scholarly journals The Size‐Accelerated Kinetic Resolution of Secondary Alcohols

2020 ◽  
Vol 60 (2) ◽  
pp. 774-778
Author(s):  
Benjamin Pölloth ◽  
Mukund P. Sibi ◽  
Hendrik Zipse
Keyword(s):  
Kinetic Resolution ◽  
Secondary Alcohols

Kinetic resolution of sterically hindered secondary alcohols catalyzed by aminophosphinite organocatalyst

Tetrahedron ◽  
2018 ◽  
Vol 74 (2) ◽  
pp. 296-302 ◽  
Author(s):  
Nanami Hara ◽  
Shu Fujisawa ◽  
Mizuki Fujita ◽  
Mikako Miyazawa ◽  
Kazuma Ochiai ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Secondary Alcohols ◽  
Sterically Hindered

ChemInform Abstract: Kinetic Resolution of Racemic Secondary Alcohols via Oxidation with Yarrowia lipolytica Strains.

ChemInform ◽  
2000 ◽  
Vol 31 (40) ◽  
pp. no-no
Author(s):  
Giancarlo Fantin ◽  
Marco Fogagnolo ◽  
Alessandro Medici ◽  
Paola Pedrini ◽  
Silvia Fontana
Keyword(s):  
Yarrowia Lipolytica ◽  
Kinetic Resolution ◽  
Secondary Alcohols

scholarly journals Scalable Green Approach Toward Fragrant Acetates

Molecules ◽  
2020 ◽  
Vol 25 (14) ◽  
pp. 3217
Author(s):  
Eva Puchl’ová ◽  
Peter Szolcsányi
Keyword(s):  
Kinetic Resolution ◽  
High Reactivity ◽  
Secondary Alcohols ◽  
Enzymatic System ◽  
Single Product ◽  
Discrimination Power ◽  
Green Approach ◽  
Naturally Occurring ◽  
Glycerol Triacetate ◽  
Practical Synthesis

The advantageous properties of ethylene glycol diacetate (EGDA) qualify it as a useful substitute for glycerol triacetate (GTA) for various green applications. We scrutinised the lipase-mediated acetylation of structurally diverse alcohols in neat EGDA furnishing the range of naturally occurring fragrant acetates. We found that such enzymatic system exhibits high reactivity and selectivity towards activated (homo) allylic and non-activated primary/secondary alcohols. This feature was utilised in the scalable multigram synthesis of fragrant (Z)-hex-3-en-1-yl acetate in 70% yield. In addition, the Lipozyme 435/EGDA system was also found to be applicable for the chemo-selective acetylation of (hydroxyalkyl) phenols as well as for the kinetic resolution of chiral secondary alcohols. Lastly, its discrimination power was demonstrated in competitive experiments of equimolar mixtures of two isomeric alcohols. This enabled the practical synthesis of 1-pentyl acetate isolated as a single product in 68% yield from the equimolar mixture of 1-pentanol and 3-pentanol.

(S)-Selective Kinetic Resolution and Chemoenzymatic Dynamic Kinetic Resolution of Secondary Alcohols.

ChemInform ◽  
2006 ◽  
Vol 37 (16) ◽  
Author(s):  
Linnea Boren ◽  
Belen Martin-Matute ◽  
Yongmei Xu ◽  
Armando Cordova ◽  
Jan-E. Baeckvall
Keyword(s):  
Kinetic Resolution ◽  
Secondary Alcohols ◽  
Dynamic Kinetic Resolution

ChemInform Abstract: Kinetic Resolution of Racemic Secondary Alcohols by Ru(II)-Catalyzed Hydrogen Transfer.

ChemInform ◽  
2010 ◽  
Vol 28 (19) ◽  
pp. no-no
Author(s):  
S. HASHIGUCHI ◽  
A. FUJII ◽  
K.-J. HAACK ◽  
K. MATSUMURA ◽  
T. IKARIYA ◽  
...  
Keyword(s):  
Hydrogen Transfer ◽  
Kinetic Resolution ◽  
Secondary Alcohols

Efficient dynamic kinetic resolution of secondary alcohols with a novel tetrafluorosuccinato ruthenium complex

2006 ◽  
Vol 17 (15) ◽  
pp. 2299-2305 ◽  
Author(s):  
Sjoerd F.G.M. van Nispen ◽  
Jeroen van Buijtenen ◽  
Jef A.J.M. Vekemans ◽  
Jan Meuldijk ◽  
Lumbertus A. Hulshof
Keyword(s):  
Kinetic Resolution ◽  
Ruthenium Complex ◽  
Secondary Alcohols ◽  
Dynamic Kinetic Resolution

Lipase-mediated dynamic kinetic resolution (DKR) of secondary alcohols in the presence of zeolite using an ionic liquid solvent system

2015 ◽  
Vol 255 ◽  
pp. 41-48 ◽  
Author(s):  
Ken-ichi Shimomura ◽  
Hiroyuki Harami ◽  
Yui Matsubara ◽  
Toshiki Nokami ◽  
Naonobu Katada ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Kinetic Resolution ◽  
Solvent System ◽  
Secondary Alcohols ◽  
Dynamic Kinetic Resolution
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