scholarly journals Evolution of Oxygen–Metal Electron Transfer and Metal Electronic States During Manganese Oxide Catalyzed Water Oxidation Revealed with In Situ Soft X‐Ray Spectroscopy

2019 ◽  
Vol 58 (11) ◽  
pp. 3426-3432 ◽  
Author(s):  
Marc F. Tesch ◽  
Shannon A. Bonke ◽  
Travis E. Jones ◽  
Maryam N. Shaker ◽  
Jie Xiao ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Manganese Oxide ◽  
Water Oxidation ◽  
Electronic States ◽  
X Ray ◽  
Evolution Of Oxygen ◽  
Metal Electron

scholarly journals Evolution of Oxygen–Metal Electron Transfer and Metal Electronic States During Manganese Oxide Catalyzed Water Oxidation Revealed with In Situ Soft X‐Ray Spectroscopy

2019 ◽  
Vol 131 (11) ◽  
pp. 3464-3470 ◽  
Author(s):  
Marc F. Tesch ◽  
Shannon A. Bonke ◽  
Travis E. Jones ◽  
Maryam N. Shaker ◽  
Jie Xiao ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Manganese Oxide ◽  
Water Oxidation ◽  
Electronic States ◽  
X Ray ◽  
Evolution Of Oxygen ◽  
Metal Electron

Direct Observation of Active Nickel Oxide Cluster in Nickel–Borate Electrocatalyst for Water Oxidation by In Situ O K-Edge X-ray Absorption Spectroscopy

2015 ◽  
Vol 119 (33) ◽  
pp. 19279-19286 ◽  
Author(s):  
Masaaki Yoshida ◽  
Yosuke Mitsutomi ◽  
Takehiro Mineo ◽  
Masanari Nagasaka ◽  
Hayato Yuzawa ◽  
...  
Keyword(s):  
Nickel Oxide ◽  
Absorption Spectroscopy ◽  
Direct Observation ◽  
Water Oxidation ◽  
Oxide Cluster ◽  
X Ray ◽  
X Ray Absorption

scholarly journals Redox Processes of Manganese Oxide in Catalyzing Oxygen Evolution and Reduction: An in Situ Soft X-ray Absorption Spectroscopy Study

2017 ◽  
Vol 121 (33) ◽  
pp. 17682-17692 ◽  
Author(s):  
Marcel Risch ◽  
Kelsey A. Stoerzinger ◽  
Binghong Han ◽  
Tom Z. Regier ◽  
Derek Peak ◽  
...  
Keyword(s):  
Manganese Oxide ◽  
Oxygen Evolution ◽  
Absorption Spectroscopy ◽  
Redox Processes ◽  
Spectroscopy Study ◽  
X Ray ◽  
X Ray Absorption

scholarly journals Development of a soft X-ray angle-resolved photoemission system applicable to 100 µm crystals

2011 ◽  
Vol 18 (6) ◽  
pp. 879-884 ◽  
Author(s):  
Takayuki Muro ◽  
Yukako Kato ◽  
Tomohiro Matsushita ◽  
Toyohiko Kinoshita ◽  
Yoshio Watanabe ◽  
...  
Keyword(s):  
Electronic States ◽  
Spot Size ◽  
Optical Microscope ◽  
Photoemission Spectroscopy ◽  
Beam Spot ◽  
X Ray ◽  
Angle Resolved Photoemission Spectroscopy ◽  
Clear Band ◽  
Sample Position

A system for angle-resolved photoemission spectroscopy (ARPES) of small single crystals with sizes down to 100 µm has been developed. Soft X-ray synchrotron radiation with a spot size of ∼40 µm × 65 µm at the sample position is used for the excitation. Using this system an ARPES measurement has been performed on a Si crystal of size 120 µm × 100 µm × 80 µm. The crystal was properly oriented on a sample stage by measuring the Laue spots. The crystal was cleavedin situwith a microcleaver at 100 K. The cleaved surface was adjusted to the beam spot using an optical microscope. Consequently, clear band dispersions along the Γ–Xdirection reflecting the bulk electronic states were observed with a photon energy of 879 eV.

In situ Synthesis of Mixed-Valent Manganese Oxide Nanocrystals:  An In situ Synchrotron X-ray Diffraction Study

2006 ◽  
Vol 128 (14) ◽  
pp. 4570-4571 ◽  
Author(s):  
Xiong-Fei Shen ◽  
Yun-Shuang Ding ◽  
Jonathan C. Hanson ◽  
Mark Aindow ◽  
Steven L. Suib
Keyword(s):  
Manganese Oxide ◽  
Diffraction Study ◽  
In Situ Synthesis ◽  
X Ray Diffraction ◽  
X Ray

Valence- and element-dependent water oxidation behaviors: in situ X-ray diffraction, absorption and electrochemical impedance spectroscopies

2017 ◽  
Vol 19 (13) ◽  
pp. 8681-8693 ◽  
Author(s):  
Chia-Shuo Hsu ◽  
Nian-Tzu Suen ◽  
Ying-Ya Hsu ◽  
Hsuan-Yu Lin ◽  
Ching-Wei Tung ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Electrochemical Impedance ◽  
X Ray Diffraction ◽  
X Ray ◽  
Oxidation Behaviors

Various metal oxides of the spinel family have shown great potential towards the oxygen evolution reaction, but this behavior only works in specific cases.

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