scholarly journals Ferrocene- and Biferrocene-Containing Macrocycles towards Single-Molecule Electronics

2017 ◽  
Vol 56 (24) ◽  
pp. 6838-6842 ◽  
Author(s):  
Lucy E. Wilson ◽  
Christopher Hassenrück ◽  
Rainer F. Winter ◽  
Andrew J. P. White ◽  
Tim Albrecht ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Electronics

scholarly journals Carbon tips for all-carbon single-molecule electronics

Nanoscale ◽  
2014 ◽  
Vol 6 (12) ◽  
pp. 6953-6958 ◽  
Author(s):  
Y. J. Dappe ◽  
C. González ◽  
J. C. Cuevas
Keyword(s):  
Ab Initio ◽  
Molecular Electronics ◽  
Single Molecule ◽  
Carbon Nanostructures ◽  
Molecular Junctions ◽  
Single Molecule Electronics ◽  
Single Molecule Junctions ◽  
Carbon Based

We present anab initiostudy of the use of carbon-based tips as electrodes in single-molecule junctions. We show that carbon tips can be combined with other carbon nanostructures to form all-carbon molecular junctions with molecules like benzene or C60. Results show that the use of carbon tips can lead to conductive molecular junctions and open new perspectives in all-carbon molecular electronics.

Functionality emergence of single molecule electronics

2015 ◽  
Author(s):  
Takuji Ogawa ◽  
Murni Handayani ◽  
Tomoko Inose ◽  
Takashi Tamaki ◽  
Minoru Fukumori ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Electronics

scholarly journals Electrical properties and mechanical stability of anchoring groups for single-molecule electronics

2015 ◽  
Vol 6 ◽  
pp. 1558-1567 ◽  
Author(s):  
Riccardo Frisenda ◽  
Simge Tarkuç ◽  
Elena Galán ◽  
Mickael L Perrin ◽  
Rienk Eelkema ◽  
...  
Keyword(s):  
Single Molecule ◽  
Density Functional ◽  
Mechanical Stability ◽  
Phenylene Ethynylene ◽  
Current Voltage ◽  
Single Molecule Electronics ◽  
Level Model ◽  
Anchoring Groups ◽  
Experimental Findings

We report on an experimental investigation of transport through single molecules, trapped between two gold nano-electrodes fabricated with the mechanically controlled break junction (MCBJ) technique. The four molecules studied share the same core structure, namely oligo(phenylene ethynylene) (OPE3), while having different aurophilic anchoring groups: thiol (SAc), methyl sulfide (SMe), pyridyl (Py) and amine (NH2). The focus of this paper is on the combined characterization of the electrical and mechanical properties determined by the anchoring groups. From conductance histograms we find that thiol anchored molecules provide the highest conductance; a single-level model fit to current–voltage characteristics suggests that SAc groups exhibit a higher electronic coupling to the electrodes, together with better level alignment than the other three groups. An analysis of the mechanical stability, recording the lifetime in a self-breaking method, shows that Py and SAc yield the most stable junctions while SMe form short-lived junctions. Density functional theory combined with non-equlibrium Green’s function calculations help in elucidating the experimental findings.

Electrical properties and mechanical stability of anchoring groups for single-molecule electronics

nano Online ◽  
2016 ◽  
Author(s):  
Riccardo Frisenda ◽  
Simge Tarkuç ◽  
Elena Galán ◽  
Mickael Perrin ◽  
Rienk Eelkema ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Single Molecule ◽  
Mechanical Stability ◽  
Single Molecule Electronics ◽  
Anchoring Groups
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