Elusive Zintl Ions [μ‐HSi 4 ] 3− and [Si 5 ] 2− in Liquid Ammonia: Protonation States, Sites, and Bonding Situation Evaluated by NMR and Theory

2019 ◽  
Vol 58 (10) ◽  
pp. 3133-3137 ◽  
Author(s):  
Florian Hastreiter ◽  
Corinna Lorenz ◽  
Johnny Hioe ◽  
Stefanie Gärtner ◽  
Nanjundappa Lokesh ◽  
...  
Keyword(s):  
Liquid Ammonia ◽  
Zintl Ions

Detection of the Elusive Highly Charged Zintl Ions Si44−and Sn44−in Liquid Ammonia by NMR Spectroscopy

2013 ◽  
Vol 52 (16) ◽  
pp. 4483-4486 ◽  
Author(s):  
Maria Neumeier ◽  
Franziska Fendt ◽  
Stefanie Gärtner ◽  
Carina Koch ◽  
Tobias Gärtner ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Liquid Ammonia ◽  
Zintl Ions

ChemInform Abstract: Detection of the Elusive Highly Charged Zintl Ions Si44-and Sn44-in Liquid Ammonia by NMR Spectroscopy.

ChemInform ◽  
2013 ◽  
Vol 44 (28) ◽  
pp. no-no
Author(s):  
Maria Neumeier ◽  
Franziska Fendt ◽  
Stefanie Gaertner ◽  
Carina Koch ◽  
Tobias Gaertner ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Liquid Ammonia ◽  
Zintl Ions

scholarly journals Back Cover: Detection of the Elusive Highly Charged Zintl Ions Si44−and Sn44−in Liquid Ammonia by NMR Spectroscopy (Angew. Chem. Int. Ed. 16/2013)

2013 ◽  
Vol 52 (16) ◽  
pp. 4494-4494 ◽  
Author(s):  
Maria Neumeier ◽  
Franziska Fendt ◽  
Stefanie Gärtner ◽  
Carina Koch ◽  
Tobias Gärtner ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Liquid Ammonia ◽  
Back Cover ◽  
Zintl Ions

Elusive Zintl Ions [μ‐HSi 4 ] 3− and [Si 5 ] 2− in Liquid Ammonia: Protonation States, Sites, and Bonding Situation Evaluated by NMR and Theory

2019 ◽  
Vol 131 (10) ◽  
pp. 3165-3169 ◽  
Author(s):  
Florian Hastreiter ◽  
Corinna Lorenz ◽  
Johnny Hioe ◽  
Stefanie Gärtner ◽  
Nanjundappa Lokesh ◽  
...  
Keyword(s):  
Liquid Ammonia ◽  
Zintl Ions

Ammonolysis of titanium tetrachloride in liquid ammonia

1976 ◽  
Vol 73 ◽  
pp. 849-851 ◽  
Author(s):  
Thomas Kottarathil ◽  
Gérard Lepoutre
Keyword(s):  
Liquid Ammonia ◽  
Titanium Tetrachloride

Solubility of argon, and gaseous mixture argon-methane-nitrogen in liquid ammonia

1970 ◽  
Vol 35 (12) ◽  
pp. 3757-3761 ◽  
Author(s):  
J. Matouš ◽  
J. Šobr ◽  
J. P. Novák
Keyword(s):  
Liquid Ammonia ◽  
Gaseous Mixture

Preparation, properties and structure of some intermediate nido- and arachno-monocarbaboranes

1981 ◽  
Vol 46 (10) ◽  
pp. 2345-2353 ◽  
Author(s):  
Karel Baše ◽  
Bohumil Štíbr ◽  
Jiří Dolanský ◽  
Josef Duben
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nmr Spectra ◽  
Liquid Ammonia ◽  
X Ray Diffraction ◽  
X Ray ◽  
H Nmr ◽  
Starting Compound

The 6-N(CH3)3-6-CB9H11 carbaborane reacts with sodium in liquid ammonia with the formation of 6-CB9H12- which was used as a starting compound for preparing the 4-CB8H14, 9-L-6-CB9H13 (L = (CH3)2S, CH3CN and P(C6H5)3), 1-(η5-C5H5)-1,2-FeCB9H10-, and 2,3-(η5-C5H5)2-2,31-Co2CB9H10- carboranes. The 4-CB8H14 compound was dehydrogenated at 623 K to give 4-(7)-CB8H12 carborane. Base degradation of 6-N(CH3)3-6-CB9H11 in methanol resulted in the formation of 3,4-μ-N(CH3)3CH-B5H10. The structure of all compounds was proposed on the basis of their 11B and 1H NMR spectra and X-ray diffraction was used in the case of the transition metal complexes.

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