Copper‐Mediated Reversible Deactivation Radical Polymerization in Aqueous Media

2018 ◽  
Vol 57 (33) ◽  
pp. 10468-10482 ◽  
Author(s):  
Glen R. Jones ◽  
Athina Anastasaki ◽  
Richard Whitfield ◽  
Nikolaos Engelis ◽  
Evelina Liarou ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Aqueous Media ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

The effect of ligand, solvent and Cu(0) source on the efficient polymerization of polyether acrylates and methacrylates in aqueous and organic media

2015 ◽  
Vol 6 (32) ◽  
pp. 5940-5950 ◽  
Author(s):  
Alexandre Simula ◽  
Vasiliki Nikolaou ◽  
Fehaid Alsubaie ◽  
Athina Anastasaki ◽  
David M. Haddleton
Keyword(s):  
Radical Polymerization ◽  
Aqueous Media ◽  
Organic Media ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

The synthesis of well-defined telechelic polyacrylates and polymethacrylates in organic and aqueous media via Cu(0)-mediated reversible-deactivation radical polymerization is thoroughly investigated.

Photocontrolled iodine-mediated reversible-deactivation radical polymerization with a semifluorinated alternating copolymer as the macroinitiator

2020 ◽  
Vol 11 (47) ◽  
pp. 7497-7505
Author(s):  
Jiannan Cheng ◽  
Kai Tu ◽  
Enjie He ◽  
Jinying Wang ◽  
Lifen Zhang ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Room Temperature ◽  
Blue Led ◽  
Led Light ◽  
Alternating Copolymers ◽  
Alternating Copolymer ◽  
Reversible Deactivation ◽  
Novel Strategy ◽  
Reversible Deactivation Radical Polymerization

A novel strategy for preparing block copolymers with semifluorinated alternating copolymers as macroinitiators was established by photocontrolled iodine-mediated RDRP under irradiation with blue LED light at room temperature.

Copolymerization of simple methacrylates by Cu(0)-mediated reversible deactivation radical polymerization

2018 ◽  
Vol 51 (5) ◽  
pp. 449-459 ◽  
Author(s):  
Jongwon Choe ◽  
Woo Jung Lee ◽  
Han Gyeol Jang ◽  
Youngjoo Song ◽  
Jae Hyun Sim ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

Hexamethylphosphoramide as a highly reactive catalyst for the reversible-deactivation radical polymerization of MMA with an in situ formed alkyl iodide initiator

2017 ◽  
Vol 8 (39) ◽  
pp. 6073-6085 ◽  
Author(s):  
Yan-an Wang ◽  
Yan Shi ◽  
Zhifeng Fu ◽  
Wantai Yang
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Alkyl Iodide ◽  
Highly Efficient ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization ◽  
Organic Catalyst

A novel and highly efficient organic catalyst for the reversible-deactivation radical polymerization (RDRP) of methyl methacrylate with anin situformed alkyl iodide initiator.

scholarly journals Tunable Quantum Photoinitiators for Radical Photopolymerization

Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2694
Author(s):  
Shubhangi Shukla ◽  
Prem C. Pandey ◽  
Roger J. Narayan
Keyword(s):  
Quantum Dots ◽  
Metal Oxides ◽  
Radical Polymerization ◽  
Mechanism Of Action ◽  
Carbon Dots ◽  
Semiconductor Nanocrystals ◽  
Metal Sulfides ◽  
Cross Linking ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

This review describes the use of nanocrystal-based photocatalysts as quantum photoinitiators, including semiconductor nanocrystals (e.g., metal oxides, metal sulfides, quantum dots), carbon dots, graphene-based nanohybrids, plasmonic nanocomposites with organic photoinitiators, and tunable upconverting nanocomposites. The optoelectronic properties, cross-linking behavior, and mechanism of action of quantum photoinitiators are considered. The challenges and prospects associated with the use of quantum photoinitiators for processes such as radical polymerization, reversible deactivation radical polymerization, and photoinduced atom transfer radical polymerization are reviewed. Due to their unique capabilities, we forsee a growing role for quantum photoinitiators over the coming years.

scholarly journals Rapid Synthesis of Well-Defined Polyacrylamide by Aqueous Cu(0)-Mediated Reversible-Deactivation Radical Polymerization

2016 ◽  
Vol 49 (2) ◽  
pp. 483-489 ◽  
Author(s):  
Glen R. Jones ◽  
Zaidong Li ◽  
Athina Anastasaki ◽  
Danielle J. Lloyd ◽  
Paul Wilson ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Rapid Synthesis ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization
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