Product-Derived Bimetallic Palladium Complex Catalyzes Direct Carbonylation of Sulfonylazides

2016 ◽  
Vol 55 (18) ◽  
pp. 5545-5549 ◽  
Author(s):  
Jin Zhao ◽  
Zongyang Li ◽  
Shaole Song ◽  
Ming-An Wang ◽  
Bin Fu ◽  
...  
Keyword(s):  
Palladium Complex ◽  
Bimetallic Palladium

Product-Derived Bimetallic Palladium Complex Catalyzes Direct Carbonylation of Sulfonylazides

2016 ◽  
Vol 128 (18) ◽  
pp. 5635-5639 ◽  
Author(s):  
Jin Zhao ◽  
Zongyang Li ◽  
Shaole Song ◽  
Ming-An Wang ◽  
Bin Fu ◽  
...  
Keyword(s):  
Palladium Complex ◽  
Bimetallic Palladium

Synthesis and redox properties of a phosphine-subsituted para-dioxolene and its bimetallic palladium complex

2008 ◽  
Vol 86 (10) ◽  
pp. 976-981 ◽  
Author(s):  
Sharon L Caldwell ◽  
Joe B Gilroy ◽  
Rajsapan Jain ◽  
Evan Crawford ◽  
Brian O Patrick ◽  
...  
Keyword(s):  
Palladium Complex ◽  
Electronic Spectroscopy ◽  
Chemical Oxidation ◽  
Redox Properties ◽  
Redox Activity ◽  
Redox Potentials ◽  
Cationic Complex ◽  
Bridging Ligands ◽  
Reduction Potentials ◽  
Bimetallic Palladium

Oxidation of 2,5-bis(diphenylphosphino)-1,4-hydroquinone (8) with iodobenzene diacetate produces the corresponding bis(phosphine) substituted benzoquinone (9), the first phosphine-substitued quinone. Cyclic voltammetry studies reveal that the redox functionality of the quinone unit in 9 is retained, and the reduction potentials render this compound slightly more easily reduced than the parent p-benzoquinone. Reaction of the precursor hydroquinone 8 with Pd(hfac)2 affords a binuclear complex 10 with the hydroquinonate ligand bridging two Pd(hfac) substrates. The redox activity of the bridging dioxolene ligand is retained in complex 10, although there are significant changes in the redox potentials relative to those of the free quinone 9. Chemical oxidation of 10 with AgPF6 yields a persistent cationic complex 11, which, based on EPR and electronic spectroscopy, can be formulated as containing a bridging semiquinone ligand.Key words: p-quinones, phosphines, bridging ligands, redox properties.

Electrochemical Reduction of CO2to CO Catalyzed by a Bimetallic Palladium Complex

2006 ◽  
Vol 25 (14) ◽  
pp. 3345-3351 ◽  
Author(s):  
James W. Raebiger ◽  
Jeffrey W. Turner ◽  
Bruce C. Noll ◽  
Calvin J. Curtis ◽  
Alex Miedaner ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Palladium Complex ◽  
Bimetallic Palladium

ChemInform Abstract: Product-Derived Bimetallic Palladium Complex Catalyzes Direct Carbonylation of Sulfonylazides.

ChemInform ◽  
2016 ◽  
Vol 47 (36) ◽  
Author(s):  
Jin Zhao ◽  
Zongyang Li ◽  
Shaole Song ◽  
Ming-An Wang ◽  
Bin Fu ◽  
...  
Keyword(s):  
Palladium Complex ◽  
Bimetallic Palladium

A rare P, C−bridged bimetallic palladium complex

2018 ◽  
Vol 862 ◽  
pp. 1-6 ◽  
Author(s):  
Jin Zhang ◽  
Baoyan Xing ◽  
Jianguo Zhao ◽  
Guibin Ma ◽  
Robert McDonald ◽  
...  
Keyword(s):  
Palladium Complex ◽  
Bimetallic Palladium

ChemInform Abstract: Diastereoselective Carbonyl Allylation with Simple Olefins Enabled by Palladium Complex-Catalyzed C-H Oxidative Borylation.

ChemInform ◽  
2015 ◽  
Vol 46 (35) ◽  
pp. no-no
Author(s):  
Zhong-Lin Tao ◽  
Xing-Han Li ◽  
Zhi-Yong Han ◽  
Liu-Zhu Gong
Keyword(s):  
Palladium Complex ◽  
Carbonyl Allylation
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