Formation of Short Zn−Zn Bonds Stabilized by Simple Cyanide and Isocyanide Ligands

2020 ◽  
Vol 59 (6) ◽  
pp. 2496-2504 ◽  
Author(s):  
Lester Andrews ◽  
Han‐Gook Cho
Keyword(s):  
Isocyanide Ligands

Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties

2021 ◽  
Vol 91 (3) ◽  
pp. 393-400
Author(s):  
S. A. Katkova ◽  
I. I. Eliseev ◽  
A. S. Mikherdov ◽  
E. V. Sokolova ◽  
G. L. Starova ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Isocyanide Ligands

Coupling of trifluoromethyl isocyanide ligands in binuclear iron carbonyl complexes

2014 ◽  
Vol 166 ◽  
pp. 34-43 ◽  
Author(s):  
Guoliang Li ◽  
Lihua Liu ◽  
Jing Wang ◽  
Qian-shu Li ◽  
Yaoming Xie ◽  
...  
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Isocyanide Ligands ◽  
Binuclear Iron

The lowest energy excited states of the binuclear silver(I) halide complexes, Ag2(dmb)2X2. Metal-centered or charge transfer states?

1994 ◽  
Vol 72 (3) ◽  
pp. 705-713 ◽  
Author(s):  
Daniel Piché ◽  
Pierre D. Harvey
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Excited States ◽  
Silver Halide ◽  
Molecular Orbital Calculations ◽  
Isocyanide Ligands ◽  
Visible Spectra ◽  
Halide Complexes ◽  
The Media ◽  
Uv Visible

The nature of the lowest energy excited states of the Ag2(dmb)2X2 complexes (X = Cl, Br, I; dmb = 1,8-diisocyano-ρ-menthane) have been addressed both experimentally and theoretically. It is shown that the lowest energy excited states of the complexes are charge transfer states from the silver-halide frame to the isocyanide ligands (M/XLCT) based upon UV-visible spectra and emission polarization ratio measurements, and extended Hückel molecular orbital calculations (EHMO). The metal-centered dσ* → pσ bands have been observed in the higher energy region of the spectra (232–242 nm). The complexes are luminescent (440 ≤ λe ≤ 480 nm) both in a glass and in the solid state at 77 K where the emission lifetimes, τe, range from 20 to 90 µs, which depend upon the nature of the halide (for the solid state data) and the media. No emission is observed at room temperature.

Formation of thiolate-bridged diiron complexes featuring anionic isocyanide originated from the activation of counterions in the outer sphere

2021 ◽  
Author(s):  
Sunlin Xu ◽  
Dawei Yang ◽  
Jinfeng Zhao ◽  
Baomin Wang ◽  
Jingping Qu
Keyword(s):  
Transition Metal ◽  
Outer Sphere ◽  
Organic Transformations ◽  
Isocyanide Ligands

Transition metal isocyanide complexes have attracted increasing attention owing to their versatile applications in catalytic organic transformations. Compared with metallic complexes with neutral isocyanide ligands, those featuring anionic isocyanide groups...

Preference of carbonyl ligands over isocyanide ligands in nucleophile-induced coupling with alkylidyne ligands

1992 ◽  
Vol 11 (12) ◽  
pp. 4358-4362 ◽  
Author(s):  
Andreas Mayr ◽  
Stephen M. Holmes ◽  
Cecilia M. Bastos
Keyword(s):  
Isocyanide Ligands ◽  
Carbonyl Ligands
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