly journals On-Surface Hydrogen-Induced Covalent Coupling of Polycyclic Aromatic Hydrocarbons via a Superhydrogenated Intermediate

2019 ◽  
Vol 141 (8) ◽  
pp. 3550-3557 ◽  
Author(s):  
Carlos Sánchez-Sánchez ◽  
José Ignacio Martínez ◽  
Nerea Ruiz del Arbol ◽  
Pascal Ruffieux ◽  
Roman Fasel ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Covalent Coupling ◽  
Surface Hydrogen ◽  
Polycyclic Aromatic

The Assessment of Contamination and Source of Polycyclic Aromatic Hydrocarbons from the Sediments of the Someş River

2019 ◽  
Vol 64 (1) ◽  
pp. 55-67
Author(s):  
Vlad Pӑnescu ◽  
◽  
Mihaela Cӑtӑlina Herghelegiu ◽  
Sorin Pop ◽  
Mircea Anton ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Polycyclic Aromatic

1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Polycyclic Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbon ◽  
Electronic Properties ◽  
Aromatic Hydrocarbons ◽  
Model Systems ◽  
Redox Potentials ◽  
Dimer Model ◽  
Optical And Electronic Properties ◽  
Polycyclic Aromatic

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>

1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Polycyclic Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbon ◽  
Electronic Properties ◽  
Aromatic Hydrocarbons ◽  
Model Systems ◽  
Redox Potentials ◽  
Dimer Model ◽  
Optical And Electronic Properties ◽  
Polycyclic Aromatic

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>

EMISSION OF POLYCYCLIC AROMATIC HYDROCARBONS CONTAINED IN COMBUSTION PRODUCTS OF GASOLINE ENGINES

2018 ◽  
Vol 62 (3) ◽  
pp. 341-346 ◽  
Author(s):  
M. Assad ◽  
V. V. Grushevski ◽  
O. G. Penyazkov ◽  
I. N. Tarasenko
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
High Speed ◽  
Internal Combustion Engines ◽  
Catalytic Converter ◽  
Combustion Products ◽  
Chromatography Method ◽  
Exhaust Gases ◽  
Polycyclic Aromatic ◽  
Load Mode

The concentration of 16 polycyclic aromatic hydrocarbons (PAHs) in the gasoline combustion products emitted into the atmosphere by internal combustion engines (ICE) has been measured using the gas chromatography method. The concentrations of PAHs in the exhaust gases sampled behind a catalytic converter has been determined when the ICE operates in five modes: idle mode, high speed mode, load mode, ICE cold start mode (engine warm-up) and transient mode. Using 92 RON, 95 RON and 98 RON gasoline the effect of the octane number of gasoline on the PAHs content in the exhaust gases has been revealed. The concentration of the most carcinogenic component (benzo(α)pyrene) in the exhaust gases behind a catalytic converter significantly exceeds a reference value of benzo(α)pyrene in the atmospheric air established by the WHO and the EU for ICE in the load mode.

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