A Water-Soluble Perylene Bisimide Cyclophane as a Molecular Probe for the Recognition of Aromatic Alkaloids

2019 ◽  
Vol 58 (11) ◽  
pp. 3516-3520 ◽  
Author(s):  
Meike Sapotta ◽  
Anja Hofmann ◽  
David Bialas ◽  
Frank Würthner
Keyword(s):  
Water Soluble ◽  
Molecular Probe ◽  
Perylene Bisimide

A Water-Soluble Perylene Bisimide Cyclophane as a Molecular Probe for the Recognition of Aromatic Alkaloids

2019 ◽  
Vol 131 (11) ◽  
pp. 3554-3558 ◽  
Author(s):  
Meike Sapotta ◽  
Anja Hofmann ◽  
David Bialas ◽  
Frank Würthner
Keyword(s):  
Water Soluble ◽  
Molecular Probe ◽  
Perylene Bisimide

Water soluble perylene bisimide and its turn off/on fluorescence are used to detect cysteine and homocysteine

2015 ◽  
Vol 39 (7) ◽  
pp. 5084-5087 ◽  
Author(s):  
Pradip K. Sukul ◽  
Dines C. Santra ◽  
Pradeep K. Singh ◽  
Samir K. Maji ◽  
Sudip Malik
Keyword(s):  
Water Soluble ◽  
Perylene Bisimide

Herein, we have reported a perylene based supramolecular chemo-sensing probe which can detect cysteine or homocysteine over glutathione at physiological pH.

scholarly journals Insight into the Self-Assembly of Water-Soluble Perylene Bisimide Derivatives Through a Combined Computational and Experimental Approach

2019 ◽  
Author(s):  
Emily R. Draper ◽  
Liam Wilbraham ◽  
Dave J. Adams ◽  
Matthew Wallace ◽  
Martijn Zwijnenburg
Keyword(s):  
Density Functional Theory ◽  
Self Assembly ◽  
Density Functional ◽  
Colloidal Stability ◽  
Water Soluble ◽  
The Self ◽  
Functional Theory ◽  
Perylene Bisimide ◽  
Aggregate Growth ◽  
Perylene Bisimides

We use a combination of computational and experimental techniques to study the self-assembly and gelation of water-soluble perylene bisimides derivatised at the imide position with an amino acid. Specifically, we study the likely structure of self-assembled aggregates of the alanine-functionalised perylene bisimide (PBI-A) and the thermodynamics of their formation using density functional theory and predict the UV-vis spectra of such aggregates using time-dependent density functional theory. We compare these predictions to experiments in which we study the evolution of the UV-Vis and NMR spectra and rheology of alkaline PBI-A solutions when gradually decreasing the pH. Based on the combined computational and experimental results, we show that PBI-A self-assembles at all pH values but that aggregates grow in size upon protonation. Gelation is driven not by aggregate growth but reduction of the aggregation surface-charge and a decrease in the colloidal stability of the aggregation with respect to agglomeration.

scholarly journals Insight into the self-assembly of water-soluble perylene bisimide derivatives through a combined computational and experimental approach

Nanoscale ◽  
2019 ◽  
Vol 11 (34) ◽  
pp. 15917-15928 ◽  
Author(s):  
Emily R. Draper ◽  
Liam Wilbraham ◽  
Dave J. Adams ◽  
Matthew Wallace ◽  
Ralf Schweins ◽  
...  
Keyword(s):  
Amino Acid ◽  
Self Assembly ◽  
Experimental Approach ◽  
Water Soluble ◽  
The Self ◽  
Experimental Techniques ◽  
Perylene Bisimide ◽  
Perylene Bisimides ◽  
Insight Into

We use a combination of computational and experimental techniques to study the self-assembly and gelation of amino-acid functionalised water-soluble perylene bisimides.

Sensing of Double-Stranded DNA/RNA Secondary Structures by Water Soluble Homochiral Perylene Bisimide Dyes

2015 ◽  
Vol 21 (21) ◽  
pp. 7886-7895 ◽  
Author(s):  
Jana Gershberg ◽  
Marijana Radić Stojković ◽  
Marko Škugor ◽  
Sanja Tomić ◽  
Thomas H. Rehm ◽  
...  
Keyword(s):  
Secondary Structures ◽  
Water Soluble ◽  
Rna Secondary Structures ◽  
Perylene Bisimide ◽  
Double Stranded Dna

scholarly journals Insight into the Self-Assembly of Water-Soluble Perylene Bisimide Derivatives Through a Combined Computational and Experimental Approach

2019 ◽  
Author(s):  
Emily R. Draper ◽  
Liam Wilbraham ◽  
Dave J. Adams ◽  
Matthew Wallace ◽  
Martijn Zwijnenburg
Keyword(s):  
Density Functional Theory ◽  
Self Assembly ◽  
Density Functional ◽  
Colloidal Stability ◽  
Water Soluble ◽  
The Self ◽  
Functional Theory ◽  
Perylene Bisimide ◽  
Aggregate Growth ◽  
Perylene Bisimides

We use a combination of computational and experimental techniques to study the self-assembly and gelation of water-soluble perylene bisimides derivatised at the imide position with an amino acid. Specifically, we study the likely structure of self-assembled aggregates of the alanine-functionalised perylene bisimide (PBI-A) and the thermodynamics of their formation using density functional theory and predict the UV-vis spectra of such aggregates using time-dependent density functional theory. We compare these predictions to experiments in which we study the evolution of the UV-Vis and NMR spectra and rheology of alkaline PBI-A solutions when gradually decreasing the pH. Based on the combined computational and experimental results, we show that PBI-A self-assembles at all pH values but that aggregates grow in size upon protonation. Gelation is driven not by aggregate growth but reduction of the aggregation surface-charge and a decrease in the colloidal stability of the aggregation with respect to agglomeration.

Synthesis of highly fluorescent and water soluble perylene bisimide

2012 ◽  
Vol 23 (2) ◽  
pp. 149-153 ◽  
Author(s):  
Gopal Boobalan ◽  
Predhanekar Mohamed Imran ◽  
Samuthira Nagarajan
Keyword(s):  
Water Soluble ◽  
Perylene Bisimide

Perylene bisimide-incorporated water-soluble polyurethanes for living cell fluorescence labeling

Polymer ◽  
2016 ◽  
Vol 82 ◽  
pp. 172-180 ◽  
Author(s):  
Liang Wang ◽  
Chen Sun ◽  
Shuofeng Li ◽  
Ning Jia ◽  
Jian Li ◽  
...  
Keyword(s):  
Living Cell ◽  
Water Soluble ◽  
Fluorescence Labeling ◽  
Perylene Bisimide
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