Dynamic Control of Chiral Space Through Local Symmetry Breaking in a Rotaxane Organocatalyst

2019 ◽  
Vol 58 (42) ◽  
pp. 14955-14958 ◽  
Author(s):  
Marcel Dommaschk ◽  
Javier Echavarren ◽  
David A. Leigh ◽  
Vanesa Marcos ◽  
Thomas A. Singleton
Keyword(s):  
Symmetry Breaking ◽  
Dynamic Control ◽  
Local Symmetry

Dynamic Control of Chiral Space Through Local Symmetry Breaking in a Rotaxane Organocatalyst

2019 ◽  
Vol 131 (42) ◽  
pp. 15097-15100 ◽  
Author(s):  
Marcel Dommaschk ◽  
Javier Echavarren ◽  
David A. Leigh ◽  
Vanesa Marcos ◽  
Thomas A. Singleton
Keyword(s):  
Symmetry Breaking ◽  
Dynamic Control ◽  
Local Symmetry

Pressure-induced local symmetry breaking upon liquid–liquid transition of GeI4 and SnI4

2019 ◽  
Vol 150 (11) ◽  
pp. 114501 ◽  
Author(s):  
Kazuhiro Fuchizaki ◽  
Takahiro Sakagami ◽  
Hiroshi Iwayama
Keyword(s):  
Symmetry Breaking ◽  
Local Symmetry ◽  
Liquid Transition

scholarly journals Lattice dynamics reveals a local symmetry breaking in the emergent dipole phase of PbTe

2012 ◽  
Vol 86 (8) ◽  
Author(s):  
Kirsten M. Ø. Jensen ◽  
Emil S. Božin ◽  
Christos D. Malliakas ◽  
Matthew B. Stone ◽  
Mark D. Lumsden ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Lattice Dynamics ◽  
Local Symmetry

Local symmetry breaking inK2V3O8as studied by infrared spectroscopy

2001 ◽  
Vol 65 (5) ◽  
Author(s):  
J. Choi ◽  
Z. T. Zhu ◽  
J. L. Musfeldt ◽  
G. Ragghianti ◽  
D. Mandrus ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Symmetry Breaking ◽  
Local Symmetry

scholarly journals Chiral symmetry breaking in hidden local symmetry

1995 ◽  
Vol 108 (9) ◽  
pp. 1051-1067 ◽  
Author(s):  
S. Furui ◽  
R. Kobayashi ◽  
M. Nakagawa
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Chiral Symmetry Breaking ◽  
Local Symmetry

Photoinduced Local Symmetry Breaking in SrTiO3

2013 ◽  
Vol 6 (6) ◽  
pp. 061501 ◽  
Author(s):  
Shunsuke Nozawa ◽  
Toshiaki Iwazumi ◽  
Hitoshi Osawa ◽  
Takayuki Uozumi
Keyword(s):  
Symmetry Breaking ◽  
Local Symmetry

scholarly journals Pattern-induced local symmetry breaking in active-matter systems

2020 ◽  
Vol 117 (50) ◽  
pp. 31623-31630
Author(s):  
Jonas Denk ◽  
Erwin Frey
Keyword(s):  
Symmetry Breaking ◽  
Biological Systems ◽  
Local Symmetry ◽  
Theoretical Explanation ◽  
Feedback Mechanism ◽  
Hydrodynamic Theory ◽  
Active Matter ◽  
Theoretical Understanding ◽  
Self Organized ◽  
Microscopic Interactions

The emergence of macroscopic order and patterns is a central paradigm in systems of (self-)propelled agents and a key component in the structuring of many biological systems. The relationships between the ordering process and the underlying microscopic interactions have been extensively explored both experimentally and theoretically. While emerging patterns often show one specific symmetry (e.g., nematic lane patterns or polarized traveling flocks), depending on the symmetry of the alignment interactions patterns with different symmetries can apparently coexist. Indeed, recent experiments with an actomysin motility assay suggest that polar and nematic patterns of actin filaments can interact and dynamically transform into each other. However, theoretical understanding of the mechanism responsible remains elusive. Here, we present a kinetic approach complemented by a hydrodynamic theory for agents with mixed alignment symmetries, which captures the experimentally observed phenomenology and provides a theoretical explanation for the coexistence and interaction of patterns with different symmetries. We show that local, pattern-induced symmetry breaking can account for dynamically coexisting patterns with different symmetries. Specifically, in a regime with moderate densities and a weak polar bias in the alignment interaction, nematic bands show a local symmetry-breaking instability within their high-density core region, which induces the formation of polar waves along the bands. These instabilities eventually result in a self-organized system of nematic bands and polar waves that dynamically transform into each other. Our study reveals a mutual feedback mechanism between pattern formation and local symmetry breaking in active matter that has interesting consequences for structure formation in biological systems.

Fano-resonance collapse induced terahertz magnetic dipole oscillation in complementary meta-atoms via local symmetry breaking

2019 ◽  
Vol 125 (14) ◽  
pp. 143102 ◽  
Author(s):  
Zhidong Gu ◽  
Zhenyu Zhao ◽  
Hui Zhao ◽  
Wei Peng ◽  
Jianbing Zhang ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Magnetic Dipole ◽  
Fano Resonance ◽  
Local Symmetry ◽  
Dipole Oscillation
Sign in / Sign up

Export Citation Format

Share Document