Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives

2018 ◽  
Vol 57 (46) ◽  
pp. 15002-15027 ◽  
Author(s):  
Heng Zhang ◽  
Gebrekidan Gebresilassie Eshetu ◽  
Xabier Judez ◽  
Chunmei Li ◽  
Lide M. Rodriguez‐Martínez ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Electrolyte Additives ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Metal Anodes

Flame-retardant single-ion conducting polymer electrolytes based on anion acceptors for high-safety lithium metal batteries

2021 ◽  
Author(s):  
Kuirong Deng ◽  
Tianyu Guan ◽  
Fuhui Liang ◽  
Xiaoqiong Zheng ◽  
Qingguang Zeng ◽  
...  
Keyword(s):  
Solid State ◽  
Flame Retardant ◽  
Conducting Polymer ◽  
Polymer Electrolytes ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Ion Conducting ◽  
Ion Conducting Polymer ◽  
Metal Anodes

Solid-state lithium metal batteries (LMBs) assembled with polymer electrolytes (PEs) and lithium metal anodes are promising batteries owing to their enhanced safeties and ultrahigh theoretical energy densities. Nevertheless, polymer electrolytes...

scholarly journals Lithium Metal Anodes: Uniform Lithium Nucleation Guided by Atomically Dispersed Lithiophilic CoN x Sites for Safe Lithium Metal Batteries (Small Methods 9/2019)

Small Methods ◽  
2019 ◽  
Vol 3 (9) ◽  
pp. 1970026 ◽  
Author(s):  
He Liu ◽  
Xiang Chen ◽  
Xin‐Bing Cheng ◽  
Bo‐Quan Li ◽  
Rui Zhang ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Metal Anodes

Dendrite-free carbon/lithium metal anodes for use in flexible lithium metal batteries

Carbon ◽  
2018 ◽  
Vol 130 ◽  
pp. 848 ◽  
Author(s):  
Xiao-ru Chen ◽  
Rui Zhang ◽  
Xin-bing Cheng ◽  
Qiang Zhang
Keyword(s):  
Free Carbon ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Metal Anodes

Revisiting the strategies for stabilizing lithium metal anodes

2020 ◽  
Vol 8 (28) ◽  
pp. 13874-13895 ◽  
Author(s):  
Ji Hyun Um ◽  
Kookhan Kim ◽  
Jungjin Park ◽  
Yung-Eun Sung ◽  
Seung-Ho Yu
Keyword(s):  
Lithium Metal ◽  
Future Perspectives ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Metal Anodes

This review focuses on a comprehensive summary of and future perspectives on stable lithium metal batteries.

Revisiting the Electroplating Process for Lithium‐Metal Anodes for Lithium‐Metal Batteries

2020 ◽  
Vol 132 (17) ◽  
pp. 6730-6739 ◽  
Author(s):  
Xiaowen Sun ◽  
Xinyue Zhang ◽  
Qingtao Ma ◽  
Xuze Guan ◽  
Wei Wang ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Electroplating Process ◽  
Metal Anodes

scholarly journals Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes

2021 ◽  
Vol 2021 ◽  
pp. 1-16
Author(s):  
Xiangbo Meng ◽  
Kah Chun Lau ◽  
Hua Zhou ◽  
Sujan Kumar Ghosh ◽  
Mourad Benamara ◽  
...  
Keyword(s):  
Molecular Layer ◽  
Solid Electrolyte Interphase ◽  
Lithium Metal ◽  
Molecular Layer Deposition ◽  
Lithium Metal Batteries ◽  
Layer Deposition ◽  
Lithium Metal Anodes ◽  
First Time ◽  
Metal Anodes

In this work, we for the first time developed a novel lithium-containing crosslinked polymeric material, a lithicone that enables excellent protection effects over lithium (Li) metal anodes. This new lithicone was synthesized via an accurately controllable molecular layer deposition (MLD) process, in which lithium tert-butoxide (LTB) and glycerol (GL) were used as precursors. The resultant LiGL lithicone was analyzed using a suite of characterizations. Furthermore, we found that the LiGL thichicone could serve as an exceptional polymeric protection film over Li metal anodes. Our experimental data revealed that the Li electrodes coated by this LiGL lithicone can achieve a superior cycling stability, accounting for an extremely long cyclability of >13,600 Li-stripping/plating cycles and having no failures so far in Li/Li symmetric cells at a current density of 5 mA/cm2 and an areal capacity of 1 mAh/cm2. We found that, with a sufficient protection by this LiGL coating, Li electrodes could realize long-term stable cyclability with little formation of Li dendrites and solid electrolyte interphase. This novel LiGL represents a facile and effective solution to the existing issues of Li anodes and potentially paves a technically feasible route for lithium metal batteries.

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