scholarly journals A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

2016 ◽  
Vol 55 (37) ◽  
pp. 11082-11085 ◽  
Author(s):  
Thomas Pugh ◽  
Nicholas F. Chilton ◽  
Richard A. Layfield
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy ◽  
Low Symmetry

scholarly journals A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

2016 ◽  
Vol 128 (37) ◽  
pp. 11248-11251 ◽  
Author(s):  
Thomas Pugh ◽  
Nicholas F. Chilton ◽  
Richard A. Layfield
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy ◽  
Low Symmetry

DFT Computational Rationalization of an Unusual Spin Ground State in an Mn12 Single-Molecule Magnet with a Low-Symmetry Loop Structure

2005 ◽  
Vol 117 (6) ◽  
pp. 919-923 ◽  
Author(s):  
Dolos Foguet-Albiol ◽  
Ted A. O'Brien ◽  
Wolfgang Wernsdorfer ◽  
Brian Moulton ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Single Molecule ◽  
Ground State ◽  
Loop Structure ◽  
Single Molecule Magnet ◽  
Low Symmetry ◽  
Spin Ground State

Linking high anisotropy Dy3 triangles to create a Dy6 single-molecule magnet

2009 ◽  
pp. 1100 ◽  
Author(s):  
Bashir Hussain ◽  
Didier Savard ◽  
Tara J. Burchell ◽  
Wolfgang Wernsdorfer ◽  
Muralee Murugesu
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy

A High Anisotropy Barrier in a Sulfur-Bridged Organodysprosium Single-Molecule Magnet

2012 ◽  
Vol 51 (28) ◽  
pp. 6976-6980 ◽  
Author(s):  
Floriana Tuna ◽  
Charlene A. Smith ◽  
Michael Bodensteiner ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy

A High Anisotropy Barrier in a Sulfur-Bridged Organodysprosium Single-Molecule Magnet

2012 ◽  
Vol 124 (28) ◽  
pp. 7082-7086 ◽  
Author(s):  
Floriana Tuna ◽  
Charlene A. Smith ◽  
Michael Bodensteiner ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy

scholarly journals A Flexible Approach for Engineering Macrocyclic High Performance Pentagonal Bipyramidal Dy(III) Single-Ion Magnets

2020 ◽  
Author(s):  
Angelos Canaj ◽  
Sourav Dey ◽  
Claire Wilson ◽  
Oscar Céspedes ◽  
Rajaraman Gopalan ◽  
...  
Keyword(s):  
Ab Initio ◽  
Single Molecule ◽  
High Performance ◽  
Macrocyclic Ligand ◽  
Hysteresis Loops ◽  
Ligand Field ◽  
Single Molecule Magnet ◽  
Flexible Approach ◽  
High Anisotropy

A strong uniaxial ligand field generated by the Ph3SiO<sup>-</sup> ligand combined with the weak equatorial field of the macrocyclic ligand LN5, generates [DyIII(LN5)(Ph3SiO)2]+, a pentagonal bipyramidal Dy(III) Single-Molecule Magnet with a high anisotropy barrier of 1108 K, and hysteresis loops open up to 14 K. Based on our synthetic blueprint, we use <i>ab initio</i> calculations to predict changes to the macrocycle to increase the barrier to ~ 1800 K.

DFT Computational Rationalization of an Unusual Spin Ground State in an Mn12 Single-Molecule Magnet with a Low-Symmetry Loop Structure

2005 ◽  
Vol 44 (6) ◽  
pp. 897-901 ◽  
Author(s):  
Dolos Foguet-Albiol ◽  
Ted A. O'Brien ◽  
Wolfgang Wernsdorfer ◽  
Brian Moulton ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Single Molecule ◽  
Ground State ◽  
Loop Structure ◽  
Single Molecule Magnet ◽  
Low Symmetry ◽  
Spin Ground State

Ferromagnetic coupling in a chloride-bridged erbium single-molecule magnet

2017 ◽  
Vol 53 (53) ◽  
pp. 7322-7324 ◽  
Author(s):  
J. D. Hilgar ◽  
B. S. Flores ◽  
J. D. Rinehart
Keyword(s):  
Single Molecule ◽  
Ferromagnetic Coupling ◽  
Single Molecule Magnet ◽  
High Anisotropy

We present the first ferromagnetically-coupled Er3+ complex with linked, high-anisotropy Er–COT (COT2− = cyclooctatetraene dianion) subunits.

scholarly journals A Flexible Approach for Engineering Macrocyclic High Performance Pentagonal Bipyramidal Dy(III) Single-Ion Magnets

2020 ◽  
Author(s):  
Angelos Canaj ◽  
Sourav Dey ◽  
Claire Wilson ◽  
Oscar Céspedes ◽  
Rajaraman Gopalan ◽  
...  
Keyword(s):  
Ab Initio ◽  
Single Molecule ◽  
High Performance ◽  
Macrocyclic Ligand ◽  
Hysteresis Loops ◽  
Ligand Field ◽  
Single Molecule Magnet ◽  
Flexible Approach ◽  
High Anisotropy

A strong uniaxial ligand field generated by the Ph3SiO<sup>-</sup> ligand combined with the weak equatorial field of the macrocyclic ligand LN5, generates [DyIII(LN5)(Ph3SiO)2]+, a pentagonal bipyramidal Dy(III) Single-Molecule Magnet with a high anisotropy barrier of 1108 K, and hysteresis loops open up to 14 K. Based on our synthetic blueprint, we use <i>ab initio</i> calculations to predict changes to the macrocycle to increase the barrier to ~ 1800 K.

Sign in / Sign up

Export Citation Format

Share Document