scholarly journals Facile Fabrication of Concentrated Polymer Brushes with Complex Patterning by Photocontrolled Organocatalyzed Living Radical Polymerization

2018 ◽  
Vol 57 (41) ◽  
pp. 13504-13508 ◽  
Author(s):  
Chen-Gang Wang ◽  
Chen Chen ◽  
Keita Sakakibara ◽  
Yoshinobu Tsujii ◽  
Atsushi Goto
2018 ◽  
Vol 130 (41) ◽  
pp. 13692-13696 ◽  
Author(s):  
Chen-Gang Wang ◽  
Chen Chen ◽  
Keita Sakakibara ◽  
Yoshinobu Tsujii ◽  
Atsushi Goto

2015 ◽  
Vol 6 (14) ◽  
pp. 2726-2733 ◽  
Author(s):  
Tao Zhang ◽  
Yunhao Du ◽  
Felix Müller ◽  
Ihsan Amin ◽  
Rainer Jordan

We report on a new, extremely fast, very simple and versatile method to produce polymer brushes by surface-initiated controlled/living radical polymerization.


2005 ◽  
Vol 58 (6) ◽  
pp. 379 ◽  
Author(s):  
Graeme Moad ◽  
Ezio Rizzardo ◽  
San H. Thang

This paper presents a review of living radical polymerization achieved with thiocarbonylthio compounds [ZC(=S)SR] by a mechanism of reversible addition–fragmentation chain transfer (RAFT). Since we first introduced the technique in 1998, the number of papers and patents on the RAFT process has increased exponentially as the technique has proved to be one of the most versatile for the provision of polymers of well defined architecture. The factors influencing the effectiveness of RAFT agents and outcome of RAFT polymerization are detailed. With this insight, guidelines are presented on how to conduct RAFT and choose RAFT agents to achieve particular structures. A survey is provided of the current scope and applications of the RAFT process in the synthesis of well defined homo-, gradient, diblock, triblock, and star polymers, as well as more complex architectures including microgels and polymer brushes.


2016 ◽  
Vol 7 (20) ◽  
pp. 3471-3476 ◽  
Author(s):  
Taeseung Yang ◽  
Sang Koo Choi ◽  
Yea Ram Lee ◽  
Yoonki Cho ◽  
Jin Woong Kim

Novel associative nanoparticles (ANPs) are synthesized by grafting poly(2-methacryloyloxyethyl phosphorylcholine-co-stearyl methacrylate) polymer brushes on silica nanoparticles by using surface-mediated living radical polymerization.


2013 ◽  
Vol 46 (17) ◽  
pp. 6777-6785 ◽  
Author(s):  
Shigeru Yamago ◽  
Yoshikazu Yahata ◽  
Kouji Nakanishi ◽  
Shota Konishi ◽  
Eiichi Kayahara ◽  
...  

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