scholarly journals Lithium‐Metal Anode Instability of the Superionic Halide Solid Electrolytes and the Implications for Solid‐State Batteries

2020 ◽  
Author(s):  
Luise Riegger ◽  
Roman Schlem ◽  
Joachim Sann ◽  
Wolfgang G Zeier ◽  
Jürgen Janek
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Solid State Batteries

Creep and Anisotropy of Free-Standing Lithium Metal Foils in an Industrial Dry Room

2021 ◽  
pp. 1-32
Author(s):  
Lara Dienemann ◽  
Anil Saigal ◽  
Michael A Zimmerman
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
High Volume ◽  
Dominant Mode ◽  
Lithium Metal ◽  
Free Standing ◽  
Metal Anode ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anode ◽  
Solid State Batteries

Abstract Commercialization of energy-dense lithium metal batteries relies on stable and uniform plating and stripping on the lithium metal anode. In electrochemical-mechanical modeling of solid-state batteries, there is a lack of consideration of specific mechanical properties of battery-grade lithium metal. Defining these characteristics is crucial for understanding how lithium ions plate on the lithium metal anode, how plating and stripping affect deformation of the anode and its interfacing material, and whether dendrites are suppressed. Recent experiments show that the dominant mode of deformation of lithium metal is creep. This study measures the time and temperature dependent mechanics of two thicknesses of commercial lithium anodes inside an industrial dry room, where battery cells are manufactured at high volume. Furthermore, a directional study examines the anisotropic microstructure of 100 µm thick lithium anodes and its effect on bulk creep mechanics. It is shown that these lithium anodes undergo plastic creep as soon as a coin cell is manufactured at a pressure of 0.30 MPa, and achieving thinner lithium foils, a critical goal for solid-state lithium batteries, is correlated to anisotropy in both lithium's microstructure and mechanical properties.

Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries

2020 ◽  
Vol 120 (15) ◽  
pp. 7745-7794 ◽  
Author(s):  
Thorben Krauskopf ◽  
Felix H. Richter ◽  
Wolfgang G. Zeier ◽  
Jürgen Janek
Keyword(s):  
Solid State ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Solid State Batteries

All‐Solid‐State Batteries with a Limited Lithium Metal Anode at Room Temperature using a Garnet‐Based Electrolyte

2020 ◽  
Vol 33 (1) ◽  
pp. 2002325
Author(s):  
Shaojie Chen ◽  
Jingxuan Zhang ◽  
Lu Nie ◽  
Xiangchen Hu ◽  
Yuanqi Huang ◽  
...  
Keyword(s):  
Solid State ◽  
Room Temperature ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Solid State Batteries ◽  
All Solid State Batteries
Sign in / Sign up

Export Citation Format

Share Document