Direct Conversion of Syngas into Methyl Acetate, Ethanol, and Ethylene by Relay Catalysis via the Intermediate Dimethyl Ether

2018 ◽  
Vol 57 (37) ◽  
pp. 12012-12016 ◽  
Author(s):  
Wei Zhou ◽  
Jincan Kang ◽  
Kang Cheng ◽  
Shun He ◽  
Jiaqing Shi ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Direct Conversion

Direct Conversion of Syngas into Methyl Acetate, Ethanol, and Ethylene by Relay Catalysis via the Intermediate Dimethyl Ether

2018 ◽  
Vol 130 (37) ◽  
pp. 12188-12192 ◽  
Author(s):  
Wei Zhou ◽  
Jincan Kang ◽  
Kang Cheng ◽  
Shun He ◽  
Jiaqing Shi ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Direct Conversion

Direct Conversion of Dimethyl Ether and CO to Acetone via Coupling Carbonylation and Ketonization

2021 ◽  
Author(s):  
Ziqiao Zhou ◽  
Hongchao Liu ◽  
Youming Ni ◽  
Fuli Wen ◽  
Zhiyang Chen ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Direct Conversion

Selective Carbonylation of Dimethyl Ether to Methyl Acetate Catalyzed by Acidic Zeolites

2006 ◽  
Vol 45 (10) ◽  
pp. 1617-1620 ◽  
Author(s):  
Patricia Cheung ◽  
Aditya Bhan ◽  
Glenn J. Sunley ◽  
Enrique Iglesia
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Acidic Zeolites

Carbonylation of dimethyl ether over Co-HMOR

2018 ◽  
Vol 8 (8) ◽  
pp. 2124-2130 ◽  
Author(s):  
Meng Ma ◽  
Ensheng Zhan ◽  
Xiumin Huang ◽  
Na Ta ◽  
Zhiping Xiong ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate

Incorporation of Co2+ into the framework of HMOR significantly enhanced the activity for the carbonylation of dimethyl ether to methyl acetate.

A brand new zeolite catalyst for carbonylation reaction

2019 ◽  
Vol 55 (8) ◽  
pp. 1048-1051 ◽  
Author(s):  
Xiaobo Feng ◽  
Jie Yao ◽  
Hangjie Li ◽  
Yuan Fang ◽  
Yoshiharu Yoneyama ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Methyl Acetate ◽  
Zeolite Catalyst ◽  
Catalytic Performance ◽  
Carbonylation Reaction

EU-12 zeolite was discovered to posses unreported catalytic performance for carbonylation reaction converting dimethyl ether to methyl acetate.

scholarly journals Direct Conversion of CO2 into Dimethyl Ether over Al2O3/Cu/ZnO Catalysts Prepared by Sequential Precipitation

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 524 ◽  
Author(s):  
Cheonwoo Jeong ◽  
Jinsung Kim ◽  
Ji-Hyeon Kim ◽  
Sunghoon Lee ◽  
Jong Wook Bae ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Catalyst System ◽  
Direct Conversion ◽  
Mixed Metal Oxide ◽  
Oxide Materials ◽  
Co2 Conversion ◽  
Activity Test ◽  
Sequential Precipitation ◽  
Dual Bed ◽  
Complete Precipitation

Bifunctional Al2O3/Cu/ZnO catalysts with Al composition of between 30 mol% and 80 mol% were prepared by sequential precipitation (SP) for the conversion of CO2 into dimethyl ether (DME). In the SP synthesis, the concentration of a precipitation agent managed to be high enough to induce the complete precipitation of Al3+. The prepared precipitates were composed of zincian malachite and amorphous AlO(OH). Furthermore, the calcined mixed metal oxide materials of 60% and 80% Al exhibited a higher acidity than commercial Al2O3 and the H2-reduced catalysts showed the similar Cu dispersion of 6%–7% at all Cu loadings. In the activity test at 573 K and 50 bar, the SP-derived catalyst of 80% Al (SP-80) displayed the best performance corresponding to CO2 conversion of 25% and DME selectivity of 75% that are close to equilibrium values. In order to overcome the thermodynamic limitation, a dual-bed catalyst system was made up of SP-80 in the first layer and zeolite ferrierite in the next. This approach enabled DME selectivity to be enhanced to 90% while CO2 conversion increased a little. Consequently, the studied catalyst system based on the SP-derived catalysts can contribute greatly to selective DME production from CO2.

Vapor phase carbonylation of dimethyl ether and methyl acetate with nickel-active carbon catalysts

1983 ◽  
Vol 7 (3) ◽  
pp. 361-368 ◽  
Author(s):  
Tsutomu Shikada ◽  
Kaoru Fujimoto ◽  
Michiharu Miyauchi ◽  
Hiro-o Tominaga
Keyword(s):  
Dimethyl Ether ◽  
Vapor Phase ◽  
Active Carbon ◽  
Methyl Acetate ◽  
Carbon Catalysts
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