Sulfonium Ylides by (3+2) Cycloaddition of Arynes with Vinyl Sulfides: Stereoselective Synthesis of Highly Substituted Alkenes

2016 ◽  
Vol 55 (46) ◽  
pp. 14435-14438 ◽  
Author(s):  
Yuanming Li ◽  
Christian Mück-Lichtenfeld ◽  
Armido Studer
Keyword(s):  
Stereoselective Synthesis ◽  
Vinyl Sulfides ◽  
Sulfonium Ylides

Lanthanum-catalyzed stereoselective synthesis of vinyl sulfides and selenides

2010 ◽  
Vol 51 (2) ◽  
pp. 293-296 ◽  
Author(s):  
V. Prakash Reddy ◽  
K. Swapna ◽  
A. Vijay Kumar ◽  
K. Rama Rao
Keyword(s):  
Stereoselective Synthesis ◽  
Vinyl Sulfides

Recyclable Nano Copper Oxide Catalyzed Stereoselective Synthesis of Vinyl Sulfides under Ligand-Free Conditions

Synlett ◽  
2009 ◽  
Vol 2009 (17) ◽  
pp. 2783-2788 ◽  
Author(s):  
Kakulapati Rao ◽  
Vutukuri Reddy ◽  
Kokkirala Swapna ◽  
Akkilagunta Kumar
Keyword(s):  
Copper Oxide ◽  
Stereoselective Synthesis ◽  
Vinyl Sulfides ◽  
Ligand Free

ChemInform Abstract: Recyclable Nano Copper Oxide Catalyzed Stereoselective Synthesis of Vinyl Sulfides under Ligand-Free Conditions.

ChemInform ◽  
2010 ◽  
Vol 41 (9) ◽  
Author(s):  
Vutukuri Prakash Reddy ◽  
Kokkirala Swapna ◽  
Akkilagunta Vijay Kumar ◽  
Kakulapati Rama Rao
Keyword(s):  
Copper Oxide ◽  
Stereoselective Synthesis ◽  
Vinyl Sulfides ◽  
Ligand Free

scholarly journals Modular and stereoselective synthesis of tetrasubstituted vinyl sulfides leading to a library of AIEgens

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xun-Shen Liu ◽  
Zhiqiong Tang ◽  
Zhiming Li ◽  
Mingjia Li ◽  
Lin Xu ◽  
...  
Keyword(s):  
Sulfur Atom ◽  
Density Functional ◽  
Stereoselective Synthesis ◽  
Photophysical Properties ◽  
Density Functional Theory Calculation ◽  
Vital Role ◽  
Biologically Active ◽  
Vinyl Sulfides ◽  
Emission Effect ◽  
Diazo Carbonyl Compounds

AbstractTetraarylethylenes exhibit intriguing photophysical properties and sulfur atom frequently play a vital role in organic photoelectric materials and biologically active compounds. Tetrasubstituted vinyl sulfides, which include both sulfur atom and tetrasubstituted alkenes motifs, might be a suitable skeleton for the discovery of the new material molecules and drug with unique functions and properties. However, how to modular synthesis these kinds of compounds is still challenging. Herein, a chemo- and stereo-selective Rh(II)-catalyzed [1,4]-acyl rearrangements of α-diazo carbonyl compounds and thioesters has been developed, providing a modular strategy to a library of 63 tetrasubstituted vinyl sulfides. In this transformation, the yield is up to 95% and the turnover number is up to 3650. The mechanism of this reaction is investigated by combining experiments and density functional theory calculation. Moreover, the “aggregation-induced emission” effect of tetrasubstituted vinyl sulfides were also investigated, which might useful in functional material, biological imaging and chemicalnsing via structural modification.

Regio- and Stereoselective Synthesis of Vinyl Sulfides via PhSeBr-Catalyzed Hydrothiolation of Alkynes.

ChemInform ◽  
2007 ◽  
Vol 38 (43) ◽  
Author(s):  
Flavia Manarin ◽  
Juliano A. Roehrs ◽  
Marina Prigol ◽  
Diego Alves ◽  
Cristina W. Nogueira ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Vinyl Sulfides
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