Nickel-Catalyzed Cross-Coupling Reactions ofo-Carboranyl with Aryl Iodides: Facile Synthesis of 1-Aryl-o-Carboranes and 1,2-Diaryl-o-Carboranes

2015 ◽  
Vol 54 (26) ◽  
pp. 7662-7665 ◽  
Author(s):  
Cen Tang ◽  
Zuowei Xie
Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3292 ◽  
Author(s):  
Kazuki Komoda ◽  
Rei Iwamoto ◽  
Masakazu Kasumi ◽  
Hideki Amii

A convenient and effective route for the synthesis of aryl(difluoromethyl)phosphonates has been developed based on cross-coupling reactions. Upon treatment with a stoichiometric amount (or a catalytic amount in some cases) of CuI and CsF, aryl iodides reacted smoothly with (silyldifluoromethyl)phosphonates to give the corresponding aryl(difluoromethyl)phosphonates in good yields.


2011 ◽  
Vol 13 (5) ◽  
pp. 1218-1221 ◽  
Author(s):  
Amruta Joshi-Pangu ◽  
Madhu Ganesh ◽  
Mark R. Biscoe

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