scholarly journals Making or Breaking Metal‐Dependent Catalytic Activity: The Role of Stammers in Designed Three‐Stranded Coiled Coils

2020 ◽  
Vol 59 (46) ◽  
pp. 20445-20449
Author(s):  
Tyler B. J. Pinter ◽  
Elizabeth C. Manickas ◽  
Audrey E. Tolbert ◽  
Karl J. Koebke ◽  
Aniruddha Deb ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coiled Coils

scholarly journals Making or Breaking Metal‐Dependent Catalytic Activity: The Role of Stammers in Designed Three‐Stranded Coiled Coils

2020 ◽  
Vol 132 (46) ◽  
pp. 20625-20629
Author(s):  
Tyler B. J. Pinter ◽  
Elizabeth C. Manickas ◽  
Audrey E. Tolbert ◽  
Karl J. Koebke ◽  
Aniruddha Deb ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coiled Coils

Catalytic Activity of Binary and Triple Systems Based on Redox Inactive Metal Compound, LiSt and Additives of Monodentate Ligands-Modifiers: DMF, HMPA and PhOH, in Selective Ethylbenzene Oxidation with Dioxygen

2016 ◽  
Vol 10 (3) ◽  
pp. 259-270
Author(s):  
Ludmila Matienko ◽  
◽  
Larisa Mosolova ◽  
Vladimir Binyukov ◽  
Gennady Zaikov ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Triple System ◽  
Metal Compound ◽  
Ethylbenzene Oxidation ◽  
Catalytic Systems ◽  
Triple Systems ◽  
Lithium Compound ◽  
Mechanism Of Catalysis ◽  
Monodentate Ligands

Mechanism of catalysis with binary and triple catalytic systems based on redox inactive metal (lithium) compound {LiSt+L2} and {LiSt+L2+PhOH} (L2=DMF or HMPA), in the selective ethylbenzene oxidation by dioxygen into -phenylethyl hydroperoxide is researched. The results are compared with catalysis by nickel-lithium triple system {NiII(acac)2+LiSt+PhOH} in selective ethylbenzene oxidation to PEH. The role of H-bonding in mechanism of catalysis is discussed. The possibility of the stable supramolecular nanostructures formation on the basis of triple systems, {LiSt+L2+PhOH}, due to intermolecular H-bonds, is researched with the AFM method.

scholarly journals Role of CO2 During Oxidative Dehydrogenation of Propane Over Bulk and Activated-Carbon Supported Cerium and Vanadium Based Catalysts

2021 ◽  
Author(s):  
Petar Djinović ◽  
Janez Zavašnik ◽  
Janvit Teržan ◽  
Ivan Jerman
Keyword(s):  
Catalytic Activity ◽  
Activated Carbon ◽  
Oxidative Dehydrogenation ◽  
Active Phase ◽  
Lattice Oxygen ◽  
Chemisorbed Oxygen ◽  
Catalytically Active ◽  
Temperature Programmed ◽  
Propane Cracking

AbstractCeO2, V2O5 and CeVO4 were synthesised as bulk oxides, or deposited over activated carbon, characterized by XRD, HRTEM, CO2-TPO, C3H8-TPR, DRIFTS and Raman techniques and tested in propane oxidative dehydrogenation using CO2. Complete oxidation of propane to CO and CO2 is favoured by lattice oxygen of CeO2. The temperature programmed experiments show the ~ 4 nm AC supported CeO2 crystallites become more susceptible to reduction by propane, but less prone to re-oxidation with CO2 compared to bulk CeO2. Catalytic activity of CeVO4/AC catalysts requires a 1–2 nm amorphous CeVO4 layer. During reaction, the amorphous CeVO4 layer crystallises and several atomic layers of carbon cover the CeVO4 surface, resulting in deactivation. During reaction, V2O5 is irreversibly reduced to V2O3. The lattice oxygen in bulk V2O5 favours catalytic activity and propene selectivity. Bulk V2O3 promotes only propane cracking with no propene selectivity. In VOx/AC materials, vanadium carbide is the catalytically active phase. Propane dehydrogenation over VC proceeds via chemisorbed oxygen species originating from the dissociated CO2. Graphic Abstract

scholarly journals Role of arginine 292 in the catalytic activity of chondroitin AC lyase from Flavobacterium heparinum

2002 ◽  
Vol 1597 (2) ◽  
pp. 260-270 ◽  
Author(s):  
Ishan Capila ◽  
Yi Wu ◽  
David W Rethwisch ◽  
Allan Matte ◽  
Miroslaw Cygler ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Chondroitin Ac Lyase ◽  
Flavobacterium Heparinum

Isomerization ofn-butane on sulfated zirconia: Evidence for the dominant role of Lewis acidity on the catalytic activity

1994 ◽  
Vol 26 (3-4) ◽  
pp. 339-344 ◽  
Author(s):  
F. Pinna ◽  
M. Signoretto ◽  
G. Strukul ◽  
G. Cerrato ◽  
C. Morterra
Keyword(s):  
Catalytic Activity ◽  
Sulfated Zirconia ◽  
Dominant Role ◽  
Lewis Acidity

scholarly journals A green approach to the synthesis of a nano catalyst and the role of basicity, calcination, catalytic activity and aging in the green synthesis of 2-aryl bezimidazoles, benzothiazoles and benzoxazoles

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42000-42012 ◽  
Author(s):  
Pramod K. Sahu
Keyword(s):  
Catalytic Activity ◽  
Green Synthesis ◽  
Room Temperature ◽  
Molar Ratios ◽  
Green Approach ◽  
Grinding Method ◽  
Nano Catalyst ◽  
Layered Catalyst

A green synthesis of hydrotalcite (a double layered catalyst) by a grinding method using Al/Mg molar ratios of 1.0–3.0 at room temperature is described.

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