Controlling the Subtle Energy Balance in Protic Ionic Liquids: Dispersion Forces Compete with Hydrogen Bonds

2015 ◽  
Vol 54 (9) ◽  
pp. 2792-2795 ◽  
Author(s):  
Koichi Fumino ◽  
Verlaine Fossog ◽  
Peter Stange ◽  
Dietmar Paschek ◽  
Rolf Hempelmann ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Energy Balance ◽  
Hydrogen Bonds ◽  
Dispersion Forces ◽  
Protic Ionic Liquids

scholarly journals Inside Cover: Controlling the Subtle Energy Balance in Protic Ionic Liquids: Dispersion Forces Compete with Hydrogen Bonds (Angew. Chem. Int. Ed. 9/2015)

2015 ◽  
Vol 54 (9) ◽  
pp. 2564-2564
Author(s):  
Koichi Fumino ◽  
Verlaine Fossog ◽  
Peter Stange ◽  
Dietmar Paschek ◽  
Rolf Hempelmann ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Energy Balance ◽  
Hydrogen Bonds ◽  
Dispersion Forces ◽  
Protic Ionic Liquids

Unique Structures and Vibrational Spectra of Protic Ionic Liquids Confined in TiO2 Slits: The Role of Interfacial Hydrogen Bonds

Langmuir ◽  
2018 ◽  
Vol 34 (44) ◽  
pp. 13449-13458 ◽  
Author(s):  
Zhongyang Dai ◽  
Lili Shi ◽  
Linghong Lu ◽  
Yunhao Sun ◽  
Xiaohua Lu
Keyword(s):  
Ionic Liquids ◽  
Hydrogen Bonds ◽  
Vibrational Spectra ◽  
Protic Ionic Liquids

Hydrogen bonds in protic ionic liquids and their correlation with physicochemical properties

2011 ◽  
Vol 47 (47) ◽  
pp. 12676 ◽  
Author(s):  
Muhammed Shah Miran ◽  
Hiroshi Kinoshita ◽  
Tomohiro Yasuda ◽  
Md. Abu Bin Hasan Susan ◽  
Masayoshi Watanabe
Keyword(s):  
Ionic Liquids ◽  
Hydrogen Bonds ◽  
Physicochemical Properties ◽  
Protic Ionic Liquids

scholarly journals The infrared spectra of protic ionic liquids: performances of different computational models to predict hydrogen bonds and conformer evolution

2020 ◽  
Vol 22 (14) ◽  
pp. 7497-7506 ◽  
Author(s):  
O. Palumbo ◽  
A. Cimini ◽  
F. Trequattrini ◽  
J.-B. Brubach ◽  
P. Roy ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Hydrogen Bonds ◽  
Dft Calculations ◽  
Infrared Spectra ◽  
Computational Models ◽  
Far Infrared ◽  
Protic Ionic Liquids ◽  
Far Infrared Spectra

DFT calculations with the ωB97-D functional reproduce hydrogen bonding features of the far-infrared spectra of diethylmethylammonium methanesulfonate and diethylmethylammonium trifluoromethanesulfonate.

Characterization of Doubly Ionic Hydrogen Bonds in Protic Ionic Liquids by NMR Deuteron Quadrupole Coupling Constants: Differences to H-bonds in Amides, Peptides, and Proteins

2017 ◽  
Vol 56 (45) ◽  
pp. 14310-14314 ◽  
Author(s):  
Alexander E. Khudozhitkov ◽  
Peter Stange ◽  
Benjamin Golub ◽  
Dietmar Paschek ◽  
Alexander G. Stepanov ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Hydrogen Bonds ◽  
Coupling Constants ◽  
Protic Ionic Liquids ◽  
Quadrupole Coupling ◽  
Ionic Hydrogen Bonds

scholarly journals Solvation of apolar compounds in protic ionic liquids: the non-synergistic effect of electrostatic interactions and hydrogen bonds

2017 ◽  
Vol 19 (37) ◽  
pp. 25352-25359 ◽  
Author(s):  
I. A. Sedov ◽  
T. I. Magsumov ◽  
T. M. Salikov ◽  
B. N. Solomonov
Keyword(s):  
Ionic Liquids ◽  
Hydrogen Bonds ◽  
Synergistic Effect ◽  
Electrostatic Interactions ◽  
Protic Ionic Liquids ◽  
Better Than

Protic ionic liquids can dissolve apolar compounds better than aprotic ionic liquids.

scholarly journals The effect of dispersion forces on the interaction energies and far infrared spectra of protic ionic liquids

2015 ◽  
Vol 17 (21) ◽  
pp. 13790-13793 ◽  
Author(s):  
Ralf Ludwig
Keyword(s):  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Infrared Spectra ◽  
Far Infrared ◽  
Conventional Wisdom ◽  
Dispersion Forces ◽  
Interaction Energies ◽  
Protic Ionic Liquids ◽  
Far Infrared Spectra

Challenging conventional wisdom: dispersion forces can compete with hydrogen bonding in ionic liquids.

scholarly journals Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties

RSC Advances ◽  
2018 ◽  
Vol 8 (18) ◽  
pp. 9790-9794 ◽  
Author(s):  
Mahfuzul Hoque ◽  
Morgan L. Thomas ◽  
Muhammed Shah Miran ◽  
Mio Akiyama ◽  
Mayeesha Marium ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Hydrogen Bonds ◽  
Physicochemical Properties ◽  
Protic Ionic Liquids ◽  
Physicochemical Features

The dominance of hydrogen bonds (networking) over the physicochemical features of primary alkylamine-PILs based on an amide acid.

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