Enantioselective Syntheses of Strychnos and Chelidonium Alkaloids through Regio‐ and Stereocontrolled Cooperative Catalysis

2020 ◽  
Vol 59 (40) ◽  
pp. 17556-17564
Author(s):  
Luke S. Hutchings‐Goetz ◽  
Chao Yang ◽  
James W. B. Fyfe ◽  
Thomas N. Snaddon
2020 ◽  
Vol 132 (40) ◽  
pp. 17709-17717
Author(s):  
Luke S. Hutchings‐Goetz ◽  
Chao Yang ◽  
James W. B. Fyfe ◽  
Thomas N. Snaddon

2015 ◽  
Vol 127 (23) ◽  
pp. 7004-7008 ◽  
Author(s):  
Ashkaan Younai ◽  
Bi-Shun Zeng ◽  
Herbert Y. Meltzer ◽  
Karl A. Scheidt

2018 ◽  
Vol 15 (2) ◽  
pp. 221-229 ◽  
Author(s):  
Shah Bakhtiar Nasir ◽  
Noorsaadah Abd Rahman ◽  
Chin Fei Chee

Background: The Diels-Alder reaction has been widely utilised in the syntheses of biologically important natural products over the years and continues to greatly impact modern synthetic methodology. Recent discovery of chiral organocatalysts, auxiliaries and ligands in organic synthesis has paved the way for their application in Diels-Alder chemistry with the goal to improve efficiency as well as stereochemistry. Objective: The review focuses on asymmetric syntheses of flavonoid Diels-Alder natural products that utilize chiral ligand-Lewis acid complexes through various illustrative examples. Conclusion: It is clear from the review that a significant amount of research has been done investigating various types of catalysts and chiral ligand-Lewis acid complexes for the enantioselective synthesis of flavonoid Diels-Alder natural products. The results have demonstrated improved yield and enantioselectivity. Much emphasis has been placed on the synthesis but important mechanistic work aimed at understanding the enantioselectivity has also been discussed.


2021 ◽  
Vol 503 ◽  
pp. 111415
Author(s):  
Di Wu ◽  
Qingqing Bu ◽  
Cheng Guo ◽  
Bin Dai ◽  
Ning Liu

ACS Catalysis ◽  
2021 ◽  
pp. 10789-10795
Author(s):  
Hongyu Guo ◽  
Sheng Zhang ◽  
Xiaoqiang Yu ◽  
Xiujuan Feng ◽  
Yoshinori Yamamoto ◽  
...  

2021 ◽  
Vol 86 (5) ◽  
pp. 3999-4006
Author(s):  
Cynthia M. Hong ◽  
Aaron M. Whittaker ◽  
Danielle M. Schultz

Author(s):  
Huijie Pan ◽  
Gangfeng Huang ◽  
Matthew Wodrich ◽  
Farzaneh Fadaei Tirani ◽  
Kenichi Ataka ◽  
...  

Author(s):  
Xiao-Chao CHEN ◽  
Yin-Qing YAO ◽  
Kai-Chun Zhao ◽  
Lei LIU ◽  
Yong LU ◽  
...  

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